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We investigate ten of the most recent tephra-fall deposits emplaced between ≤21 and 2 ka from the Pacheco stage of Misti volcano, Peru, to elucidate magma dynamics and explosive eruption triggers related to magma storage, recharge, and remobilization. Whole-rock, glass, and mineral textures and compositions indicate the presence of broadly felsic, intermediate, and mafic magmas in a chemically and thermally stratified magma storage system (Zones 1–3) that interact to differing extents prior to eruption. Intermediate magmas are defined by plagioclase + amphibole + two-pyroxenes + Fe-Ti oxides and phase equilibria indicate they formed at ~300 to 600 MPa and ~950°C to 1000°C. Intermediate magmas dominate the Pacheco stage and either erupted alone as hybridized magmas or mingled with minor volumes of cool felsic magmas (~800°C) in which only plagioclase + Fe-Ti oxides are stable. Felsic magmas do not exclusively comprise any tephra-fall deposit emplaced during the Pacheco stage but were remobilized by recharge and mixing with intermediate magmas in order to erupt. Furthermore, felsic-hosted amphibole cognate to the intermediate magmas are reacted despite the felsic magmas being water saturated, which suggests they are staged above the amphibole stability limit (≤200 MPa). The cryptic presence of mafic magmas is indicated by high-An plagioclase cores (An74–88), rare anhedral olivine (Fo77–80), and possibly high Mg# augite and amphibole (up to Mg# 84 and 77, respectively). The dearth of basalt to basaltic andesite melts recorded in erupted glasses and exclusivity of high-An plagioclase to crystal cores signals mafic magmas are staged deeper in the crust than the intermediate magmas. Periodic interactions between these magmas tracked via glass compositions and crystal exchange reveal an alternation between the production of mingled magmas and their eruption shortly after a recharge event, followed by a period of homogenization and eruption of hybridized magmas. As such, we identify magma recharge as a key mechanism by which half of the explosive eruptions were triggered in the Pacheco stage. A >100°C increase in Misti's fumarole temperatures from 1967 to 2018 coincident with changes in fumarolic gas compositions is consistent with degassing of a mafic recharge magma, signaling that Misti could produce similar explosive eruptions in the future. [ABSTRACT FROM AUTHOR]

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This work proposes a new method to probe the hidden magmatic evolution of quiescent Andean volcanoes from the Pb isotope composition of gases. The method is based on an assimilation-fractional crystallisation-degassing model linking the Pb isotope composition of gases with the SiO2 content of their magmatic source. The model is applied to El Misti volcano that threatens Arequipa, the second most densely populated city of Peru. Gas condensates and Pb-rich solid deposits (PbS, PbCl2, PbSO4) collected in 2018 in the bottom of El Misti crater at 260–150°C fumarole vents were used to reconstruct the mean composition of degassing magmas (60.8–61.8 wt% SiO2). These compositions are slightly more evolved than the lavas from the last AD 1440–1470 eruption, suggesting either the secular differentiation of the main magma reservoir, or the contribution of more evolved magmas to volcanic gases. On the other hand, the slight but significant difference between the instantaneous composition recorded in gas condensates and the time-integrated composition recorded in solid deposits points to the degassing of less evolved magmas over the last decades. This trend is ascribed to a recent recharge of El Misti reservoir with hot mafic magmas, in agreement with the evolution of fumarolic deposit mineralogy in the last half a century. The Pb isotope composition of gas appears to be a promising tool for probing the hidden magmatic evolution of quiescent volcanoes where assimilation-fractional crystallisation operates. [ABSTRACT FROM AUTHOR]

