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Pyrethroids (PYR) and UV filters (UVF) were investigated in tissues of paired mother-fetus dolphins from Brazilian coast in order to investigate the possibility of maternal transfer of these emerging contaminants. Comparison of PYR and UVF concentrations in maternal and fetal blubber revealed Franciscana transferred efficiently both contaminants to fetuses (F/M > 1) and Guiana dolphin transferred efficiently PYR to fetuses (F/M > 1) different than UVF (F/M < 1). PYR and UVF concentrations in fetuses were the highest-ever reported in biota (up to 6640 and 11,530 ng/g lw, respectively). Muscle was the organ with the highest PYR and UVF concentrations (p < 0.001), suggesting that these two classes of emerging contaminants may have more affinity for proteins than for lipids. The high PYR and UVF concentrations found in fetuses demonstrate these compounds are efficiently transferred through placenta. This study is the first to report maternal transfer of pyrethroids and UV filters in marine mammals. [ABSTRACT FROM AUTHOR]

Abstract: During the 2006/07 and 2008/09 growing seasons in Southern Brazil, we evaluated crop selectivity and weed control efficacy of clomazone on rice when applied alone or in a mixture with other pre- and post-emergence herbicides (BRS Querência variety). All herbicide treatments caused some degree of rice injury during both years; however, in no case was the injury still visible 21 days after application. Rice injuries were observed when application rates exceeded the recommended dose, and particularly when the herbicide was applied pre-emergence. Density reduction and panicle sterility served as measures of rice injury. Echinochloa crus-galli was the primary weed; it reduced rice yields by approximately 50% compared treated plots. In both growing seasons, clomazone herbicide (400 g ai ha−1) controlled the weed 87.0%–99.6%, and it provided 8.06 t ha−1 to 9.44 t ha−1 of rice yield. [Copyright &y& Elsevier]

Most current bioexposure assessments for UV filters focus on contaminants concentrations in fish from river and lake. To date there is not information available on the occurrence of UV filters in marine mammals. This is the first study to investigate the presence of sunscreen agents in tissue liver of Franciscana dolphin (Pontoporia blainvillei), a species under special measures for conservation. Fifty six liver tissue samples were taken from dead individuals accidentally caught or found stranded along the Brazilian coastal area (six states). The extensively used octocrylene (2-ethylhexyl-2-cyano-3,3-diphenyl-2-propenoate, OCT) was frequently found in the samples investigated (21 out of 56) at concentrations in the range 89-782 ng·g(-1) lipid weight. São Paulo was found to be the most polluted area (70% frequency of detection). Nevertheless, the highest concentration was observed in the dolphins from Rio Grande do Sul (42% frequency of detection within that area). These findings constitute the first data reported on the occurrence of UV filters in marine mammals worldwide.