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Coal-fired power plants (CFPPs) are an important anthropogenic mercury (Hg) source in China, and it is crucial to understand the environmental impacts of this detrimental element emitted from this source. In the present study, field experiments were conducted for measuring Hg in ambient atmosphere and upland agricultural soils within a radius of 10 km surrounding a large scale coal-fired power plant (1550 MW) in Tangshan, Hebei province. Short-term (20 min) average of gaseous elemental mercury (GEM or Hg0) in ambient air varying from 1.5 to 9.0 ng/m3 and total Hg (THg) in surface agricultural soil (0–20 cm) varying from 9.2 to 43.5 μg/kg at different sites were observed. THg in two soil cores decreased with depth, with concentrations being 2–2.5 times higher in the surface layer than that in the deep layer (50–60 cm), indicating the possibility of the atmospheric input of Hg. Based on the information of the total atmospheric Hg emission since this CFPP's operation in 1970s and the increased THg in nearby soils, it was estimated that about 3.9% discharged Hg has accumulated in the nearby agricultural soils. The low retention rate of the total emitted Hg by soils is a result of high proportion of Hg0 (79.5%) in stack gas emission and potential loss of Hg from soil surface reemission. The positive shifting (~ 0.5‰) of Hg isotopic signature (δ202Hg) from deep soil to surface soil reflected Hg deposition from nearby CFPP emissions that are featured with much heavier Hg isotopic signatures inherited from feed coal (δ202Hg: –0.50‰) and different combustion products (δ202Hg: –0.95 to 3.71‰) compared with that in deep soil layer (δ202Hg: ca –1.50‰). Overall, this study demonstrated that this CFPP has a slight but distinguishable effect on the elevation of ambient GEM and agricultural soil THg in the local environment. [ABSTRACT FROM AUTHOR]

Recently, more and more poisoning accidents associated with toxic heavy metals have been reported throughout China, coal-fired power plants (CFPPs) sector is regarded as one of the most important source categories of anthropogenic atmospheric releases of heavy metals due to tremendous annual coal consumption (about 1785.3 Mt in 2012). In this paper, with the concept of whole process control, the co-benefit or synergistic removal efficiencies of different control measures used in CFPPs of China are evaluated, the combination of coal washing before burning plus post combustion cleaning of selective catalytic reduction (SCR) + electrostatic precipitator/fabric filters (ESP/FFs) + wet flue gas desulfurization (WFGD) configuration is identified to be the best available control technology for heavy metals abatement of CFPPs at present and in the near future. However, the widely application of special mercury control (SMC) technologies in Chinese CFPPs in future is greatly needed. Furthermore, three energy scenarios and three control scenarios were assumed to forecast the future trend of heavy metals emissions. Under the same control scenario, the change of the energy saving and energy structure will give rise to about 24.1% and 24.6% of abatement potential for heavy metals in 2020 and 2030, respectively. Whereas, under the current energy consumption pattern and air pollution control policies, the installation of SCR + SMC + ESP/FFs + WFGD will result in about 21.0–44.1% and 36.3–67.5% of reduction for heavy metals emissions in 2020 and 2030, respectively. Finally, integrated control suggestions are proposed to minimize the final toxic heavy metals discharges. [ABSTRACT FROM AUTHOR]

Abstract: The cement industry is one of the most significant anthropogenic sources of atmospheric mercury emissions worldwide. In this study of three typical Chinese cement plants, mercury in kiln flue gas was sampled using the Ontario Hydro Method (OHM), and solid samples were analyzed. Particulate matter recycling, preheating of raw materials, and the use of coal and flue gas desulfurization derived gypsum contributed to emissions of Hg in the air and to accumulation in cement. Over 90% of the mercury input was emitted into the atmosphere. Mercury emission factors were 0.044–0.072 g/t clinker for the test plants. The major species emitted into the atmosphere from cement plants is oxidized mercury, accounting for 61%–91% of the total mercury in flue gas. The results of this study help improve the accuracy of the mercury emission inventory in China and provide useful information for developing mercury controls. [Copyright &y& Elsevier]

Cement plants (CPs) are one of the most important anthropogenic sources of mercury (Hg) emissions in China. Over 1000 cement production lines operate in China and use various raw materials; however, little data on Hg emissions is recorded on site. This study investigated a CP in Guizhou Province that uses multiple mining and industrial wastes as part of the circular economy policy. Among the various raw materials, carbide slag had the highest Hg content (2.6 mg/kg) and contributed half of the Hg input. High Hg concentration (27 mg/kg) in the kiln tail dust and a strong Hg enrichment factor (39) was found, which was determined as the ratio of total Hg accumulated within the clinker production process to the daily Hg input from raw materials and fuel. The clinker had negligible Hg (0.001 mg/kg), while the Hg in cement products (0.04 mg/kg) mostly came from additives and retarders. The estimated atmospheric emission factor of Hg from this CP was 161.5 mg Hg/t clinker, which was much higher than those of other CPs in Guizhou that employ low-Hg raw materials. A five-step sequential extraction experiment with kiln tail dust indicates that Hg mainly existed in fraction of F4 (73–96% of the total Hg, possibly as Hg 2 Cl 2) and that some samples had high proportions of water-soluble Hg (up to 21% of the total), which may be easily released into surrounding water bodies and pose high environmental risks. Using low-Hg raw (or alternative raw) materials and conducting proper disposal of kiln tail dust will reduce the environmental risk of Hg from CPs. [Display omitted] • Mercury was extremely enriched during the clinker production process. • Carbide slag is a high-mercury-laden solid waste that provided the highest mercury input. • Atmospheric emissions of mercury were higher than at other cement plants. • Kiln tail dust poses a considerable environmental risk. [ABSTRACT FROM AUTHOR]