We have reconstructed the eruptive chronology of the Ampato–Sabancaya volcanic complex (Southern Peru) on the basis of extensive fieldwork, and a large dataset of geochronological ( 40 K– 40 Ar, 14 C and 3 He) and geochemical (major and trace element) data. This volcanic complex is composed of two successive edifices that have experienced discontinuous volcanic activity from Middle Pleistocene to Holocene times. The Ampato compound volcano consists of a basal edifice constructed over at least two cone-building stages dated at 450–400 ka and 230–200 ka. After a period of quiescence, the Ampato Upper edifice was constructed firstly during an effusive stage (80–70 ka), and then by the formation of three successive peaks: the Northern, Southern (40–20 ka) and Central cones (20–10 ka). The Southern peak, which is the biggest, experienced large explosive phases, resulting in deposits such as the Corinta plinian fallout. During the Holocene, eruptive activity migrated to the NE and constructed the mostly effusive Sabancaya edifice. This cone comprised many andesitic and dacitic blocky lava flows and a young terminal cone, mostly composed of pyroclastic material. Most samples from the Ampato–Sabancaya define a broad high-K magmatic trend composed of andesites and dacites with a mineral assemblage of plagioclase, amphibole, biotite, ortho- and clino-pyroxene, and Fe–Ti oxides. A secondary trend also exists, corresponding to rare dacitic explosive eruptions (i.e. Corinta fallout and flow deposits). Both magmatic trends are derived by fractional crystallisation involving an amphibole-rich cumulate with variable amounts of upper crustal assimilation. A marked change in the overall eruptive rate has been identified between Ampato (~ 0.1 km 3 /ka) and Sabancaya (0.6–1.7 km 3 /ka). This abrupt change demonstrates that eruptive rates have not been homogeneous throughout the volcano's history. Based on tephrochronologic studies, the Late Holocene Sabancaya activity is characterised by strong vulcanian events, although its erupted volume remained low and only produced a local impact through ash fallout. We have identified at least 6 eruptions during the last 4–5 ka, including the historical AD 1750–1784 and 1987–1998 events. On the basis of this recurrent low-to-moderate explosive activity, Sabancaya must be considered active and a potentially threatening volcano. [ABSTRACT FROM AUTHOR]

Abstract: Following a fumarolic episode that started six months earlier, the most recent eruptive activity of the Ubinas volcano (south Peru) began on 27 March 2006, intensified between April and October 2006 and slowly declined until December 2009. The chronology of the explosive episode and the extent and composition of the erupted material are documented with an emphasis on ballistic ejecta. A petrological study of the juvenile products allows us to infer the magmatic processes related to the 2006–2009 eruptions of the andesitic Ubinas volcano. The juvenile magma erupted during the 2006 activity shows a homogeneous bulk-rock andesitic composition (56.7–57.6wt.% SiO2), which belongs to a medium- to high-K calc-alkaline series. The mineral assemblage of the ballistic blocks and tephra consists of plagioclase>two-pyroxenes>Fe–Ti oxide and rare olivine and amphibole set in a groundmass of the same minerals with a dacitic composition (66–67wt.% SiO2). Thermo-barometric data, based on two-pyroxene and amphibole stability, records a magma temperature of 998±14°C and a pressure of 476±36MPa. Widespread mineralogical and textural features point to a disequilibrium process in the erupted andesite magma. These features include inversely zoned “sieve textures” in plagioclase, inversely zoned clinopyroxene, and olivine crystals with reaction and thin overgrowth rims. They indicate that the pre-eruptive magmatic processes were dominated by recharge of a hotter mafic magma into a shallow reservoir, where magma mingling occurred and triggered the eruption. Prior to 2006, a probable recharge of a mafic magma produced strong convection and partial homogenization in the reservoir, as well as a pressure increase and higher magma ascent rate after four years of fumarolic activity. Mafic magmas do not prevail in the Ubinas pre-historical lavas and tephras. However, mafic andesites have been erupted during historical times (e.g. AD 1667 and 2006–2009 vulcanian eruptions). Hence, the most recent episode indicates that a resupply of mafic magmas has probably occurred at depth under Ubinas. [Copyright &y& Elsevier]

