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An increase in groundwater chloride concentrations was first reported 20 years ago in Finland. This discovery coincided with a sharp rise in the rate of road-salt application -- the annual amount of NaCl consumed had increased from 50 t a-1 in the late 1970s to 140 t a-1 10 years later. To reverse these trends, research and development projects aimed at the reduced application of sodium chloride and improved protection of valuable groundwater resources were initiated. Several innovations, methods and practices, including the use of brine and pre-wetting, preventive anti-icing, advanced devices for salt spreading, utilization of meteorological online data and rewarding the private contractors for accurate, timely and scarce anti- and deicing, has resulted in a decline of 35% in the amount of salt applied since the early 1990s. Research on the fate and behavior of road salt in groundwater aquifers, predictions of future chloride concentrations and risk assessment have guided the risk management actions taken. Campaigns with reduced salting, use of geomembranes and recent progress on alternative deicing agents provide attractive options for further work towards sound deicing at valuable groundwater areas. [ABSTRACT FROM AUTHOR]

Phenolic acids, flavonoids, proanthocyanidins, and ellagitannins are polyphenols that may have beneficial effects on human health and provide protection against chronic diseases. To date, limited data exist on quantitative intake of polyphenols. The aims of this study were to estimate the quantitative intakes of polyphenols by using analyzed concentrations together with individual food consumption records and to determine major dietary sources. Analyzed concentrations of phenolic acids, anthocyanidins, and other flavonoids, proanthocyanidins, and ellagitannins (44 total polyphenol compounds) were entered into the national food composition database, Fineli. The absolute intakes of the polyphenols and the corresponding food sources were calculated on the basis of 48-h dietary recalls of 2007 Finnish adults. The mean total intake of polyphenols was 863 ± 415 mg/d. Phenolic acids comprised the dominant group of polyphenols (75% of total intake) followed by proanthocyanidins 114%) and anthocyanidins and other flavonoids (10%). Due to their high consumption and high concentrations of phenolic acids, coffee and cereals were the main contributors to total polyphenol intake. Berries and berry products were the main source for anthocyanidins, ellagitannins, and proanthocyanidins, and fruits were the main source for flavonols, flavones, and flavanones. The results give additional support to the recommendations for a varied diet with fruits, berries, cereals, and vegetables. [ABSTRACT FROM AUTHOR]

• Specific waste water volumes and water consumption rates provided for 195 industries. • Differences up to an order of magnitude revealed in figures produced by global models. • 'Water use' suggested to be preferred to 'water consumption' as a general indicator. • Novel contributions to transparency and data quality assessment of water accounts. Sustainable exploitation of water resources is an essential global challenge and several approaches have been applied for studying water flows through economies. However, the applicability, accuracy, and reliability of all approaches is generally constrained by the lack of real data, especially when analyzing the return water flows from the economy back into the environment and when estimating the volume of consumptive water use. Sector-specific water consumption volumes reported in the literature are mainly based on modeled figures of unknown uncertainty. In this paper we demonstrate how a reliable and disaggregated national return water flow accountancy, including industry-specific consumption rates, can be compiled, and how the quality of the produced data can be assessed and documented. The introduced protocol for data quality assessment in return flow analysis is a transparent system that classifies industry-specific data representativeness into quality categories and hence allows the estimation of data reliability and the identification of important development areas. Furthermore, we compare the results of the real-data-based accountancy to modeled figures in the existing literature and widely applied modeling tools, and show that the differences are extremely large. We also analyze the potential reasons behind these differences. This study clearly illustrates the need for real data in water accountings and in various water footprint studies. We propose that water use rates based on real data should be used as an indicator of pressures exerted on water resources by national economies. We furthermore suggest that water consumption rates could be considered as an additional indicator in small-scale regional studies, where case-specific, reliable data on return flows and water resources are available. [ABSTRACT FROM AUTHOR]

A novel approach for the in situ bioremediation of acidified, nitrate-contaminated groundwater was developed. Ethanol was introduced into the groundwater to enhance the activity of intrinsic denitrifying micro-organisms. Infiltration of the carbon source was made via an infiltration gallery constructed in the unsaturated zone to avoid clogging problems and to allow wider distribution of ethanol in the groundwater. The changes in the groundwater geochemistry and soil gas composition were monitored at the site to evaluate the efficiencies of the infiltration system and nitrate removal. Moreover, the impact of pH and ethanol addition on the denitrification rate was studied in laboratory. A reduction of 95% was achieved in the groundwater nitrate concentrations during the study. Neither clogging problems nor inefficient introduction of ethanol into the saturated zone were observed. Most crucial to the denitrifying communities was pH, values above 6 were required for efficient denitrification., (Copyright © 2014 Elsevier Ltd. All rights reserved.)

Numerous in vitro and in vivo studies have suggested that dietary anthocyanins and ellagitannins or ellagic acid might have beneficial health effects. Epidemiological evidence on the disease-preventing potential of these polyphenols is lacking, due to the absence of reliable data on their contents in foods. In this study was analyzed the content of anthocyanins and ellagitannins (as ellagic acid equivalents after acid hydrolysis) in foods consumed in Finland, including berries, fruits, vegetables, and processed products, using high-performance liquid chromatographic (HPLC) methods. Anthocyanins were detected in 41 of 54 selected food items. The total anthocyanin content varied in berries from 1 to 611 mg/100 g, in fruits from 2 to 66 mg/100 g, and in vegetables from 3 to 75 mg/100 g of fresh weight as the weight of the aglycone. Ellagitannins were screened in 33 food items, but were detected only in 5 species of berries, that is, in cloudberry, raspberry, rose hip, strawberry, and sea buckthorn, the content ranging from 1 to 330 mg/100 g. The results underscore the superiority of berries, especially dark blue or red berries, as excellent sources of anthocyanins and certain berries of the Rosaceae family as the major source of ellagitannins in the Finnish diet.

This paper presents results from a lysimeter experiment on the fate of potassium formate, an alternative deicing agent. The experiment was performed through the winter and spring to identify any thermal sensitivity in the transport and biodegradation of formate in the lysimeter. Ninety-eight percent of the total quantity of formate applied was degraded while percolating through the 1.7-m-thick unsaturated sand layer within the lysimeter. Concomitantly, the bicarbonate concentration of the percolating water increased. The low concentrations of nitrogen (0.02 mg L(-1)) and phosphorous (<0.002 mg L(-1)) in the percolated water, however, potentially limited microbial activity. During the study period, 99% of the applied potassium was retained in the lysimeter, and the ion exchange between the potassium and a variety of monovalent and divalent ions was assumed to be responsible for the leaching of barium, calcium, magnesium, and sodium from the soil material. Except for manganese, the concentrations of the studied metals in the percolated water did not exceed the threshold values set for drinking water by the Council of the European Union. By contrast, the application of potassium formate had a detrimental effect on the vegetation on the lysimeter. To conclude, formate was effectively degraded in the sandy lysimeter and its application did not cause major undesirable changes in the quality of the percolating water. Further research at field scale is, however, needed for instance on the biodegradation of potassium formate and on its impacts on roadside vegetation.