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During the Ediacaran–Cambrian transition, a series of stratal continuous and well-preserved siliceous rock and phosphorite assemblages developed in Qingzhen, Guizhou Province, China, facilitating research on the biological evolution, marine chemistry, and palaeoecological environment of this period. Therefore, we investigated the paleontology, trace and rare earth elements, total organic carbon, total sulfur content, and Zn isotopes of the phosphorus-bearing rock series in the Taozichong Formation of the Cambrian period in Qingzhen. Geochemical analysis reveals that the sedimentary rocks in this area were formed in the oxygen-rich seawater environment and were not affected by high-temperature hydrothermal activity. The upwelling ocean current provided abundant rare earth elements and other nutrient elements, as well as conditions for the prosperity of biota in Qingzhen. In addition, the δ66Zn value (−0.21‰–0.41‰ range and 0.17‰ mean) in the Qingzhen phosphorous rock series was much lower than that in seawater, indicating a strong level of biological productivity. The variation trend of δ13C, δ18O, and δ66Zn exhibited four stages and three obvious drift events. The results suggest that climate change during this period led to the intermittent flourishing and extinction of organisms, which triggered the negative drift of δ13C and δ18O in the ocean, resulting in a coordinated response of δ66Zn. The unique ecological environment of the Taozichong Formation in Qingzhen also provides favorable conditions for the population continuation of Ediacaran-type benthic soft-bodied metazoon dominated by discoid fossils, Shaanxilithes, worm fossils, and sponge fossils in the Cambrian strata, as well as participation in the global biological explosion events. The study area provides new insights for rebuilding the global Ediacaran–Cambrian ecosystem during the transition period. [ABSTRACT FROM AUTHOR]

Karst bauxite is a major source of aluminum and contains high concentrations of trace elements such as Li, Ga, Sc, and rare earth elements (REEs). It is regarded as a potential non-conventional REE source due to the increasing demand for REEs. This study provides new mineralogical and geochemical evidence of a Lindai bauxite deposit in central Guizhou Province, aiming to analyze the genesis of REE minerals and reveal the forms of REEs occurring in these deposits. The results indicate that a large number of detrital and authigenic rare-earth phosphate minerals, including monazite and xenotime, were identified. In terms of their genesis, the authigenic monazite was mainly precipitated under alkaline and reducing conditions, whereas the authigenic xenotime was formed in acidic and reducing conditions. The mineralogical evidence detected by scanning electron microscopy with energy dispersive spectrometry (SEM-EDS) and a TESCAN Integrated Mineral Analyzer (TIMA) suggests that the REEs in the Lindai bauxite exhibit multiple forms, including rare-earth phosphate minerals (monazite and xenotime) and REE scavenging by hematite and anatase phases. Among them, the anatase controls some LREE (such as La, Ce, and Pr) distributions in addition to monazite, whereas the hematite also controls relatively large amounts of Sm, Eu, and HREE (such as Gd, Tb, Dy, Ho, Er, Tm, and Lu) distributions. According to the calculation of the percentage of REE-bearing mineral phases obtained by a TIMA analysis, REE scavenging by hematite accounted for 93.28% of all forms of REEs, REE scavenging by anatase accounted for 5.88%, monazite accounted for 0.67%, and xenotime accounted for 0.17%. This study provides new evidence of the forms of REEs occurring in Carboniferous karst bauxite in central Guizhou Province. [ABSTRACT FROM AUTHOR]

