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Busan Port is among the world's top ten most air-polluted ports, but the role of the anchorage zone as a significant contributor to pollution has not been studied. To assess the emission characteristics of sub-micron aerosols, a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was deployed in Busan, South Korea from September 10 to October 6, 2020. The concentration of all AMS-identified species and black carbon were highest when the winds came from the anchorage zone (11.9 µg·m−3) and lowest with winds from the open ocean (6.64 µg·m−3). The positive matrix factorization model identified one hydrocarbon-like organic aerosol (HOA) and two oxygenated organic aerosol (OOA) sources. HOAs were highest with winds from Busan Port, while oxidized OOAs were predominant with winds from the anchorage zone (less oxidized) and the open ocean (more oxidized). We calculated the emissions from the anchorage zone using ship activity data and compared them to the total emissions from Busan Port. Our results suggest that emissions from ship activities in the anchorage zone should be considered a significant source of pollution in the Busan Port area, especially given the substantial contributions of gaseous emissions (NOx: 8.78%; volatile organic compounds: 7.52%) and their oxidized moieties as secondary aerosols. [Display omitted] • Chemical characteristics of PM 1 in Busan Port were monitored using HR-ToF-AMS. • The highest PM 1 concentration was observed with winds from the anchorage zone. • PMF model identified three organic aerosol sources with dominance of oxygenated organic aerosols. • PM and gaseous emissions from the anchorage zone were calculated using ship activity data. • The emission from the anchorage zone was suggested as a significant pollution source in the port region. [ABSTRACT FROM AUTHOR]