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Soil and water loss due to traditional intensive types of agricultural management is widespread and unsustainable in Croatian croplands. In order to mitigate the accelerated land degradation, we studied different cropland soil management strategies to obtain feasible and sustainable agro-technical practices. A rainfall simulation experiment was conducted at 58 mm h–1 over 30 min on 10 paired plots (0.785 m2), bare and straw covered (2 t ha−1). The experiment was carried out in maize cultivation (Blagorodovac, Croatia) established on Stagnosols on slopes. Measurements were conducted during April (bare soil, after seeding), May (five-leaves stage), and June (intensive vegetative growth) making 60 rainfall simulations in total. Straw reduced soil and water losses significantly. The highest water, sediment loss, and sediment concentrations were identified in tillage plots during May. Straw addition resulted in delayed ponding (for 7%, 63%, and 50% during April, May and June, respectively) and runoff generation (for 37%, 32%, and 18% during April, May and June, respectively). Compared with the straw-mulched plot, tillage and bare soil increased water loss by 349%. Maize development reduced the difference between bare and straw-mulched plots. During May and June, bare plots increase water loss by 92% and 95%, respectively. The straw mulch reduced raindrop kinetic energy and sediment detachment from 9, 6, and 5 magnitude orders in April, May, and June, respectively. Overall, the straw mulch was revealed to be a highly efficient nature-based solution for soil conservation and maize cultivation protection. [ABSTRACT FROM AUTHOR]

Nutrient leaching from agricultural soils presents an economic loss for farmers and can degrade the quality of the surrounding environment. Thus, leachates from 18 in situ wick lysimeters, installed at 40 cm soil depth at the vineyard hilltop, backslope, and footslope intra- and inter-row area (SUPREHILL Critical Zone Observatory, Croatia) were collected monthly over two years and analyzed for major plant nutrient ions. Our objectives were to quantify nutrient losses via leaching from the hilltop towards the backslope and to the footslope, and to compare leaching from vine plant rows (intra-row) with grassed areas between vine rows (inter-row). We found that the concentrations of nitrate, orthophosphate, and potassium were significantly higher in leachates collected at the footslope as compared to the hilltop and backslope only at intra- and not at inter-row positions, while ammonium was independent of the slope and row positions. The vineyard intra-row is identified as the probable spatial origin of nutrient leaching along the slope, thus confirming spatially different contributions of overall hillslope to major plant nutrients leaching. The experimental field scheme used in this study, which separately analyses vineyard intra- and inter-row, was confirmed to be an adequate approach for optimizing vineyard management practices. [ABSTRACT FROM AUTHOR]

Natural landscapes in the Mediterranean ecosystem have experienced extensive changes over the last two centuries due to wildfire activity. Resulting interactions between climatic warming, vegetation species, soil natural, and meteorological condition before and after a wildfire create substantial abrupt landscape alterations. This study investigates the evolution (2 days, 3, 6, 9, and 12 months after a fire) of topsoil (0–5 cm) chemical properties in burned Cambisols (Zadar County, Croatia) with respect to different wildfire severities (HS—high severity, MS—medium severity, C—unburned) and vegetation species (Quercus pubescens Willd. and Juniperus communis L.). Soil pH, electrical conductivity (EC), calcium carbonates (CaCO3), total organic carbon (TOC), total nitrogen (TN), total sulphur (TS), copper (Cu) and zinc (Zn) were significantly higher in HS than in MS and C. Total soil potassium (TK), Fe and Ni were significantly higher in C than in HS. The increase of TOC and TN was more pronounced in Quercus p. than Juniperus c., especially in the first three months. Soil pH, EC, CaCO3, TOC, TN, and TS were most affected by wildfire severity. The distinction between C, MS and HS categories was less visible 9 and 12 months post-fire, indicating the start of the recovery of the soil system. Post-fire management and temporal recovery of the soil system should consider the obvious difference in soil disturbance under HS and MS between vegetation species. [ABSTRACT FROM AUTHOR]

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There is a lack of information in the rural Mediterranean area about agricultural pile burning impacts on soil nitrogen (N) dynamic and the N loss. Therefore, this research aims to study the impacts of moderate (MS), and high (HS) severity burn on N transformation and N losses, compared to an unburned (C) during the first year. The experimental plots (10 m2) were established in Croatia (43°58′ N 15°31′ E), in a slope ~18°, with a southwest exposition. Five days after the burn, C treatment had a significantly higher total N (TN) than MS and HS. Generally, the runoff was significantly different between burned and C treatments. Sediment yield, concentrations, and TN loss were significantly higher in MS than in C treatment. The concentrations of ammonium (NH4-N) and nitrate (NO3-N) in the runoff, and their losses were higher in burn treatments than in C treatment. These values were high in the first three months after burn, although the peaks in later periods correspond to extreme rainfall events. Principal component analysis showed that sediment yield was associated with sediment concentration, runoff, and TN loss (Factor 1). In addition, rainfall amount and intensity were inversely related to NH4-N concentration and losses (Factor 2). The NO3-N concentration was positively related to NO3-N losses. Overall, MS treatment had severe effects on N loss and, sediment yield can be used as an indicator of soil degradation after pile burns. [ABSTRACT FROM AUTHOR]