The Zunyi manganese deposits, which formed during the Middle to Late Permian period and are located in northern Guizhou and adjacent areas, are the core area of a series of large‐medium scale manganese enrichment minerogenesis in the southern margin and interior of the Yangtze platform, Southern China. This study reports the universal enrichment of rare earth elements (REEs) in Zunyi manganese deposits and examines the enrichment characteristics, metallogenic environment and genesis of REEs. The manganese ore bodies present stratiform or stratoid in shape, hosted in the silicon–mud–limestones of the Late Permian Maokou Formation. The manganese ores generally present lamellar, massive, banded and brecciated structures, and mainly consist of rhodochrosite, ropperite, tetalite, capillitite, as well as contains paragenetic gangue minerals including pyrite, chalcopyrite, rutile, barite, tuffaceous clay rock, etc. The manganese ores have higher ΣREE contents range from 158 to 1138.9 ppm (average 509.54 ppm). In addition, the ΣREE contents of tuffaceous clay rock in ore beds vary from 1032.2 to 1824.5 ppm (average 1396.42 ppm). The REEs from manganese deposits are characterized by La, Ce, Nd and Y enriched, and existing in the form of independent minerals (e.g., monazite and xenotime), indicating Zunyi manganese deposits enriched in light rare earth elements (LREE). The Ceanom ratios (average –0.13) and lithofacies and paleogeography characteristics indicate that Zunyi manganese deposits were formed in a weak oxidation‐reduction environment. The (La/Yb)ch, Y/Ho, (La/Nd)N, (Dy/Yb)N, Ce/Ce* and Eu/Eu* values of samples from the Zunyi manganese deposits are 5.53–56.92, 18–39, 1.42–3.15, 0.55–2.20, 0.21–1.76 and 0.48–0.86, respectively, indicating a hydrothermal origin for the manganese mineralization and REEs enrichment. The (δ13CV‐PDB (−0.54 to −18.1%) and (δ18OSMOW (21.6 to 26.0%) characteristics of manganese ores reveal a mixed source of magmatic and organic matter. Moreover, the manganese ore, tuffaceous clay rock and Emeishan basalt have extremely similar REE fractionation characteristic, suggesting REEs enrichment and manganese mineralization have been mainly origin from hydrothermal fluids. [ABSTRACT FROM AUTHOR]

The Permian was a key period of manganese deposition in Southern China, as evidenced by a series of large-to medium-scale manganese deposits along the margin of the Yangtze Block. This study characterizes representative examples that occur in late Middle Permian silicon–mud–limestones in Zunyi and adjacent areas and examines their implications for manganese deposit genesis and sedimentary environment. The manganese deposits are typical carbonates deposits, with the main manganese-bearing mineral being rhodochrosite, followed by calcimangite, capillitite, manganocalcite, and kutnohorite in decreasing abundance. The ore bodies, hosted in the black shale series of the Late Permian Maokou Formation, are mainly stratiform or stratoid in shape, usually have lamellar, massive, banded, fragmental, or pisolitic structures, and contain paragenetic gangue minerals including rutile, barite, pyrite, and chalcopyrite, etc . These features are characteristic of hydrothermal exhalative sedimentary deposits, implying that this was their mode of genesis. The Mn-ores have higher Co, V, Ni, Cu, Sr and total REE content, lower Y/Ho ratios, and characterized by the Fe–Mn–(Cu + Co + Ni) × 10, lgTh vs. lgU, P 2 O 5 vs. Y and Fe/Ti vs. Al/(Al + Fe + Mn) diagrams strongly suggest hydrothermal activity during manganese mineralization. The Th/U, V/Cr and V/(V + Ni) ratios of samples from the Zunyi manganese deposits are 0.38–3.27, 3.11–24.00 and 0.38–0.99, respectively, indicating the sedimentary environment was weakly oxidizing to reducing condition. [ABSTRACT FROM AUTHOR]

