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Ediacaran syn-tectonic plutonic rocks (amphibole gabbros, quartz diorites/tonalites to biotite- and muscovite-bearing granites) of the Angra Fria Magmatic Complex (Kaoko Belt, north-western Namibia) belong to two compositionally similar, magnesian, transitional tholeiitic–calc-alkaline suites, the Older (∼625–620 Ma) and the Younger (∼585–575 Ma). Both have counterparts in the broadly contemporaneous Florianópolis Batholith (southern Brazil), from which they were separated during the Cretaceous opening of the southern Atlantic. In the Angra Fria Magmatic Complex, the only unequivocal mantle contributions are identified in mingling zones of the Younger Suite and hybrid mafic–intermediate dykes of uncertain age. Previously published Hf-in-zircon isotopic data, together with new whole-rock geochemical and Sr–Nd isotopic signatures, underline an important role of crustal anatexis of a material with late Palaeoproterozoic to early Mesoproterozoic mean crustal residence (1.9–1.5 Ga). This interval resembles some of the published Nd model ages for Tonian 'Adamastor Rift'-related felsic magmatic rocks in the Namibian Coastal and Uruguayan Punta del Este terranes. In detail, the Older Suite probably originated mainly by fluid-present melting of metabasalts and metatonalites, followed by (near) closed-system fractional crystallization (with or without accumulation) of amphibole ± plagioclase. For the Younger Suite, the principal process was the dehydration melting of relatively felsic lower crustal protoliths (metagreywackes or intermediate–acid orthogneisses >> metapelites), leaving garnet in the residue. Based on the geological context, the conspicuous enrichment of hydrous-fluid-mobile large ion lithophile over the conservative high field strength elements is not interpreted through a classic model of oceanic plate subduction, devolatilization, and fluxed-melting of the overriding mantle wedge. Instead, it is thought to reflect high-grade metamorphism of deeply buried continental crust and attendant water-fluxed melting of the overlying crustal lithologies, connected with inversion of the Tonian 'Adamastor Rift'. [Display omitted] • Ediacaran magmatism in Angra Fria Complex is correlated with Florianópolis Batholith. • Mature crustal material (1.9–1.5 Ga model ages) remelted with limited mantle input. • Syn- to post-collisional intracontinental setting, unrelated to oceanic subduction. • Arc-like LILE/HFSE enrichment may reflect H 2 O-fluxed melting in the crust. [ABSTRACT FROM AUTHOR]