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The Cerrado is a diverse Brazilian savanna with more than 12,000 species. Arnicão (Lychnophora salicifolia Mart – Compositae) is an endemic species occurring in central and southeast Brazil, at higher altitudes, in sandstone and quartzite soils. Lychnophora species have been reported for anti-inflammatory, antioxidant and UV protectant effects. Local communities use it to prepare traditional remedies (i.e. ointments or creams). The aim of this work was (1) to characterize the qualitative composition of L. salicifolia volatile fraction; (2) to evaluate the influence of the environmental conditions on the volatile fraction composition, by investigating plants harvested both in areas under stress conditions and protected from human interference; (3) optimizing a non-separative method for routine in-field analyses. Separative (HS-SPME-GC-MS) and non-separative (HS-SPME-MS) approach combined with PCA are proposed to discriminate between plant populations of L. salicifolia from two distinct areas. Forty-eight individuals were randomly collected from four populations. A clear separation between populations from protected and non-protected areas was observed, with an important presence of caryophyllene derivatives in populations from non-protected areas, usually with compounds associated to plant defense. Both analytical approaches gave the same results, confirming HS-SPME a useful approach for rapid in-field analysis of samples of wild populations. [ABSTRACT FROM AUTHOR]

The volatile fraction of murici, bacuri and sapodilla are here studied because of their increasing interest for consumers, abundance of production in Brazil, and the general demand for new flavors and aromas. Their volatile profiles were studied by two High Concentration Capacity Headspace techniques (HCC-HS), Headspace Solid Phase Microextraction (HS-SPME) and Headspace Sorptive Extraction (HSSE), in combination with GC–MS. Murici volatile fraction mainly contains esters (38%), carboxylic acids (19%), aldehydes (11%), alcohols (14%), others (13%) and sulfur compounds; bacuri is characterized by terpenes (41%), non-terpenic alcohols (24%), esters (15%), aldehydes (6%), and others (12%); sapodilla consists of esters (33%), alcohols (27%), terpenes (18%) and others (21%). The GC–MS component co-elution was overcome by GC × GC-qMS. The adoption of modern analysis technologies afforded to achieve a better knowledge of the volatile fraction composition of these fruit pulps by increasing substantially the number of compounds identified. [ABSTRACT FROM AUTHOR]