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Domestic consumption of biomass fuels has been found as a leading source of polycyclic aromatic hydrocarbons (PAHs) in pristine regions. The biomass ashes would serve as both source and vector for PAHs, which may threaten residents' health. However, research focusing on the behaviors of waste biomass ashes acting as emission resources of PAHs is still lacking. In present study, occurrence and fate of PAHs released from disposal biomass ashes in the Tibetan Plateau were investigated by evaluating their patterns and levels in soils at different distances from the Lhasa landfill. Concentrations of 16 PAHs averaged at 1009 ng/g dry weight and 103 ng/g dry weight in landfill cover soils and surrounding soils, respectively. The spatial distributions of PAHs evidenced the local source of biomass ashes in landfill, while the fractionations of PAHs in soils profiles emphasized the post-deposal leaching. Since PAH compositions altered significantly during their transport and sequestration, the rectification factors were suggested to adjust the source diagnostic ratios. In study area, the emission flux of PAHs from waste biomass ashes to soils was 0.93 ton/year; extended to the Tibetan Plateau, the flux was estimated to be 13.1–32.5 ton/year. This study confirmed that waste biomass ashes would represent significant contributions of PAH emissions in this pristine region, which might remarkably exacerbate the total emissions of PAHs in Tibet by more than 25%. Image 1 • Biomass ashes disposed in Tibetan urban landfill served as a local PAH source. • Leaching process of PAHs was affected by their congener hydrophobicity and SOC contents. • Calibration factors were proposed for source diagnostic ratios. • PAH emission inventory of biomass ashes may reach 13.1–32.5 tons/year in Tibet. Biomass ashes acted as a local source of PAHs in the Tibetan Plateau, which remarkably exacerbated the total emissions of PAHs in this region by more than 25%. [ABSTRACT FROM AUTHOR]