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Magnetic resonance mass spectrometers (MRMSs), developed in the second half of the 20th century at the Ioffe Institute, have still possessed such a complex of parameters that they have no alternative for solving many analytical problems, in particular, in the isotopy of helium. With the resolution of one of the devices several thousand at the base of the 3He+ mass peak, its absolute sensitivity is <106 atoms of this isotope in the volume of the mass analyzer chamber (~2.5 L), and the 3He/4He isotope ratio measured in a single experiment can be as low as 109 and even 1010. Another device of this type demonstrated resolution of more than 150 000 at the base of the mass peak, which ensured the detection of a 3He+–3T+ doublet. Excellent analytical characteristics of the MRMSs make it possible to use them to study the isotopy of helium in natural and man-made samples (solid, liquid, or gaseous) in meteorites and lunar soil, ferromanganese nodules from the bottom of seas and oceans, in ice cores from the well of Lake Vostok in Antarctica, in water from mountain streams of Mongolia and geysers of Iceland, in volcanic gases of Kamchatka and gases released from structural materials of a modern thermonuclear installation. In this work, we consider the principle and modes of operation of an MRMS and its design. The focus is on the details that distinguish these instruments from other instruments and ensure extremely high analytical performance, which is partly presented in the article. [ABSTRACT FROM AUTHOR]

Interest in the Moon started to increase at the beginning of the 21st century, and henceforth, more and more attention has been paid to the content and distribution of water ice in the lunar polar regions. The existence of water or ice in the regolith can apparently change its dielectric features. Therefore, in this article, the Dobson model is adopted and improved according to the Moon's environmental features, to construct the relationship between the volumetric water ice content and the dielectric constant. Thereafter, a lunar regolith dielectric distribution map is generated based on the improved Dobson model and the Clementine UVVIS data. The map indicates that the imaginary part of the dielectric constants in the lunar mare is much higher than that in the highlands. However, the maximum dielectric constants occur at the north- and south-pole regions, whose values are apparently bigger than those in the middle and low latitudes. Then, an abnormal map of the dielectric constant is gained if the threshold is put as 0.053 7, which is the highest value in the middle and low latitudes. The statistical results indicate that the number of abnormal pixels is 110 596, and the average is about 0.057 9. Assuming that the mean dielectric constant in the lunar mare is the normal dielectric constant at the south and north poles and ɛ=11.58+ i0.057 9 is the abnormal one, the volumetric water ice content can be evaluated using the advanced Dobson model. The results show that the average volumetric water ice content is about 1.64%, and the total area is about 25 294 km, where 10 956 km belongs to the north pole and the rest is in the south pole. [ABSTRACT FROM AUTHOR]