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This paper reports novel data concerning the volcanic formation of thePiperno, a stone that has been used for a long time in the monumental architecture of Naples and the Campanian region (Southern Italy). A careful field survey of the outcrops or underground sites so far accessible allowed us to draw a lithostratigraphic reconstruction of the formation and enabled the recognition of the three main layers exploited in past centuries and which provided dimension stones for architectural and structural purposes. Petrophysical and mineralogical characterization also enabled us to discriminate the same layers previously identified. Different scoriae/matrix ratio, scoriae dimension and welding degree are the most peculiar features of these horizons. The combination of these three parameters, even though they did not affect the use ofPipernoas dimension stone, somehow determined its variable susceptibility to the weathering agents. However, a linear relationship between the exposure time and the decay of the stone itself, at a parity of weathering intensity, was not observed. This assumption was proved by verifying that the specific layers of the volcanic sequence controlled the weathering degree ofPipernofrom monuments disregarding their age of emplacement. [ABSTRACT FROM AUTHOR]

This current research is focused on the mineralogical and petrographic characterisation of mortar-based materials from Villa San Marco in the ancient Stabiae (modern Castellammare di Stabia, Napoli), an outstanding example of Roman otium villae , and aims at recognising the technology used by the ancient skilled workers. Several analytical techniques were used such as digital videomicroscopy, optical microscopy, digital image analysis, scanning electron microscopy coupled with EDS analysis and Quantitative Powder X-ray Diffraction. A multi-layer technology characterised the plasters; the scratch coat was made with lime mortars mixed with a pozzolanic lightweight aggregate and cocciopesto , required ingredients providing a quick-setting and a better adhesion with the support. As far as the arriccio layer is concerned, the mix-design is a lime mortar with volcanic sand as the aggregate and a minor content of pozzolan and/or cocciopesto to enhance the workability of the mortar in order to correct any error due to the roughness of the scratch coat. The plaster s.s. was the removable support in case of mistakes, and gave a lighter colour to the preparation layer of the frescoes. The last thin layer, prepared with lime mortars and a carbonate aggregate, is characterised by low porosity in order to avoid pigment adsorption. The painting technique was a fresco with encaustication . In contrast, the mortars of the building structures were made with lime added to a pozzolanic aggregate (volcanics and cocciopesto ), giving a quick setting during the implementation of the yellow tuff opus reticulatum . The rudera and nuclei of the mosaics were built with abundant volcanic sand and cocciopesto mixed with the lime, producing a more resistant surface, and finally the tesserae were fixed exclusively with lime. The white and black colours of the mosaics were produced by local limestone and tephritic lava. The results permitted an evaluation of the high level of specialization of both the workers and the artists that built and decorated these maritime villas. Moreover, the collected data highlighted the wide potentiality of the materials cropping out in the environs of the Somma-Vesuvius volcanic complex. This research aims at furnishing a useful reference for future restoration action in Villa San Marco and the other Roman villas in this area. [ABSTRACT FROM AUTHOR]