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Economic development, population growth, and rapid urbanization are the reasons for an increasing generation of waste all over the world. Recently, the statistics showed that 2.1 million of tons municipal solid waste (MSW) was produced in 2016, which is estimated to enhance by 3.4 million tons in 2050. In recent times, municipal solid waste generation is dramatically increasing due to factors such as rapid urbanization, altered living standard, and increased population. These factors make the municipal solid waste management system complex and break the pollution-controlling strategies. So it necessitates the system to accurately predict the waste composition. Based on the waste classification, a suitable decomposition technique is preferred. Therefore, this paper proposed CMSOA optimized dual faster R-CNN based waste management system to accurately classify the waste composition. The proposed system is formed by hybridizing dual faster RCNN along with complex-valued encoding multi-chain seeker optimization algorithm (CMSOA). Various evaluation measures, namely accuracy, precision, recall, F-measure, RMSE, MAE, and MAPE metrics, are computed, and the case study analysis is conducted on the major five cities of Maharashtra. The comparative analysis is carried out for various approaches, and from the analysis, the results revealed that the proposed method provides better classification results than other methods. [ABSTRACT FROM AUTHOR]