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The energy transition for a net-zero future will require deep decarbonisation that hydrogen is uniquely positioned to facilitate. This technoeconomic study considers renewable hydrogen production, transmission and storage for energy networks using the National Electricity Market (NEM) region of Eastern Australia as a case study. Plausible growth projections are developed to meet domestic demands for gas out to 2040 based on industry commitments and scalable technology deployment. Analysis using the discounted cash flow technique is performed to determine possible levelised cost figures for key processes out to 2050. Variables include geographic limitations, growth rates and capacity factors to minimise abatement costs compared to business-as-usual natural gas forecasts. The study provides an optimistic outlook considering renewable power-to-X opportunities for blending, replacement and gas-to-power to show viable pathways for the gas transition to green hydrogen. Blending is achievable with modest (3%) green premiums this decade, and substitution for natural gas combustion in the long-term is likely to represent an abatement cost of AUD 18/tCO2-e including transmission and storage. [ABSTRACT FROM AUTHOR]

Hydrogen (H 2) generation using Steam Methane Reforming (SMR) is at present the most economical and preferred pathway for commercial H 2 generation. This process, however, emits a considerable amount of CO 2 , ultimately negating the benefit of using H 2 as a clean industrial feedstock and energy carrier. That has prompted growing interest in enabling CO 2 capture from SMR for either storage or utilisation and producing zero-emission "blue H 2 ". In this paper, we propose a spatial techno-economic framework for assessing blue hydrogen production SMR hubs with carbon capture, utilisation and storage (CCUS), using Australia as a case study. Australia offers a unique opportunity for developing such 'blue H 2 ' hubs given its extensive natural gas resources, availability of known carbon storage reservoirs and an ambitious government target to produce clean/zero-emission H 2 at the cost of A$2.7 kg H2 −1). On the other hand, Western Australia offers lower gas pricing and relatively lesser storage costs, which would lead to more economically favourable hydrogen production (

In this study, we investigated the relationship between water characteristics and removal of natural organic matter (NOM) using polyaluminium chloride (PACl) and a newly developed coagulant obtained by hybridising PACl with chitosan (PACl-chitosan) for two different types of water. Using UV-visible spectroscopy analysis, we showed that PACl-chitosan is more effective than PACl for treating water samples that contain higher levels of activated polyhydroxyaromatic moieties. As a result, a lower level of total trihalomethanes formation potential (THMFP) was detected for synthetic water treated with PACl-chitosan coagulant compared to water treated with PACl only. In contrast, no difference was observed for the total THMFP that were formed following coagulation with either coagulant, for water sample containing the same level of organic carbon concentration, but lower levels of polyhydroxyaromatic moieties. Our work shows how the complex characteristics and interactions of organic matter with coagulant component can affect the outcome of the treatment process, and in this case, enhance the treatment. The use of PACl-chitosan was also shown to produce larger floc for both water samples; this again, can lead to better removal., (Copyright © 2013 Elsevier B.V. All rights reserved.)

The effect of TiO2 photocatalytic oxidation on the natural organic matter (NOM) properties of two Australian surface waters were quantified using UV-vis spectroscopy, high performance size exclusion chromatography (HPSEC) with a multi-wavelength UV detector, liquid chromatography with organic carbon detector (LC-OCD), and trihalomethane formation potential (THMFP) analyses. Both the UV absorbance at wavelengths greater than 250 nm and dissolved organic carbon (DOC) content decreased significantly with treatment, although complete mineralization of NOM could not be achieved. Multi-wavelength UV detection of HPSEC analysis was shown to be useful to display further changes to NOM composition and molecular weight profiles because the organic molecules was transformed into compounds that absorb weakly at the typical detection wavelength of 250-260 nm. The multi-wavelength HPSEC results also revealed that photocatalytic oxidation yields by-products with a low aromaticity and low molecular weight. The LC-OCD chromatograms indicated that low molecular acids and neutral compounds remained after photocatalytic oxidation. Those groups of compounds did not seem to contribute significantly to the formation of trihalomethanes., (Copyright (c) 2010 Elsevier Ltd. All rights reserved.)