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The implementation of analytical techniques able to certify food quality and origin in a fast and non-destructive way is becoming a widespread need in the agri-food sector. Among the physical non-destructive techniques, X-ray fluorescence (XRF) spectrometry is often used to analyze the elemental composition of biological samples. In this study, X-ray fluorescence (XRF) elemental profiles were measured on tomato samples belonging to different geographical areas in Sicily (Italy). The purpose of this investigation was aiming to establish a protocol for in-situ measurement and analysis able to provide quality assessment and traceability of PGI agri-food products, specifically sustaining health safety and self qualifying bio-chemical signature. In detail, sampling was performed in one of the most tomato productive area of south-eastern Sicily (Pachino district), characterised by a relative higher amount of Organic Carbon and Cation Exchange Capacity, and compared with samples from other growing areas of Sicily, falling in Ragusa province and Mt. Etna region. Experimental data were analyzed in the framework of multivariate analysis by using principal component analysis and further validated by discriminant analysis. The results show the presence of specific elemental signatures associated to several characterizing elements. This methodology establishes the possibility to disentangle a clear fingerprint pattern associated to the geographical origin of an agri-food product. [ABSTRACT FROM AUTHOR]

This study provides experimental insights into the optimization of alkali-activated materials (AAMs) carried out in situ at the restoration site of Monreale Cathedral, Italy. Volcanic ash from Mt. Etna volcano (Italy) was used as a precursor to obtain AAMs. Standard and modified pastes with a small amount of slaked lime paste were compared in terms of setting time, rheology, mineralogy, chemical morphology, and mechanical performance. The modified pastes exhibited a faster setting time, superior mechanical strength and rheological properties. Mineralogically, no difference was observed between the two pastes for the small amount of slaked lime paste added very close to the detectable limit (<2 wt%). Moreover, its addition causes slight differences in the morphology of the gel without changing the chemical composition of the Na 2 O–CaO–Al 2 O 3 –SiO 2 –H 2 O ((N,C)-A-S-H)) type. The results obtained may be useful for the development and optimization of building materials (especially for restoration purposes) where appropriate physico-mechanical performance is required. [Display omitted] [ABSTRACT FROM AUTHOR]

The structural properties of geopolymers based on locally available volcanic feedstocks were here investigated in the optics of the development of sustainable non-structural building materials. Geopolymer binders and mortars based on two volcanic pyroclastic residues from Mt. Etna (ejected ash and a paleosoil, named "ghiara") were studied to assess the effects of natural weathering. The strength and durability of the resultant products were examined before and after six months of outdoor exposure by comparing ultrasound pulse velocity (UPV), specific weight, Brazilian Disk test (BD) and Digital Image Correlation (DIC) together with Dynamic Vapour Sorption (DVS) results. DVS data were also compared to those of pure salts (e.g. sulphates and carbonates) commonly occurring in geopolymers as efflorescences. The results obtained on unexposed and exposed samples and the relationship between the moisture transportation, efflorescence development, and structure degradation have shown a better response of the volcanic ash-based geopolymers to weathering in the hot summer Mediterranean climate zone than ghiara-based products. The latter are more affected by exposure conditions as revealed by the decrease of UPV, the influence of efflorescences on moisture adsorption-desorption curves and the consequent worsening of mechanical performances. The correlation between UPV and DVS applied for the first time to the study of volcanic precursors-based geopolymers exposed to natural weathering has proven to be an effective and useful tool for assessing the durability of materials. [ABSTRACT FROM AUTHOR]

A combination of conventional and un-conventional methods is here used to assess the physical-mechanical properties of some alkaline activated pastes and mortars. The latter were purposely synthetized by using Etna ashes as precursor, whose suitability in the alkaline activation process has been ascertained by previous studies. Additionally, the potential reuse of the huge quantities of pyroclastic deposits released into the atmosphere during explosive volcanic eruptions represents an ambitious challenge for the local communities, other than being part of the "Ecological transition" topic promoted by the European Community. The physical-mechanical characterization of the experimental materials has been carried out by using: capillary water absorption test, infrared thermography (IRT), accelerated ageing test by salt mist, uniaxial compressive strength and drilling resistance test. The data obtained for pastes and mortars have been compared to each other and also with traditional materials commonly used in the building sector. The experimental results displayed a strong correlation between the rate of heat dispersion and the microstructure of the samples. In detail, the pastes show a more compact structure than mortars, which is responsible for a slower heat release and a lower capillary water absorption rate, as well as a better mechanical performance. IRT, used for the first time on these materials, revealed a high potential in providing feedback on other physical-mechanical features of alkali activated materials, commonly derived by using destructive methods. [ABSTRACT FROM AUTHOR]

