Search

Reactive silica additives, such as clays, can increase the filterability of phosphogypsum (PG) during wet phosphoric acid production from phosphate rock (PR). In this study, the effect of adding inexpensive fly ash waste (34 kg per t PR) together with lower quantities of pure silica (8.5 kg per t PR) on the radioactivity of PG was investigated. The addition of fly ash waste/pure silica reduced the radiological activity of the PG by roughly 30%. The reduction was attributed to decreased activities from 238U (60% reduction) and 226Ra (30% reduction) in PG. Besides, P2O5 losses were slightly decreased. [ABSTRACT FROM AUTHOR]

• Khouribga PR shows relevant REE (577 ppm) and Y (240 ppm) concentrations. • The majority of REE (<80%) and Y (<70%) transfer to the solid PG stream. • Recovering REE and Y from solid PG is economically challenging. • Fly-ash/pure silica additives increase REE and Y transfer to the liquid PA stream. Adding active silica (SiO 2) to reduce the free fluoride content is a known method to improve the filterability of phosphogypsum (PG) during wet phosphoric acid (WPA) processing of phosphate rock (PR). Besides, this process can also promote the transfer of valuable rare earth elements (REE) from the PR into the liquid phosphoric acid (PA) stream rather than into the solid PG matrix from which later economic recovery is more challenging. Khouribga PR, that shows total REE concentrations of 577 ppm (328 ppm heavy REE and 249 ppm light REE) of which yttrium (Y) with 240 ppm constitutes the major fraction, is processed at the Jorf Lasfar El-Jadida chemical complex in Morocco that is also home to the country's largest coal power plant. Fly ash produced during thermal power production, 70% of which is stacked in the immediate vicinity, presently remains mostly unused and consists largely (48%) of silica. In this work the use of fly ash (34 kg per t PR) and pure silica (8.5 kg per t PR) on the transfer of REE from Khouribga PR into the PA and PG stream during dihydrate WPA production was examined. The inexpensive fly ash/silica additive increases the transfer of various REE to the PA stream. For Y an increase of 37% was measured that resulted in a concentration of 48 ppm in the PA stream prior to further concentration by evaporation. [ABSTRACT FROM AUTHOR]

• Argan nutshells were ground to sawdust and used in packed column experiments. • The sawdust successfully adsorbed U from synthetic solutions. • The sawdust absorbed 54% of U and 75% of Cd from merchant-grade PA. • Direct heavy metal recovery using argan nutshell sawdust is not reasonable. • Heavy metal extraction using argan nutshell sawdust and later recovery is promising. Argan nutshells, available in Morocco as a low-cost by-product from Argan oil production, were used to produce a sawdust biosorbent for the extraction of U and other heavy metals (Cd, As, Zn, Cu, Ni and Cr) from merchant-grade phosphoric acid (PA). Packed column (D = 20 mm, L = 250 mm, flowrate 1 mL/min) lab-scale experiments were carried out with three different solutions: (1) a synthetic heavy metals solution, (2) pure PA at different concentrations (0.85%, 8.5% and 85%) in water, and (3) merchant-grade PA from an industrial fertilizer plant in Morocco that was diluted with water to analyze different P 2 O 5 contents (5%, 30% and 54%) and a U concentration of up to 157 ppm. The sawdust successfully adsorbed 99% of the U from (1) the synthetic solution and (2) the pure PA independent of the acid concentration. It further managed to adsorb more than half (54%) of U, 75% of Cd, 74% of As, 84% of Zn, 86% of Cu, 83% of Cr of the merchant-grade PA at 54% P 2 O 5 content and a flow-rate of 1 mL/min. The sawdust was characterized by SEM and FTIR to understand the adsorption of metal ions. Column studies were carried out to know the breakthrough point. At breakthrough, the effluent volume was found to be 50 mL and the maximum adsorption capacity for U was found to be 0.93 mg/g. Heavy metal recovery using ANS does not seem to be promising as a result of the low (>10%) desorption rates if citric- or oxalic acid is used as was done in this study. Heavy metal extraction without direct recovery using ANS is promising and should further be investigated though. [ABSTRACT FROM AUTHOR]