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During the late Carboniferous–middle Permian, the basement of the Chilean Coastal Cordillera was deformed by the Gondwanan Orogeny, developed by the subduction of the Paleo-Pacific plate under Gondwana from the early Carboniferous. In the Maule sector (35.4°S), the following metamorphic rock units are distinguished: (i) Western Series, formed by metapelites, metabasites, metacherts, metaconglomerates, and marbles, mixed in a subduction channel, with probably ages between the Cambrian and the Carboniferous; (ii) Eastern Series, consisting of metasediments of a fore-arc basin, Carboniferous in age. In the Eastern Series two units are recognized in terms of lithology and deformation style: the Eastern Pelitic Series and the Eastern Sandy Series. Three Gondwanan deformation episodes have been distinguished, affecting both series unequaly. In the Western Series, D1 structures consist of a foliation (S 1) developed under high-pressure and low-temperature conditions, while in the Eastern Series it comprise tight east-verging folds, with the associated S 1 developed under low PT metamorphic conditions (greenschist facies). D2 structures are only present in the Western Series and Eastern Pelitic Series and represent the exhumation of the accretionary prism and its emplacement to the east over the fore-arc basin, with the development of east-verging recumbent folds and a thick shear-zone. Difficulties in the propagation of the deformation by the presence of the Coastal Batholith to the east led to the development of the D3 deformation event, only well developed in the Eastern Sandy Series, and represented by the Los Tablones Back-thrust and associated folds, as well as N–S open right folds formed under low PT metamorphic conditions. • New data on the lithology, structure and metamorphism of the Paleozoic rocks of the Chilean Coastal Range are presented. • Paleozoic rocks of the Maule River were deformed during the Gondwana orogeny under different metamorphic conditions • The Western Series deformed in HP metamorphic conditions during D1 in the subduction channel and was exhumed by an east-directed thrust during D2 • Structures D1, D2 and D3 of the Oriental Series were developed under LP-LT metamorphic conditions. The D1 and D2 have East vergence and the D3 West [ABSTRACT FROM AUTHOR]