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This study analyzed the spatiotemporal variation characteristics of extreme maximum temperature events (EMTEs) in East China in the last 60 years and investigated the relationship between EMTEs and atmospheric circulation. The arithmetic mean, linear trend, and the Mann–Kendall test were applied to daily maximum temperature (DMT) data (1961–2020) from 345 meteorological observation stations with complete observation records in East China to compile four characteristic indexes of EMTEs: intensity, consecutive days, first days, and last days. The analysis of these indexes revealed the following: (1) The annual number of days with a DMT ≥ 35 °C increased at the rate of 1.45 d/decade (p ≤ 0.05); the mutation occurred in 2009 with a growth rate before and after the mutation of 0.4 and 2.8 d/10a, respectively. Most of the region showed an increasing trend, with the most significant increase to the east of the Yangtze River Delta, in coastal areas of Zhejiang and Fujian, and south of Jiangxi. (2) The EMTE intensity rose at the rate of 0.15 °C/decade (p ≤ 0.05). Most areas showed a significant upward trend, and the historical extreme values of EMTEs mostly appeared in the 21st century. (3) The annual mean growth rate of consecutive EMTE days was 0.24 d/10a, which increased significantly after 2003. In comparison with 1961–2002, consecutive EMTE days increased by 35% during 2003–2020. The rate of increase was significant (p ≤ 0.05) for most areas east of the Yangtze River Delta, coastal areas of Zhejiang and Fujian, and areas south of Jiangxi. The mean mutation time was 2003, and the growth rate before and after the mutation was 0.4 and 1.4 d/10a, respectively. (4) The mean first EMTE day advanced and the mean last EMTE day became delayed, especially in the 21st century. Over the study period, the mean first EMTE day advanced by 12 days and the mean last EMTE day became delayed by 7 days. (5) The analysis of National Centers for Environmental Prediction/National Center for Atmospheric Research reanalysis data indicated that an increasing number of EMTEs have occurred in East China. The reason is that this region experiences atmospheric subsidence resulting from the intensification and westward extension of the subtropical high coupled with the weakening and northward displacement of the mid-latitude westerly trough. [ABSTRACT FROM AUTHOR]