Abstract: Ubinas volcano is located 75km East of Arequipa and ca. 5000 people are living within 12km from the summit. This composite cone is considered the most active volcano in southern Peru owing to its 24 low to moderate magnitude (VEI 1–3) eruptions in the past 500years. The onset of the most recent eruptive episode occurred on 27 March 2006, following 8months of heightened fumarolic activity. Vulcanian explosions occurred between 14 April 2006 and September 2007, at a time ejecting blocks up to 40cm in diameter to distances of 2km. Ash columns commonly rose to 3.5km above the caldera rim and dispersed fine ash and aerosols to distances of 80km between April 2006 and April 2007. Until April 2007, the total volume of ash was estimated at 0.004km3, suggesting that the volume of fresh magma was small. Ash fallout has affected residents, livestock, water supplies, and crop cultivation within an area of ca. 100km2 around the volcano. Continuous degassing and intermittent mild vulcanian explosions lasted until the end of 2008. Shortly after the initial explosions on mid April 2006 that spread ash fallout within 7km of the volcano, an integrated Scientific Committee including three Peruvian institutes affiliated to the Regional Committee of Civil Defense for Moquegua, aided by members of the international cooperation, worked together to: i) elaborate and publish volcanic hazard maps; ii) inform and educate the population; and iii) advise regional authorities in regard to the management of the volcanic crisis and the preparation of contingency plans. Although the 2006–2008 volcanic crisis has been moderate, its management has been a difficult task even though less than 5000 people now live around the Ubinas volcano. However, the successful management has provided experience and skills to the scientific community. This volcanic crisis was not the first one that Peru has experienced but the 2006–2008 experience is the first long-lasting crisis that the Peruvian civil authorities have had to cope with, including attempts to utilize a new alert-level scheme and communications system, and the successful evacuation of 1150 people. Lessons learned can be applied to future volcanic crises in southern Peru, particularly in the case of reawakening of El Misti volcano nearby Arequipa. [Copyright &y& Elsevier]

Understanding the links between the magma differentiation processes, the magma plumbing system and the magma composition at arc volcanoes is of paramount importance for volcanic hazard assessment. In this work we focus on the post-glacial, Holocene, historical, and recent eruption products of Ubinas volcano (Peru), which display an overall decrease in silica content from the older, plinian (VEI 3–5), rhyolitic eruptions (69–71 wt% SiO 2) to the historical and recent (2006–2009, 2013–2017), vulcanian (VEI 1–2) basaltic andesitic eruptions (55–57 wt% SiO 2). Based on a comprehensive study of the major and trace elements and the Sr-Nd-Pb isotopes, we conclude that this temporal pattern reflects the evolution of the Ubinas magmas in the middle-to-upper crust by a coupled Assimilation-Fractional Crystallization (AFC) process involving a cumulate composed of plagioclase, amphibole, clinopyroxene, orthopyroxene and Fe–Ti oxides, with minor amounts of olivine and biotite at the mafic and felsic end-members, respectively. Upper crustal assimilation is limited to 5–8 vol%, but the overall radiogenic Sr-Nd-Pb signature of the Ubinas magmas requires a larger crustal component, which must therefore occur at middle to lower crustal depths. The petrology of the Ubinas magmas also points to an overall increase in P-T conditions: the large Holocene dacitic and rhyolitic eruptions record temperatures ranging from 800 to 850 °C and pressures in the range of 200–400 MPa, whereas the historical and recent (2006–2009, 2013–2017) basaltic andesitic eruptions provide higher temperatures and pressures (1000 °C, >300–400 MPa). Overall, the thermo-barometry, phase equilibrium and geochemical constraints allow us to propose the existence of a middle-to-upper crust magma column composed of a highly crystalline magma mush containing batches of liquid magma, which seems to be continually recharged from deeper levels. On the basis of the petrological nature of the historical basaltic andesitic eruptions (1667 CE , 2006–2009, 2013–2017), we postulate that during the last centuries, Ubinas experienced a recharge-dominated process, with no evidence for a rejuvenation of the silica-rich reservoir that fed the large Holocene dacitic to rhyolitic eruptions. This study highlights the importance of detailed petrological studies of Holocene sequences at explosive arc volcanoes in order to constrain the magmatic processes and conditions that control large explosive eruptions. • Holocene to recent eruptive products of Ubinas volcano display a progressive decrease in silica content • Ubinas eruptions reveal a link between magmatic processes and magma chemistry • Magma diversity results of middle-to-upper crust assimilation-fractional crystallization process • Petrology suggests a progressive increase in P-T conditions, from the older to the younger eruptive products • Older magmas are stored at a reservoir at 250-400 MPa, which seems to be recharged by the historical and recent magmas [ABSTRACT FROM AUTHOR]

