1. Aggregation‐dependent phosphorus adsorption under different land uses of district Kupwara of Kashmir Valley.
- Author
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Naikoo, Nasir Bashir, Mir, Aamir Hassan, Jianjun, Han, Nazir, Shaista, Yasin, Ghulam, Jeelani, Fehim, Bhat, Raies Ahmad, Bashir, Owais, Wani, Owais Ali, Koubouris, Georgios, and Rahman, Shafeeq Ur
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LANGMUIR isotherms , *SOIL structure , *LAND use , *ADSORPTION (Chemistry) , *PHOSPHATE fertilizers - Abstract
Background: Phosphorus (P) is among the essential elements for plant growth and one of the main elements of fertilizers. Decreased availability of P may limit agricultural production in the coming years. The magnitude of soil aggregation influences phosphorus access to mineral surfaces. Aim: The present study aims to determine phosphorus adsorption processes affected by soil aggregation under different land‐use systems. Methods: The distribution of soil aggregates was determined in representative soil samples in the district Kupwara of Kashmir Valley in India. To predict the phosphorus fertilizer requirement of a particular soil, we used the Freundlich adsorption equation and Langmuir equation and drew a clear comparison between these two models. Results and discussion: Maximum phosphorus (P) adsorption was recorded at the smallest aggregate size, 0.5–0.1 mm. However, soil aggregates >2.0 mm (the largest category) adsorbed the least amount of P. Our results revealed that increasing the addition of P to the soil decreased the percentage of adsorbed P regardless of aggregate size. The maximum P adsorption of different size aggregates varied between 1869–1924, 1872–1900, 1718–1739, and 1800–1890 mg P kg–1 in irrigated agriculture, forest, orchard and rainfed agriculture soils, respectively. The variation in P adsorption parameters across the different land uses was attributed to their mean weight diameter difference. The maximum bonding energy in the forest resulted in higher P adsorption. Langmuir and Freundlich's adsorption equations were fitted to each soil aggregate size and land‐use system. Conclusion: Our results revealed that for all soil aggregate sizes and land use systems, the Freundlich adsorption equation performs better than the Langmuir equation. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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