Bedded barite deposits are found in Cambrian and Devonian strata in China. In this paper, we report the occurrence of Late Paleozoic methane seeps from bedded barite in one of the largest barite deposits in China. The ore bodies are stratiform and lenticular in shape and are hosted within Upper Devonian cherts. The barite deposits usually have laminar, banded, fragmental, massive and rosette textures, and radial and spheroidal structures were observed in the barite ores. Nodular limestones are associated with the barite deposits; they consist of clotted micrites and framboidal pyrites. The internal structure of framboidal pyrite is simple, in which the sun-flower structure has been observed, similar to modern seep carbonates. The δ 13 C V-PDB values range from − 8.82‰ to − 10.27‰, and δ 18 O V-PDB ranges from − 8.10‰ to − 8.20‰ in Xiyahe and from + 0.03‰ to − 3.31‰ in Luocheng. The 13 C depletion suggests that these carbonates formed in a methane seep through the anaerobic oxidation of methane (AOM). This evidence lends strong support to the interpretation that methane hydrate contributed to the barite deposition. In addition, the δ 13 C V-PDB values decrease gradually from Xiyahe to Luocheng, which indicates the gradually weakening strength of the methane seep activities. The δ 30 Si NBS-28 values of the cherts range from − 0.3‰ to + 0.5‰, except for two samples (LJ-24: δ 30 Si NBS-28 values = + 0.9‰; ZL18: δ 30 Si NBS-28 values = + 1.1‰). The lowest δ 30 Si NBS-28 values reflect silicon derived from hydrothermal fluids ascribed to intense tectonic activity, which consequently caused the rapid maturity of hydrocarbons. The 87 Sr/ 86 Sr values ( 87 Sr/ 86 Sr = 0.70863–0.70898, avg. 0.70877; n = 11) of barite are higher than the average value of contemporary seawater, showing that hydrothermal processes played a minor role in barite mineralization. [ABSTRACT FROM AUTHOR]

In the study of the phosphate-bearing stratum at the bottom of the Cambrian system, the authors found that there occurred carbon isotope negative anomalies in the Taozichong section phosphate-bearing stratum in Qingzhen, Guizhou Province; they can be correspondingly compared with other synsedimentary carbon isotope negative anomalies both at home and abroad. The results showed that there occurred three negative anomalies of carbon isotopes in the Neoproterozoic-Early Cambrian Taozichong Formation, indicating that the temporal palaeo-oceanographical environment changed significantly, in which there happened two times of intensive carbon isotope variation, corresponding to creature extinction. Meanwhile, it is believed that the carbon isotope negative anomalies in phosphorites were caused by the ascending water mass of ocean current with the negative carbon isotopic composition of deep-ocean hydrothermal deposits. [ABSTRACT FROM AUTHOR]

The evolution of the global sulfur isotope curve was plotted based on the δ 34S values of evaporates resultant from oceanic evaporation. In the long period of geological history the δ 34S values showed obvious peaks for three times during the process of ancient oceans’ sulfur isotope evolution, namely the Early Cambrian (+30‰), the Late Devonian (+25‰) and the Permian-Triassic transition interval (+17‰), but the causes of the abnormal rise of sulfur isotopic values during the geological period are still in question. In this paper, 18 samples collected from a large Devonian barite deposit from Zhenning County were analyzed to determine their δ 34S values, revealing that the 18 samples have very high δ 34S values (δ 34S=41.88‰–+68.39‰), with an average close to 56.30‰, which are higher than the isotopic values of contemporary sulfates (+17‰–+25‰). A comparative analysis was conducted of the emerging of high δ 34S barite deposits (from Cambrian and Devonian) and the δ 34S variation curves of the ancient oceans. The results indicate that the time when the obvious peaks of δ 34S values appeared and the time of massive sedimentation of high δ 34S barite deposits are very close to each other, which, in our opinion, is not a coincidence. There may exist some correlations between the sulfur isotope evolution of ancient oceans during the diverse periods of geological history and the massive sedimentation of high δ 34S barite deposits. Therefore, it is inferred that perhaps it was the massive sedimentation of high δ 34S barites that caused the sharp rise of δ 34S values in a short period of time. [ABSTRACT FROM AUTHOR]

