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The ongoing transition from fossil fuel-based electricity generation toward green energy relying on the intermittent renewable energy sources indispensably requires development of novel energy conversion and storage methods. Depending on a particular location and local resources, pumped storage, lithium- or sodium-ion batteries, compressed air energy storage, as well as the so called power-to-gas (P2G) technologies may be applied. Taking into account the abundant solar energy resources available in the northwestern China, such as Ningxia hui autonomous region, and local water resources coming from the Yellow River, a power-to-hydrogen (P2H2) distributed energy conversion system is proposed in this paper, which is based on a high-efficiency reversible Solid Oxide Cell (rSOC). The conducted studies comprise tests with simulated current based on the actual photovoltaic power station data, and with usage of the as-obtained Yellow River water for the electrolysis mode without any pretreatment. It is documented that the reversible operation is beneficial, and the tested cell can operate for a prolonged time. Of importance, Na, Ca, Mg, and Si elements remain in an evaporator, and do not contaminate the cell, while higher than the initial boron concentration can be found in the condensed exhaust gases. The respective operational parameters of the system correspond to an electrolysis current density loading up 433.3 mA cm−2 for 4 h, as well as fuel cell operation mode with a current density of 8.3 mA cm−2 for 12 h. It is found that the average voltage losses in the electrolysis cell and fuel cell mode are 0.27 %/cycle and 0.886 %/cycle, respectively, indicating that the lifetime of the cells can be more than 800 h. The reported studies demonstrate validity of applying rSOC-based P2H2 system, especially if abundant photovoltaic power and water resources are available. [Display omitted] • The Yellow River water was utilized by rSOC for the first time. • The designed test current was modeled with local photovoltaics. • The P2H2 nearby consumption system can reversibly operate for over 800 h. • The degradation rates in SOFC mode are lower than those in SOEC mode. • The Yellow River water has no significant effect on the degradation rate. [ABSTRACT FROM AUTHOR]