Intensive agricultural practices increase agrochemical pollution, particularly nitrogen (N) based fertilizers, which present an environmental risk. This study aims to evaluate long-term (2009–2020) data on soil water regime and nitrate dynamics at an agricultural experimental site on fine-textured soils and to better understand the implications of N management in relation to groundwater pollution. The field site is located in the Biđ field (eastern Croatia), in the proximity of the Sava river. Zero-tension lysimeters were installed at six selected locations. Lysimeters were used to monitor the water regime, i.e., outflows in which nitrate concentration was measured, while additional soil-water samples were collected via 4 and 15-meter-deep monitoring wells. Soil hydraulic parameters were estimated by combining the laboratory measurements, and estimation in RETC software. Water regime and nitrate leaching in lysimeters were simulated using HYDRUS-1D for each year to allow crop rotation and to evaluate their effects individually. The HYDRUS-1D model successfully reproduced lysimeter outflows and nitrate dynamics, which was confirmed with high R2 values (water: 93% above 0.7, and nitrate: 73% above 0.7) indicating the good performance of the model simulating nitrification chain reactions. Principal component analysis (PCA) was performed to identify the relationships among all soil properties and environmental characteristics. The results showed the complex interaction of soil hydraulic properties, precipitation patterns, plant uptake, and N application. All locations have a decreasing trend of nitrate leaching over the investigation period. Most of the lysimeter outflows and elevated nitrate concentrations were connected to the wet period of the year when the soil was saturated, and evapotranspiration was low. The results of this study show that it is important to optimize N fertilizer applications for each particular environmental condition to reduce nitrate loss. The study indicates the importance of long-term field studies, key for agro-hydrological modeling and the improvement of agricultural practices. [Display omitted] • Interaction of soil hydraulic parameters, rainfall, crops, and nitrogen is presented. • HYDRUS-1D successfully reproduced long-term lysimeter outflows and nitrate dynamics. • Field conditions and evapotranspiration affected outflows and nitrate concentrations. • Long-term field data is key for modeling and improvement of agricultural practices. [ABSTRACT FROM AUTHOR]

• Lysimeters provided the data on soil water fluxes for model validation. • Soil hydraulic properties were optimized using Shuffled Complex Evolution algorithm. • Mutual Information suggests a concurrent role of the hydrological processes. • Significance of the upward fluxes was identified during shallow groundwater levels. This study aims to explain complex vadose zone hydrology of fine-textured (gley) agricultural soils influenced by a shallow and dynamic groundwater (GW) levels. The field site was located in the Biđ field (Eastern Croatia), where a detailed soil survey was performed. The simulations included a three-year period (2016–2018) at four locations. Soil hydraulic parameters (SHP) were estimated based on variables determined in the laboratory, while soil water flow was monitored using in-field zero-tension lysimeters. Piezometers were installed and used to monitor daily oscillations of groundwater levels (average depth to GW 2.2 m), while data from nearby Sava River was monitored. Unsaturated flow and water regime assessment was performed using HYDRUS-1D numerical modeling. Additional SHP optimization of van Genuchten-Mualem parameters (α and n) was performed using Shuffled Complex Evolution algorithm (SCE). The autocorrelation analysis was used to detect patterns in the precipitation, GW, and river level time series, while the Mutual Information (MI) was used to estimate the codependence of the processes in unsaturated zone and the main hydrological events. The model successfully (R2 0.72 – 0.94) reproduced measured lysimeters outflows. The outflows from lysimeters were connected to precipitation patterns, transpiration intensity, and soil moisture content influenced by the shallow water table. Comparable MI values obtained for precipitation, GW, and river level suggest a concurrent role of these parameters in the unsaturated flow dynamics. The relationship between upward flux/water storage change into the domain, and transpiration/growth stages, suggests a strong connection between the water fluxes and the root water uptake. Results confirm the importance of GW for the agricultural production due to the major influence on upper soil layer moisture. [ABSTRACT FROM AUTHOR]

Burning slash piles is common in the Mediterranean regions to manage the unwanted biomass. This work aims to study the effect of two experimental pile burns ((moderate (MS) and high severity (HS)) conducted in Croatia on vegetation and soil compared to an unburned treatment (UB). We studied vegetation cover (VC), soil water repellency (SWR), mean weight diameter (MWD), water-stable aggregates (WSA), pH, electrical conductivity (EC), soil organic matter (SOM), the total content of calcium (Ca), aluminium (Al), silicon (Si), and iron (Fe), available phosphorus (P 2 O 5 ) and potassium (K 2 O). The impacts of the burn were studied 5 days after burning (DAB), 3, 8, 12, and 15 months after burn (MAB). The results showed that VC was significantly higher in UB than in MS 5 DAB-15MAB. SWR was significantly higher in the smallest soil fractions (<0.25 mm) in burn treatments than in the UB on 5 DAB and 3 MAB. Also, 3 MAB, MWD and WSA were significantly lower in the burned treatments than in UB. pH was significantly higher in HS than in UB 3, 12 and 15 MAB, while EC was significantly higher in HS than in UB, 5 DAB, 3 and 15 MAB. MS and HS did not significantly affect SOM content. Total Ca was significantly higher in burn treatments than in UB 5 DAB-12 MAB. Total Al and Si were significantly higher in UB than in HS (5 DAB-15MAB), while total Fe was significantly higher in UB than in HS 5 DAB, and 8-15 MAB. P 2 O 5 was significantly higher in HS than in UB from 3 to 15 MAB, while K 2 O was significantly higher in MS and HS than in UB 5 DAB. Soils need more time to recover from pile burning disturbance, likely due to the soil poor natural conditions, therefore this type of management is detrimental., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)