[Display omitted] • The ore-forming fluids originated from ELIP volcanism-related hydrothermal activities. • The sedimentary environment likely evolved from anoxic through suboxic to oxic. • Permian Mn mineralization led by ELIP-induced tectono-hydrothermal activities and redox changes. The Permian manganese (Mn) ore belt lies in western South China Block, and contains many large-medium Mn deposits. However, the genesis and metallogenic mechanism of these deposits remains a matter of debate. Here we shed light on this issue based on new mineralogical, geochemical, and Sr isotope data from the Changgou Mn deposit in the Zunyi orefield (Guizhou, SW China). The Mn orebodies occur as lenses and layers, and are hosted in carbonaceous-siliceous limestone, carbonaceous mudstone, and tuffaceous claystone. The ores show a variety of structures (e.g., detrital, brecciated, massive, and banded) and complex mineral compositions (e.g., galena, sphalerite, siegenite, molybdenite, barite, rutile, and monazite). The ore samples are characterized by chalcophile and siderophile element enrichments, low Al 2 O 3 /TiO 2 ratios (mean 10.36), high and varying Mn/Fe ratios (1.26–4.71), distinctly high REY (rare earth and yttrium) contents (mean 766.46 ppm), and high La/Ce (mean 1.04) and low Y/Ho (mean 28.17) ratios. The footwall and ore samples have 87Sr/86Sr ratios of 0.706897 to 0.707093. Integrated mineralogical and geochemical signatures indicate that the ore-forming fluids were most probably originated from hydrothermal activities related to early-stage Emeishan Large Igneous Province (ELIP) subaqueous volcanism. Redox proxies reveal that sedimentary conditions evolved from euxinic-anoxic (footwall deposition), through anoxic-suboxic (Mn mineralization), to oxic (hanging-wall deposition). Such changes were probably resulted from a coeval eustatic sea-level drop and enhanced seawater oxygen supply. Manganese was likely initially enriched in form of Mn2+, and subsequently precipitated with oxidation, and then transformed into Mn carbonate during sediment diagenesis. To conclude, the tectono-hydrothermal activities and major environmental redox changes led by the ELIP volcanism have provided a favorable source-migration-sink system for the Mn mineralization. [ABSTRACT FROM AUTHOR]

The Nibao gold deposit, which includes both fault-controlled and strata-bound gold orebodies, constitutes an important part of the Yunnan–Guizhou–Guangxi "Golden Triangle" region. Defining the mineralization age of these gold orebodies may provide additional evidence for constraining the formation ages of low-temperature orebodies and their metallogenic distribution in South China. Petrographic studies of gold-bearing pyrites and ore-related quartz veins indicate that these pyrites coexist with quartz or filled in vein-like quartz, which suggests a possible genetic relationship between the two from Nibao gold deposit. Minerals chemistry shows that Rb and Sr are usually hosted in fluid inclusions in quartz ranging from 0.0786 to 2.0760 ppm and 0.1703 to 2.1820 ppm, respectively. The Rb–Sr isotopic composition of gold-bearing quartz-hosted fluid inclusions from the Nibao gold deposit were found to have Rb–Sr isochron ages of 142 ± 3 and 141 ± 2 Ma for both fault-controlled and strata-bound orebodies, respectively, adding more evidence to previous studies and thus revealing a regional gold mineralization age of 148–134 Ma. These results also confirm the Middle-Late Yanshanian mineralizing events of Carlin-type gold deposits in Yunnan, Guizhou, and Guangxi Provinces of Southwest China. In addition, previous studies indicated that antimony deposits in the region which were formed at ca. 148–126 Ma have a close affinity with gold deposits. This illustrates that the regional low-temperature hydrothermal gold mineralization is related in space and time to the Yanshanian (ca. 146–115 Ma) magmatic activity. Specifically, the large-scale gold and antimony mineralization are considered to be inherently related to mantle-derived mafic and ultramafic magmatic rocks associated with an extensional tectonic environment. Based on the initial 87Sr/86Sr ratios of 0.70844 ± 0.00022 (2σ) and 0.70862 ± 0.00020 (2σ) for gold-bearing quartz veins from fault-controlled and strata-bound gold orebodies, respectively, at the Nibao gold deposit, as well as the C, H, O, and S isotopic characteristics of gold deposits located in the Golden Triangle region, we suggest that the mantle-derived material can be involved in the formation of the Nibao gold deposit and that the ore-forming fluid can be derived from a mixed crust–mantle source. [ABSTRACT FROM AUTHOR]