Search

Zinc isotopes have been increasingly utilized as a proxy for (bio)geochemical cycles of nutrient Zn in the ecosystem like soils, but the behavior and mechanism of Zn isotope fractionation during weathering and soil formation remain to be constrained. Here we reported zinc contents and isotope data for saprolites and laterites from two well-characterized mafic-rock weathering profiles, formed under a subtropical climate (South Carolina, USA) and a tropical climate (Hainan Island, China), respectively. Leaching experiments with basalt and andesite as the starting materials were also performed for comparison. The leaching results revealed no resolvable Zn isotope fractionation during dissolution of silicate minerals in the absence of organic ligands in solutions. The Hainan laterites show strong Zn depletion and have lower δ66Zn Lyon values (0.10‰ to 0.27‰) relative to the parent rock (0.31 ± 0.04‰), which are coupled with light copper isotope compositions in the same samples. These observations suggest that Zn mobilization was achieved via metal-organic complexation and Fe-colloids transportation. By contrast, saprolites from the South Carolina are extremely Zn-rich (ten-fold higher concentration than the parent rock) and most samples have higher δ66Zn values (0.10‰ to 0.65‰) compared with the parent rock (0.24 ± 0.04‰). Zinc isotope ratios of the South Carolina profile are positively correlated with iron isotope ratios (δ56Fe) and Fe3+/Fe Total , the latter of which is related to secondary Fe (hydr)oxide formation. These relationships link the high Zn contents and δ66Zn values of saprolites from the South Carolina profile to the substantial adsorption of Zn onto or isomorphic substitution into Fe (hydr)oxides that prefers heavier Zn isotopes. Our study highlights that Fe (hydr)oxides exert a strong influence on the re-distribution of nutrient Zn in natural soils and the (bio)geochemical cycling in natural soil systems. [ABSTRACT FROM AUTHOR]

A series of Cenozoic post-collisional mantle-derived magmas developed in the Southeastern Tibetan Plateau (the SE Plateau), which can be utilized to trace source components and mantle metasomatism, and further constrain the mantle evolution. In this paper, we present a systematic study on petrography, whole-rock major and trace element, Sr-Nd-Pb-Mg isotopes of Miocene-Holocene alkali basalts at the southeastern margin of the SE Plateau. These Miocene-Holocene alkali basalts were the products of the northward extension of the Cenozoic mantle-derived magmatism in Southeast Asia (SE Asia), since they are comparable in terms of geographical distributions, petrographic characteristics, geochronology patterns, and geochemical compositions. The alkali basalts in this study are mainly basanite and trachybasalt, characterized by enriched LILEs, depleted Sr-Nd-Pb isotopes, positive anomaly in HFSEs, and significantly lighter Mg isotopes (−0.51‰ to −0.32‰) relative to primitive mantle. Integrated Sr-Nd-Mg isotopes and seismic tomography suggest a source regions from the mantle transition zone that has been enriched by significant carbonate sediments. The decoupling of high Sr contents and depleted Sr Nd isotopes in the alkali basalts indicate that the mantle carbonation is subjected to recent subduction events and is possibly related to the subduction of the Neo-Tethyan seafloor. The calculated melting temperature of these basalts are generally high (1487–1583 °C), which is consistent with that of Cenozoic basalts in SE Asia (1470–1480 °C) and Hainan island (1480–1530 °C), showing a high-temperature gradient similar to that of mantle plume-related magmatism. Consequently, the generation of Miocene-Holocene alkali basalts is plausibly associated with the Hainan plume. • Sanjiang alkaline basalts are the northward extension of basalts in Southeast Asia. • Sanjiang alkali basalts are originated from the mantle transition zone. • Alkali basalts in the southeastern Plateau originated from the carbonated mantle. • Alkali basalts are related to the Hainan mantle plume. [ABSTRACT FROM AUTHOR]