Search

Chemical weathering of silicate minerals releases elements into solution whereas the neoformation of secondary minerals works in the opposite direction, potentially confounding estimates of silicate weathering rates. Silicon isotopes (δ 30 Si) may be a useful tool to investigate these processes. Here, we present 82 δ 30 Si measurements from surface waters, pore waters, biogenic silica (BSi), clays, sand and vegetation from the Okavango Delta, Botswana, a freshwater sub-tropical, flood-pulse wetland. Hydrologically, the Okavango is dominated by evapotranspiration water losses to the atmosphere. It receives an annual pulse of water that inundates seasonal floodplains, while river baseflow is sufficient to maintain a permanent floodplain. δ 30 Si in dissolved silica (DSi) in surface waters along a 300 km transect at near-peak flood show a limited range (0.36–1.19‰), implying the Delta is well buffered by a balance of processes adding and removing DSi from the surface water. A key control on DSi concentrations is the uptake, production of BSi and recycling of Si by aquatic vegetation, although the net isotopic effect is necessarily small since all BSi re-dissolves on short timescales. In the sediments, BSi δ 30 Si ( n = 30) ranges from −1.49‰ to +0.31‰ and during dissolution, residual BSi tends towards higher δ 30 Si. The data permit a field-based estimate of the fractionation associated with BSi dissolution, ε 30 BSi-DSi = −0.26‰, though it is unclear if this is an artefact of the process of dissolution. Clay δ 30 Si ranges from −0.97‰ to +0.10‰, ( n = 15, mean = −0.31‰) and include the highest values yet published, which we speculate may be due to an equilibrium isotope effect during diagenetic transformation of BSi. Two key trends in surface water DSi δ 30 Si merit further examination: declining δ 30 Si in an area roughly corresponding to the permanent floodplains despite net DSi removal, and increasing δ 30 Si in the area corresponding to the seasonal floodplains. We infer that evaporative enrichment of surface waters creates two contrasting regimes. Chemical weathering of low δ 30 Si phases releases low δ 30 Si DSi in the relatively dilute waters of the permanent floodplains, whereas silicon removal via clay formation or vegetation uptake is the dominant process in the more enriched, seasonal floodplains. [ABSTRACT FROM AUTHOR]