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Abstract: One of the significant features of loess-derived soils in Kansas is the occurrence of clay-rich subsurface horizons above a layer enriched with pedogenic carbonates. In order to examine the extent of clay increase and pedogenic carbonate enrichment in a precipitation gradient, ten soil profiles from three different precipitation regions were studied using micromorphological and mineralogical techniques. The precipitation gradient was divided into three groups: 400–550 mm, 550–750 mm, and 750–1100 mm regions. The objectives were to (1) understand the cause of clay orientation in clay-rich horizons (2) investigate the reasons for the clay increase, and (3) observe the interaction of clay and pedogenic carbonate accumulation features along a precipitation gradient in Kansas. Although clay films were identified in the field for soils in the 400–550 mm regions, illuvial clay films were not observed in thin section analysis. The clay accumulations mostly occurred as grain coatings. The rest of the clay accumulations observed were very thin, striated, and mostly associated with voids. The argillic horizons had a granostriated b-fabric, which indicates stress orientation of micromass caused by high shrink–swell activity. Thick and continuous illuvial coatings were observed in the buried horizons of paleosols. In the other two regions where precipitation exceeds 550 mm, illuvial clay coatings with strong orientation were observed along with thin and striated stress-oriented clay. Both types of clay orientations exceeded 1% of the cross-sectional area for the thin section. Although illuvial clay features and pedogenic carbonates were observed in all soils at approximately the same depth, complete obliteration of clay coatings was not observed in these horizons. In-situ weathering of biotite was one of the reasons for the clay increase in all soil profiles. In all soils studied, the clay increase and cause of clay orientation cannot be attributed to a single genetic process or event. Both illuviation and shrink–swell activity were involved in the orientation of clay. Although orientation of clay and pedogenic carbonates were observed in all soils at approximately the same depth, the decomposition of clay coatings was not observed in these horizons. [Copyright &y& Elsevier]

Abstract: The genesis and micromorphology of three Harney soils from different precipitation regions (from 540mm to 715mm) (fine, smectitic, mesic Typic Argiustolls) in the Smoky Hills of central Kansas were investigated. The objectives were to (1) examine the morphological, chemical, physical and mineralogical characteristics of Harney soils formed in loess; (2) determine the clay mineral distribution with depth and the origin of the clay minerals present; and (3) investigate the relationship between the clay mineralogy and other soil properties such as soil plasmic fabric, COLE values and fine clay/total clay ratios. Mineralogical and micromorphological techniques were used to evaluate the characteristics of the loess-derived soils. The first pedon was formed in 88cm of Bignell loess over Peoria loess and the other two pedons were formed from Peoria loess. The chemical properties were similar for the pedons studied. Differences were observed in physical properties, especially in particle size distribution, oven-dry bulk density and coefficient of linear extensibility values. Although the soils were mapped in the same soil series, the geomorphic positions of the pedons and the nature of the parent material affected the characteristics of the soils. Smectite was the predominant clay mineral, especially in the fine clay fraction, regardless of the location in the precipitation gradient. The dominance of smectite increased in the C-horizons. This implies a detrital source of smectite in the B-horizons formed in both Bignell and Peoria loess units. The presence of randomly interstratified mica-smectite and the micromorphological observations of weathering biotite indicate that weathering also plays an important role in the mineralogy of Harney soils. The high content of clay mica in the surface horizons was caused by dust fall in the study area. Thick and continuous argillans were observed when FC/TC and COLE values were low and crystalline smectite was present. In the lower part of the soil profiles, the plasmic fabric was mostly ma-skelsepic (granostriated b-fabric) and smectite was more crystalline as indicated by sharper X-ray diffraction peaks. [Copyright &y& Elsevier]