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Herbal infusions are consumed worldwide owing to their beneficial properties. Cultivated or obtained from the wild, herbal raw plant materials may contain trace elements at various levels. This study relates to the release of beneficial and potentially toxic trace elements from herbal preparations during infusion. The elemental contents of seven commercially available herbal tea products were determined prior to and following two modes of infusion. Teabags (of equal herb content) were infused in 200 mL of boiling bottled water "Holy Spirit" for 15 and 45 min, in glass beakers. The total content of 57 elements including heavy metals, rare earth elements, as well as Th and U, were determined by ICP-MS and ICP-AES. The metals present in the highest concentrations were K, Ca, P, and S. Potassium, Mg, Co, Ni, As, Rb, and Cs had the highest extractability, whereas Ga, Ge, Se, Zr, Nb, Te, Er, Yb, W, Tl, and U had the lowest extractability. [ABSTRACT FROM AUTHOR]

The moss biomonitoring technique was used for assessment of air pollution in the central part of Georgia, Caucasus, in the framework of the UNECE ICP Vegetation. A total of 35 major and trace elements were determined by two complementary analytical techniques, epithermal neutron activation analysis (Na, Mg, Al, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Se, B, Rb, Sr, Zr, Mo, Sb, I, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, Hf, Ta, W, Th, and U) and atomic absorption spectrometry (Cu, Cd, and Pb) in the moss samples collected in 2019. Principal Component Analyses was applied to show the association between the elements in the study area. Four factors were determined, of which two are of geogenic origin (Factor 1 including Na, Al, Sc, Ti, V, Cr, Fe, Co, Ni, Th, and U and Factor 3 with As, Sb, and W), mixed geogenic–anthropogenic (Factor 2 with Cl, K, Zn, Se, Br, I, and Cu) and anthropogenic (Factor 4 comprising Ca, Cd, Pb, and Br). Geographic information system (GIS) technologies were used to construct distributions maps of factor scores over the investigated territory. Comparison of the median values with the analogous data of moss biomonitoring in countries with similar climatic conditions was carried out. [ABSTRACT FROM AUTHOR]

The results of atmospheric deposition of trace elements in a 2015 moss survey in Georgia are reported. The 36 moss samples were collected in different regions of the Caucasus in compliance with the UNECE ICP Vegetation guidelines. Elemental determination was carried out by epithermal neutron activation analysis (ENAA). For the first time, 47 elements were determined for the sampled areas. The scanning electron microscopy with x-ray energy-dispersive analysis was applied to examine the origin of atmospheric particles accumulated by mosses. Microanalysis of moss samples collected in the highlands of Georgia showed the presence of clastic, anthropogenic, and cosmic dust particles. Comparison of the determined values with corresponding data from a pristine area of Norway was carried out. Multivariate statistical analysis of the results obtained was used to identify and characterize pollution sources in the sampled areas of Georgia. Elevated levels of heavy metals were revealed in Western Georgia, where many industrial mining enterprises and high-traffic roads are located. [ABSTRACT FROM AUTHOR]