Abstract: Coal is one of the major energy resources in China, with nearly half of produced Chinese coal used for power and heat generation. The large use of coal for power and heat generation in China may result in significant atmospheric emissions of toxic volatile trace elements (i.e. F, As, Se, Hg, and Sb). For the purpose of estimating the atmospheric emissions from coal-fired power and heat generation in China, a simple method based on coal consumption, concentration and emission factor of trace element was adopted to calculate the gaseous emissions of elements F, As, Se, Hg, and Sb. Results indicate that about 162161, 236, 637, 172, and 33t F, As, Se, Hg, and Sb, respectively, were introduced into atmosphere from coal combustion by power and heat generation in China in 2009. The atmospheric emissions of F, As, Se, Hg, and Sb by power and heat generation increased from 2005 to 2009 with increasing coal consumptions. [Copyright &y& Elsevier]

This paper will address significant issues related to discrepancies between the atmospheric measurements of HCFC142b and estimated emissions from production and use data, and attempt to improve the agreement between them. Current discussions and regulations regarding materials used to make extruded polystyrene foam (XPS) are using insufficient and incorrect data. This poor information may affect current and future use of an important energy management product. This paper presents new data and information regarding emissions of HCFC142b used to make XPS products. The data are from a variety of governmental and industry sources. Furthermore, as HCFC142b is being phased out of use in developed XPS markets, its use is increasing significantly in emerging markets, particularly China. The new information is used to develop a bottom-up model for HCFC142b that reasonably estimates atmospheric measurements. It is a reliable tool for assessing use scenarios of HCFC142b, and can be used to develop useful management actions for the use of this material, and develop appropriate policies for replacement materials for HCFC142b in XPS products. [ABSTRACT FROM AUTHOR]

Residential coal combustion (RCC) is a major source of atmospheric mercury (Hg) in rural areas of China, but little is known about the isotope signatures of Hg from this source. In the present study, the isotope compositions of speciated Hg (Hg0, Hg2+, and Hgp) in flue gas emitted from RCC were investigated in two important coal-producing areas (Xingren (XR) and Jinsha (JS)) of Guizhou Province, Southwest China. The total Hg concentration in discharged flue gas is in the range of 1.80–9.65 μg/m3 at the two sites, and the emission ratio reaches 99.87%. Isotope signatures of total Hg in flue gas are similar to those of Hg in feed coal, with near-zero Δ199Hg and negative δ202Hg (−1.47‰ for XR and −3.00‰ for JS) in discharged flue gas. Such isotope signatures are very different from those of Hg emissions from modern coal-fired power plants with much higher δ202Hg signals. Negative shifts from Hg0 to Hg2+ in flue gas for δ202Hg (−0.94‰) and Δ199Hg (−0.51‰) were observed, suggesting that both mass-dependent fractionation and mass-independent fractionation occurred during RCC. The nuclear volume effect produced by chlorine oxidation of Hg0 to Hg2+ may play an important role in the observed mass-independent fractionation in Hg2+. Without any air pollution control devices, RCC potentially increases the atmospheric Hg levels and has a negative-shifting impact on the δ202Hg of atmospheric Hg. Image 1 • Isotope signature of total Hg is consistent between flue gas and feed coal • Obvious MDF occurred among different Hg species in the flue gas • Significant MIF is observed for Hg2+ due to the oxidation of Hg0 • RCC is an important Hg source and potentially impacts atmospheric Hg isotope composition [ABSTRACT FROM AUTHOR]

Coal burning is a main concern for a range of atmospheric pollutants, including the environmentally sensitive element chromium (Cr). Cr migrates to the environment through stack emissions and can leach out from solid coal-burning byproducts, thereby causing adverse effects on the ecosystem. In this study, atmospheric emissions of Cr from six coal-fired power plants (CFPPs), as well as the distribution of Cr inside these CFPPs in Guizhou Province, Southwest China, were investigated. Among the six CFPPs, one was a circulating fluidized bed boiler and the others were pulverized coal boilers. The results showed that Cr in the feed fuel of these CFPPs ranged from 39.5 to 101.5 mg·kg−1 (average: 68.0 ± 24.8 mg·kg−1) and was approximately four times higher than the national and global average. Cr in the feed fuel correlated significantly with the ash yield, demonstrating that Cr in coal is closely associated with ash-forming minerals. After the coal combustion and the treatment by different air pollution control devices, most Cr (>92%) in the installation was retained in the captured fly ash and bottom ash, with less as gypsum (0.69–7.94%); eventually, only 0.01–0.03% of Cr was emitted into the atmosphere with a concentration of 1.4–2.2 μg·Nm−3. The atmospheric emission factors of Cr for these utility boilers were as low as 14.86 ± 3.62 mg Cr·t−1 coal, 7.72 ± 2.53 μg Cr (kW·h)−1, and 0.70 ± 0.19 g Cr·TJ−1, respectively. About 981 kg·y−1 of Cr was discharged into the atmosphere from Guizhuo's CFPPs in 2017, much lower than previous reported values. Most of the Cr in the CFPPs ended up in solid combustion products, identifying the need for the careful disposal of high-Cr-containing ashes (up to 500 mg·kg−1) to prevent possible mobilization into the environment. [ABSTRACT FROM AUTHOR]