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The long‐term absorption by the oceans of atmospheric carbon dioxide is leading to the slow decline of ocean pH, a process termed ocean acidification (OA). The Arctic is a challenging region to gather enough data to examine the changes in carbonate chemistry over sufficient scales. However, algorithms that calculate carbonate chemistry parameters from more frequently measured parameters, such as temperature and salinity, can be used to fill in data gaps. Here, these published algorithms were evaluated against in situ measurements using different data input types (data from satellites or in situ re‐analysis climatologies) across the Arctic Ocean. With the lowest uncertainties in the Atlantic influenced Seas (AiS), where re‐analysis inputs achieved total alkalinity estimates with Root Mean Squared Deviation (RMSD) of 21 μmol kg−1 and a bias of 2 μmol kg−1 (n = 162) and dissolved inorganic carbon RMSD of 24 μmol kg−1 and bias of −14 μmol kg−1 (n = 262). AiS results using satellite observation inputs show similar bias but larger RMSD, although due to the shorter time span of available satellite observations, more contemporary in situ data would provide further assessment and improvement. Synoptic‐scale observations of surface water carbonate conditions in the Arctic are now possible to monitor OA, but targeted in situ data collection is needed to enable the full exploitation of satellite observation‐based approaches. Plain Language Summary: The long‐term absorption by the oceans of atmospheric carbon dioxide is leading to the slow decline of ocean pH, a process termed ocean acidification (OA). Sea surface salinity and temperature measurements from satellites or in situ re‐analysis products can be used as input to empirical algorithms to calculate OA parameters. This paper provides a first analysis of published Arctic Ocean empirical algorithms to estimate surface water OA parameters using observation‐based data sets. Results show promise in the Atlantic influenced Seas using both in situ re‐analysis and satellite products, but satellite salinity is relatively recent, and a paucity of in situ data in the satellite salinity era precludes a robust assessment. To fully exploit satellite‐based approaches, efforts need to focus on collecting in situ data while these satellites are overhead and operating in orbit. Key Points: Observation‐based data sets enable synoptic spatio‐temporal assessments of Arctic Ocean carbonate system parametersRe‐analysis and satellite products predict total alkalinity with accuracies of ∼21 μmol kg−1Targeted in situ data collection is needed to fully exploit satellite observations in the Arctic to enable carbonate system monitoring [ABSTRACT FROM AUTHOR]

Warming of the Arctic due to climate change means the Arctic Ocean is now free from ice for longer, as sea ice melts earlier and refreezes later. Yet, it remains unclear how this extended ice-free period will impact carbon dioxide (CO 2) fluxes due to scarcity of surface ocean CO 2 measurements. Baseline measurements are urgently needed to understand spatial and temporal air–sea CO 2 flux variability in the changing Arctic Ocean. There is also uncertainty as to whether the previous basin-wide surveys are representative of the many smaller bays and inlets that make up the Canadian Arctic Archipelago (CAA). By using a research vessel that is based in the remote Inuit community of Ikaluqtuutiak (Cambridge Bay, Nunavut), we have been able to reliably survey p CO 2 shortly after ice melt and access previously unsampled bays and inlets in the nearby region. Here we present 4 years of consecutive summertime p CO 2 measurements collected in the Kitikmeot Sea in the southern CAA. Overall, we found that this region is a sink for atmospheric CO 2 in August (average of all calculated fluxes over the four cruises was - 4.64 mmol m -2 d -1), but the magnitude of this sink varies substantially between years and locations (average calculated fluxes of + 3.58, - 2.96, - 16.79 and - 0.57 mmol m -2 d -1 during the 2016, 2017, 2018 and 2019 cruises, respectively). Surface ocean p CO 2 varied by up to 156 µ atm between years, highlighting the importance of repeat observations in this region, as this high interannual variability would not have been captured by sparse and infrequent measurements. We find that the surface ocean p CO 2 value at the time of ice melt is extremely important in constraining the magnitude of the air–sea CO 2 flux throughout the ice-free season. However, further constraining the air–sea CO 2 flux in the Kitikmeot Sea will require a better understanding of how p CO 2 changes outside of the summer season. Surface ocean p CO 2 measurements made in small bays and inlets of the Kitikmeot Sea were ∼ 20–40 µ atm lower than in the main channels. Surface ocean p CO 2 measurements made close in time to ice breakup (i.e. within 2 weeks) were ∼ 50 µ atm lower than measurements made > 4 weeks after breakup. As previous basin-wide surveys of the CAA have focused on the deep shipping channels and rarely measure close to the ice breakup date, we hypothesize that there may be an observational bias in previous studies, leading to an underestimate of the CO 2 sink in the CAA. These high-resolution measurements constitute an important new baseline for gaining a better understanding of the role this region plays in the uptake of atmospheric CO 2. [ABSTRACT FROM AUTHOR]

Warming of the Arctic due to climate change means the Arctic Ocean is now ice-free for longer as sea ice melts earlier and refreezes later. It remains unclear how the extended ice-free period will impact carbon dioxide (CO2) fluxes due to scarcity of surface ocean CO2 measurements. Baseline measurements are urgently needed to understand how air-sea CO2 fluxes will spatially and temporally vary in a changing Arctic Ocean. It is uncertain whether the previous basin-wide surveys are representative of the many smaller bays and inlets that make up the Canadian Arctic Archipelago. By using a research vessel that is based in the remote Inuit community of Cambridge Bay (Ikaluqtuutiak, Nunavut), we have been able to reliably survey pCO2 shortly after ice melt and access previously unsampled bays and inlets in the nearby region. We present four years of consecutive summertime pCO2 measurements collected in the Kitikmeot Sea in the southern Canadian Arctic Archipelago. Overall, we found that this region is a sink for atmospheric CO2 in August (average of all calculated fluxes over the four cruises was -8.3 mmol m-2 d-1) but the magnitude of this sink varies substantially between years and locations (average calculated fluxes of 0.41, -7.70, -21.26 and -2.08 mmol m-2 d-1 during the 2016.2017,2018 and 2019 cruises respectively). Surface ocean pCO2 varied by up to 142 μatm between years; this highlights the importance of repeat observations in the Arctic as this high interannual variability would not have been captured by sparse and infrequent measurements. We find that the pCO2 value of the surface ocean at the time of ice melt is extremely important in constraining the magnitude of the air-sea flux throughout the ice-free season. Further constraining the flux in the Kitikmeot Sea will require a better understanding of how pCO2 changes outside of the summer season. Surface ocean pCO2 measurements made in the bays and inlets in the Kitikmeot Sea were ~20-40 μatm lower than in the main channels, and pCO2 measurements made close to ice breakup (i.e. within 2 weeks) were 50-100 μatm lower than measurements made >4 weeks after breakup. As basin-wide surveys of the CAA have focused on the deeper shipping channels and rarely measure close to the ice break-up date, we hypothesize that there may be an observational bias in previous studies, leading to an underestimate of the CO2 sink in the Canadian Arctic Archipelago. These high-resolution measurements constitute an important new baseline for gaining a better understanding of the role this region plays in the uptake of atmospheric CO2. [ABSTRACT FROM AUTHOR]