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Materials-oriented chemical engineering involves the intersection of materials science and chemical engineering. Development of materials-oriented chemical engineering not only contributes to material research and industrialization techniques but also opens new avenues for chemical engineering science. This review details the major achievements of materials-oriented chemical engineering fields in China, including preparation strategies for advanced materials based on the principles of chemical engineering as well as innovative separation and reaction techniques determined by new materials. Representative industrial applications are also illustrated, highlighting recent advances in the field of materials-oriented chemical engineering technologies. In addition, we also look at the ongoing trends in materials-oriented chemical engineering in China. [ABSTRACT FROM AUTHOR]

A combined study of zircon LA-ICP-MS U-Pb dating, trace elements and Hf isotope was carried out for gneissic granite from the Sanzhishu area in Jingning, SW Zhejiang Province. Nearly all the zircons separated from the granite exhibited oscillatory zoning and high Th/U ratios (>0.1). The REE profile showed a pronounced positive Ce anomaly, negative Eu anomaly and an enrichment of HREE, which are typical characteristics of magmatic zircon. Thirteen concordant or nearly concordant analytical data yielded a weighted mean 207Pb/206Pb age of 1860±13 Ma (MSWD=0.084), representing the formation age of the granite. The magmatic zircons had negative ϵHf(t) values of -15.6 to -10.0 and two-stage Hf model ages of 3.1 to 3.4 Ga, indicating that the granites were formed by reworking of ancient crust. The major- and trace-element data indicate that the gneissic granites are metaluminous high-K calc-alkaline rocks and exhibit the same geochemical characteristics as aluminous A-type granites, implying the emplacement of the granite in a post-orogenic extensional tectonic setting. We conclude that the Paleoproterozoic crustal reworking event in the Cathaysia Block of South China marked the transition from assembly to break-up of the Columbia supercontinent. [ABSTRACT FROM AUTHOR]

Abstract: The Precambrian basement of northern Wuyishan (southern Zhejiang Province, eastern Cathaysia Block, South China), consists mainly of Paleoproterozoic granites and metamorphic rocks of the Badu Complex, which are the oldest rocks found in the Cathaysia Block. LA-ICPMS zircon U–Pb ages for a gneiss and five gneissic granites from the Tianhou, Danzhu, Xiaji and Lizhuang plutons indicate that magmatism and metamorphism took place between 1888 and 1855Ma. The Xiaji (1888±7Ma) and Lizhuang (1875±9Ma) granites have high SiO2, K2O and Rb contents, high A/CNK (1.09–1.40) and Rb/Sr, and low contents of Sr, REE and mafic components (Mg, Fe, Ti, Mn and other transition metals). They have the geochemical signature of S-type granites, and a sedimentary protolith is confirmed by the presence of abundant inherited zircons with a range of ages and Hf-isotope compositions. The Tianhou and Danzhu granites are metaluminous to weakly peraluminous (A/CNK=0.80–1.07), and have low SiO2 contents, high Ga/Al and FeO/(FeO+MgO) ratios, and Zn and HFSE concentrations typical of A-type granites. They also record high crystallization temperatures (885–920°C), consistent with A-type granites. High Y/Nb ratios (>1.4) indicate that they belong to the A2 subgroup, suggesting that they probably formed in a post-orogenic tectonic setting. Their ages range from 1867 to 1855Ma, slightly later than the syn-collisional Lizhuang and Xiaji S-type granites. These granitic rocks and the metamorphic rocks of the Badu Complex define a late Paleoproterozoic orogenic cycle in the area. All the 1.86–1.90Ga zircons, whether derived from S- or A-type granites, show similar Hf-isotopic compositions, with Hf model ages clustering at ∼2.8Ga. These model ages, and inherited zircons (ca. 2.5–2.7Ga) found in some rocks, indicate that the late Paleoproterozoic magmatism and tectonism of the eastern Cathaysia Block represent an overprint on an Archaean basement. This Paleoproterozoic orogeny in the Wuyishan terrane coincides with the assembly of the supercontinent Columbia, suggesting that the Wuyishan terrane was the part of this supercontinent. Zircon ages also record an early Mesozoic (Triassic) tectonothermal overprint that was very intensive in the northern Wuyishan area, leading to high-grade metamorphism of Paleoproterozoic basement, Pb loss from Paleoproterozoic zircons and overgrowth of new zircon. The central and southern parts of Wuyishan and the Chencai area (northern Zhejiang Province) also experienced strong reworking in Neoproterozoic and early Paleozoic times. The Wuyishan terrane (especially in the north) represents a long-lived remnant of the old craton, which has survived for at least one billion years. The compositions of the basement rocks, the Paleoproterozoic orogeny and the Triassic tectonothermal imprint in the Wuyishan terrane are similar to those recognized in the Yeongnam massif of South Korea, suggesting that the two terranes may have been connected from Paleoproterozoic to Triassic time. [Copyright &y& Elsevier]