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[Display omitted] • PRISMA imagery provides valid support in the delineation of hydrothermal and supergene alteration zones. • Spectral feature parameters aids in identifying and characterising alteration minerals. • Mineral mapping of Porphyry-Cu and IOCG systems assists in mineral exploration at the province- and district-scales. • Hyperspectral satellite interpretation helps in the delineation of new exploration targets. This study provides an overview of the application of hyperspectral imagery acquired by the Italian satellite mission "PRecursore IperSpettrale della Missione Applicativa" (PRISMA), for mapping hydrothermal and supergene mineral alteration zones associated with different Cu deposits in the Chilean Andes. Study areas include the Marimaca Copper Project in the Naguayán district (Antofagasta Province), hosting Late Jurassic – Early Cretaceous iron oxide-copper–gold mineralizations and the Río Blanco-Los Bronces district (Santiago Region) known for its Late Miocene – Early Pliocene copper-molybdenum porphyry deposits. These mineral systems exhibit hydrothermal alteration haloes extending over several kilometers, with upward and outward mineral zonation. To characterize the surface-exposed alteration, the satellite imagery was processed using a multiple feature extraction workflow targeting the relative abundances and compositions of specific supergene and hydrothermal alteration minerals, including Fe-oxides and hydroxides (hematite-goethite), phyllosilicates (micas-kaolinite-chlorite), hydroxyl-bearing sulfates (alunite-natroalunite-jarosite) and epidote. The results reveal a zonation from proximal sulfates (natroalunite to alunite) and Al-rich white mica (ranging from 0.3 km-wide for the area identified to the east of the Marimaca deposit to 1 km-wide in correspondence of the Los Sulfatos deposit, respectively) to distal Al-poor white mica (0.2 to 0.5 km-wide, respectively) and an outer chlorite-epidote zone. In the Marimaca Project area, the structurally-controlled alteration evolves west to east from chlorite-rich to phengitic white mica (Al-poor). A NNE-SSW trending supergene leached cap covers a 6 km-long and up to 2 km-wide area from north to south. Our study documents how spaceborne hyperspectral imaging spectroscopy can support mineral exploration by enabling non-invasive reconnaissance mapping of the outcropping rocks, providing specific targeting information for follow-up field surveys and drilling campaigns. [ABSTRACT FROM AUTHOR]