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Ecological hazards such as floods, drought and poor water quality remain notable disparaging natural catastrophes of climate variability in West Africa. Associated hazard manifestation is an amalgamation of various factors, which require enhanced knowledge of its spatio-temporal extent. This work aims at the identification and mapping of areas prone to ecological vulnerabilities in the Densu River Basin of Ghana. This research utilized a combination of Analytical Hierarchical Process (AHP) and multicriteria methods (MCM) using dataset such as land use land cover, type of soil, slope, drainage density, rainfall variability and the community distribution in the basin, using Geospatial Technology. Vulnerability mapping models were developed for flooding, drought and surface water quality. The resulting analysis revealed that about 15% of the basin was highly vulnerable to flooding, about 1% was prone to drought and 6% was prone to poor surface water quality. It was revealed that the southernmost part of the basin was susceptible to flooding whilst communities along the tributaries of the Densu river were predisposed to flooding and poor water quality. The study further displayed the extent of vulnerability of the communities within the Densu basin. Uniquely, a combination of AHP and MCM was successfully used to map the vulnerability of a river basin. Therefore, it is now possible to extend the procedures to other river basins for the development of effective mitigating strategies for future hazards. [ABSTRACT FROM AUTHOR]