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Blending of potentially acid generating (PAG) waste rock with non-PAG waste rock to create a rock mixture which performs as non-PAG is a possible approach to permanent prevention of acid rock drainage (ARD) for PAG waste rock. In 2012, a field weathering study using 300 kg samples was implemented at Teck Coal's Quintette Project located in northeastern British Columbia, Canada to test the prevention of acid generation in the PAG waste rock by dissolved carbonate leached from overlying non-PAG waste rock and direct neutralization of acidic water from PAG waste rock by contact with non-PAG waste rock. After eight years of monitoring the experiments, the layered non-PAG on PAG barrels provided proof-of-concept that as the thickness of the PAG layer increases relative to the thickness of the non-PAG layers, acidic waters are more likely to be produced. The PAG on non-PAG layering has resulted in non-acidic water and no indications of metal leaching despite accelerated oxidation in the PAG layer shown by sulfate loadings. The study has demonstrated that the scale of heterogeneity of PAG and non-PAG materials is a critical consideration for providing certainty that rock blends designed to be non-PAG will perform as non-PAG in perpetuity. This is contrary to the standard paradigm in which an excess of acid-consuming minerals is often considered sufficient alone to ensure ARD is not produced. [ABSTRACT FROM AUTHOR]

The leaching process and drainage chemistry of acid rock drainage is mainly controlled by geochemical reactions and how water carries soluble reaction products in waste rock piles. This paper studied how water flows through a full-scale waste rock pile at the Equity Silver mine site in British Columbia, Canada and elaborated on their effects on the leaching process and drainage chemistry. A revised dual-permeability model coupled with mass transport was adopted to investigate preferential flow and matrix flow in the pile simultaneously while considering water and geochemical products leaching/exchange between them. Furthermore, a particle-level water film model and also the effects of air flow, oxygen transport, and heat transfer in pile scale were integrated to account for geochemical reactions. Simulation results of full-scale iron discharge showed that aqueous concentrations in drainage water did not vary significantly relative to variations in drainage flow rate, which was confirmed by 12 years of field monitoring data. In addition, the comparison of pre- and post-cover simulations with measured lime consumption during ARD treatment, and mass-balance/dilution calculations for the entire pile, indicates that roughly 15–20% of total precipitation passes through the cover. [ABSTRACT FROM AUTHOR]

The Pennask Creek watershed in British Columbia (BC), Canada has been contaminated with acid rock drainage (ARD) and associated metal leaching (ML) as a result of highway construction. By combining existing and newly gathered information, this study determined the extent of metal contamination of the water and sediments, the potential biological impacts of this contamination, the influence of local geology, and estimated the potential risk to aquatic organisms. Surface water and sediment samples from the watershed were analyzed for general chemical parameters and trace metals. Rock samples were analyzed for mineralogy and chemical composition. Metal concentrations in water and sediments downstream of the ARD/ML source were higher than elsewhere in the watershed. Metals of concern include aluminum (Al), copper (Cu), and zinc (Zn). Analysis of historical water quality data indicated that the concentrations of these metals have decreased markedly since 2004, due to remediation efforts. Rock samples collected from the streambeds and banks were not found to be potentially acid generating, but did contain significant levels of metals. Al, Cu, and Zn levels consistently exceeded BC water and sediment quality guidelines for the protection of aquatic life, indicating that adverse biological effects are probable at stations downstream of the ARD/ML source. Benthic invertebrate monitoring over a 10-year period showed low abundance and diversity and a complete absence of sensitive taxa at downstream stations. Risk quotients indicated a likelihood of adverse biological effects for aquatic organisms, including rainbow trout, due to metal contamination in the watershed. [ABSTRACT FROM AUTHOR]

The Province of British Columbia, Canada, is undertaking environmental remediation at Britannia Mine, located approximately 45 km north of Vancouver. Britannia Mine operated for 70 years and produced mainly copper and zinc concentrates. During its operating life, and since its closure in 1974, the mine has discharged large volumes of acidic water with elevated concentrations of potentially toxic metals, including copper, zinc, and cadmium. Prior to the recent remedial efforts, metal loadings to Howe Sound averaged 300 kg/day each of copper and zinc. In addition to the acid rock drainage, mine infrastructure and mineral processing activities provide secondary sources of metal contamination of soils, sediments, ground water, and surface water. Effective water management is key to the remedial plan for the mine: ground water and surface water are the primary transport pathways for the metal contamination reaching the local receptors of Britannia and Furry creeks, and Howe Sound. The remedial concept includes diversion of clean water from entering the mine, use of the mine workings as a storage reservoir to balance seasonal flows to a water treatment plant, prior to discharging to Howe Sound via a deep outfall, and the interception of a metal-contaminated ground water plume. [ABSTRACT FROM AUTHOR]

An integrated hydrogeochemical and stable isotope study was undertaken to assess tailings pond leakage at the Nickel Plate Mine site in British Columbia, Canada. The approach used consisted of a hydrochemical mixing model for sulfate in conjunction with stable isotope data (18O and 2H) to estimate possible levels of contamination reaching surface waters from leakage through the dam and to determine the relative percentages of "seepage" that can be attributed to leakage through the dam and to natural groundwater flow beneath and around the dam. Results suggest that tailings pond waters are diluted by groundwaters by approximately 50% before their arrival in the collection swamps, and that the leakage from the tailings pond partially by-pass the collection (and pump-back) system at a rate of between 0.09 and 0.12 l/s. Stable isotope data indicate that tailings pond waters and swamp waters are enriched in the heavier isotopes as a result of evaporation, and thus, tend to plot along an evaporation line of slope 3.9 (D/18O). The isotope data indicate that seepage beneath the dam consists of approximately 50% real seepage and 50% meteoric waters (both surface water and groundwaters). [ABSTRACT FROM AUTHOR]

In waste rock piles, the leaching process involved in acid rock drainage is mainly controlled by water flow. This paper (Part 2) investigates the effects of heterogeneities on the water flow patterns by applying probability density functions to hydrogeological properties. In this study, a piecewise constant distribution is proposed to describe the permeability inside waste rock piles, which reflects the effect of both finer and coarser pores. Compared with uniform water flow obtained from traditional homogeneous modeling, various water flow patterns and their pathways inside waste rock piles can be simulated by the proposed model. In addition, the leaching process is also investigated by coupling the calculated water flow with the geochemical reaction based on the water film model proposed in part 1. For demonstration, these models are integrated and applied to the full-scale waste rock pile at Equity Silver mine in British Columbia, Canada. Because the iron loading is highly correlated to the acidity at this site, it is found that the fluctuation of annual lime consumption for neutralization at this site can be well predicted by the integrated model. In addition, the results indicate that waste rock piles with different spatial patterns of permeability distribution, but with the same probability density function, may have different water flow patterns and spatial distributions of iron concentrations inside the pile. However, the total water flow discharge rate and iron loading profiles from the pile are almost the same on the temporal scale. • Heterogeneities of permeability and water flow in waste rock piles are investigated. • A piecewise constant distribution for permeability in waste rock piles is proposed. • Combination of streamlines can be simulated, which is consistent to test observations. • Probability distribution function rather than its spatial pattern controls the output. • The fluctuation of lime consumption for full-scale waste rock piles can be simulated. [ABSTRACT FROM AUTHOR]