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Abstract: The Xiaotian-Mozitan fault (XMF) located north of the Dabie orogenic belt separates the North Dabie complex to the south from the Beihuaiyang low-grade metamorphic rocks to the north. It comprises several NW-striking ductile shear zones and brittle faults. The brittle faults obviously overprinted on the ductile shear zones and promoted the development of the volcanic basins in early Cretaceous to the north, which suggests that the brittle faults were normal faults formed in early Cretaceous during doming of the Dabie orogenic belt. The ductile shear zone superposed on the north Dabie gray gneiss, and it is an important channel where the Dabie HP–UHP rocks exhumed. For obtaining new structural constraint on exhumation of the HP–UHP rocks, we present here experimental results on the microstructure, quartz C-axis fabrics and the microprobe analyses of phengite. The ductile shear zone was determined to be formed at a temperature of 600–650°C and pressure of 1.1 GPa by the mineral deformation, microprobe analyses and geobarometry of Si-in-phengite of the mylonite, the results suggest that the mylonite now exposed on the surface experienced an upper amphibolite-facies metamorphism in the lower crust. The mineral stretching lineation varies from horizontal in the east segment to sub-dip in the west. Shear sense indicators from outcrop and thin sections of orientated specimen and quartz C-axis fabrics suggest that the XMF is a sinistral normal fault. The kinematics analysis of the ductile shear zone indicates that the exhumation of Dabie HP–UHP rocks is the results of a SE-directed extrusion and an anticlockwise rotation around its eastern pivot simultaneously. [Copyright &y& Elsevier]