[Display omitted] • Evaluation of activating solution influence on high temperature resistance in AAMs. • Higher availability of silicon and aluminum and better feasibility of the pastes. • Monitoring formation of Si-O-Si and Si-O-Ca networks. • Positive influence of the new crystallizations on mechanical resistance after 1000 °C. • Densification behavior of K sample contrary to the melting of that Na. Thermal performances at 1000 °C of volcanic ash-based alkali-activated materials by both sodium or potassium solutions have been tested. Once defined the feasibility for the potassium set, a multidisciplinary characterization including spectroscopic, thermal, mechanical, diffractometric before and after treatment and dilatometric analyses was applied. The formation kinetics of different networks was evaluated. A correlation between the high mechanical properties and the least amount of water was observed in non-treated samples. Treated samples at 1000 °C showed higher compressive strengths due to the crystallization of wollastonite, leucite and nepheline. Thermal stability was observed increased with the solid content in the potassium-based formulations. [ABSTRACT FROM AUTHOR]

• Volcanic-ash AA mortars, have been tested on damaged mosaics of Monreale Cathedral. • Bedding AA mortars have been applied for the reposition of detached tesserae. • Replicates of the mosaic decorations engraving and painting AA mortars were tested. • Pre-casted colored alkaline activated mortars have been created. • Colorimetric differences between original tesserae and new AAMs have been evaluated. This paper describes for the first time a case-study regarding the applicability of alkali activated mortars based on volcanic-ash (Mt. Etna) directly on-site on a UNESCO Heritage site known worldwide, the Monreale Cathedral (Sicily, Italy). In the perspective of "Advanced Green Materials for Cultural Heritage" project, small damaged areas of the mosaics were selected to test the application of bedding mortars for the filling of lacunae and the repositioning of detached original tesserae , as well as the replication of the mosaic decorations by engraving and painting on the finishing mortars or by the realization of new pre-casted tesserae. Both the critical aspects of preparation and the steps taken to improve operative conditions (e.g. use of Ca-additive) have been highlighted. The monitoring of results over time confirms the intervention's success, representing in this way a pioneering on-site cultural heritage application of these materials. [ABSTRACT FROM AUTHOR]

• Reuse of volcanic residuals from Mt. Etna was proposed via alkali-activation. • Alkali-activated materials were exposed to the environment for six months. • Mechanical strength, vapour sorption, salts formation, visual aspect were tested. • The exposed materials showed a good stability to weathering. • Volcanic precursors-based binders and mortars can be used for restoration purposes. Volcanic pyroclastic residues from Mt. Etna have been recently used to produce alkali activated materials to be employed in the restoration of the ancient buildings of the Etnean area. With the aim of preliminarily testing the durability of these products, binders and mortars have been exposed outdoors for six months. The characterization was achieved by a multi-analytical approach to determine the effect of the weathering; variations were evaluated in terms of composition, mechanical properties, dynamic vapour sorption, and visual aspect before and after exposure. The results show that both alkali activated binders and mortars are barely affected by atmospheric exposure. [ABSTRACT FROM AUTHOR]

• A complex mineralogical assemblage was revealed. • Fe(II) and Fe(III) species were detected in a variety of coordination environments. • The Fe oxidation state and speciation is not affected by water. • Significant changes were evidenced as a function of particle granulometry. • Ashes surface features may prevent direct exposure to mobile and toxic Fe(II). Volcanic ashes particles are subjected to substantial modification during explosive eruptions. The mineralogical and compositional changes have important consequences on the environment and human health. Nevertheless, the relationship between the speciation of iron (Fe) and the mineralogical composition and particle granulometry of the ashes, along with their interaction with water, are largely unknown. In particular, the Fe oxidation state and the possible formation of new Fe-bearing phases in presence of S, Cl, and F in the plume are key points to assess the impact of the ashes. Fragmental material ejected during volcanic activity (tephra) in 2013, was collected on the Mt. Etna (Italy) and investigated using a multi-technique approach that included conventional Electron Paramagnetic Resonance (EPR), high field EPR (HFEPR), EchoEPR, and Fe K-edge X-ray Absorption Spectroscopy (XAS). These element-selective techniques allowed obtaining a detailed information on the oxidation state and coordination environment of Fe, and of its speciation in the ash samples as a function of the granulometry. A complex mineralogical assemblage, consisting of variable amounts of nanometric crystalline Fe inclusions in a glass matrix, and of Fe-oxides and Fe-sulfur phases was revealed. A risk assessment of the ashes is attempted. [ABSTRACT FROM AUTHOR]