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• CO 2 sequestration and EGR are experimentally evaluated in two shale gas reservoirs. • Pore heterogeneity and connectivity are evaluated via multifractal analysis. • Shale composition controls on gas storage is evaluated from gas adsorption measurements. • Links between MICP and gas adsorption measurements were used to evaluate EGR suitability. In the global effort toward climate change mitigation, geologic storage of CO 2 in shale plays is becoming critical while it can improve production from these reservoirs. In this study, the gas storage capacity and CO 2 sequestration suitability of the Longmaxi and Niutitang shale gas reservoirs is investigated and compared via XRD analysis, programmed pyrolysis, low pressure N 2 and CO 2 adsorption, high pressure CH 4 adsorption, and MICP analysis. Results showed that clay and TOC controls on micropore heterogeneity and connectivity happens only within the Longmaxi Formation. Furthermore, both components play a role in the adsorbed quantities of gas in the formation which revealing a higher storage capacity in mesopore-macropores. This was verified by a positive correlation between adsorbed volume within the mesopore-macropore space. The Longmaxi Formation was also found to own better pore connectivity and PSD homogeneity of mesopore-macropores, indicating easier pathways for CO 2 movement channels within the pore network. Furthermore, the samples from the Longmaxi exhibited a positive relationship between adsorbed volume with the CO 2 breakthrough pressure and median pore diameter, alike between the mesopore-macropore volume and CO 2 breakthrough pressure. This means, the injected CO 2 will displace adsorbed methane within the mesopore-macropore and will be adsorbed and stored in such pores. Overall, superiority of the Longmaxi shale over the Niutitang for CO 2 storage and EGR would be significant for future operations in similar shale gas reservoirs in China and around the globe. [ABSTRACT FROM AUTHOR]