We reconstruct the eruptive chronology of the Yucamane–Calientes compound volcano in southern Peru based on extensive fieldwork and a large dataset of geochronological (K-Ar, 40Ar/39Ar, U-Pb, and 14C) and geochemical (major and trace element) analyses. This compound volcano is composed of two edifices that have experienced discontinuous volcanic activity from the middle Pleistocene to the Holocene. The Calientes volcano has been constructed in four successive stages: Calientes I is composed of andesitic lava flows dated at ~500 ka. Subsequently, the Callazas ignimbrite (Calientes II stage) was emplaced ~160–190 ka, followed by the main cone-building stage (Calientes III) at ~130–100 ka. Finally, the Holocene Calientes domes were emplaced and represent the last eruptive products of this edifice. The Yucamane volcano has been constructed in three stages: Yucamane I consists of a succession of andesitic lava flows exposed at the base of the volcano that are older than 40 ka. Yucamane II (~36–30 ka) comprises a thick sequence of block-and-ash-flow deposits that represents an episode of dome growth predating the younger Yucamane cone (Yucamane III) built after 20–25 ka. During the Holocene, Yucamane vulcanian to sub-Plinian activity has emplaced tephra-fall and pyroclastic-density-current deposits. The most recent explosive eruptions occurred ca. 3000 BP and emplaced a tephra-fall and pumice-flow deposits. Most samples from Calientes volcano are andesites and dacites (60.1–67.7 wt% SiO 2), while rocks from Yucamane volcano are basaltic-andesites to dacites (53.4–66.9 wt% SiO 2). The rocks have a mineral assemblage of plagioclase, amphibole, biotite, orthopyroxene, clinopyroxene, olivine, and Fe-Ti oxides. The analyzed samples are categorized within a high-K, calc-alkaline series. Calientes volcano erupted mostly andesitic magmas, but its history is punctuated by rare eruptions of silica-rich magmas. In contrast, Yucamane volcano follows a different trend characterized by a gradual decrease in silica content through post-glacial time, from the large (VEI 3) sub-Plinian andesitic eruption of ~3 ka to moderate (VEI ≤ 2) vulcanian eruptions of basaltic-andesitic. On the basis of such recurrent and recent (Holocene), low-to-moderate explosive activity, Yucamane must be considered an active and potentially threatening volcano, which may affect the province of Candarave with ~8000 inhabitants. • Yucamane-Calientes is a compound volcano composed of two edifices of middle Pleistocene to the Holocene • Calientes formed in 4 stages from ~500 ka to the Holocene while Yucamane formed in 3 stages from ~40 ka to the Holocene • Samples from both volcanoes are high-K calc-alkaline andesites and dacites • During the Holocene, Yucamane displayed vulcanian to sub-plinian eruptive styles that emplaced tephra-fall and PDC deposits • Yucamane-Calientes should be considered as a potentially hazardous volcano [ABSTRACT FROM AUTHOR]

Sabancaya volcano is the youngest and second most active volcano in Peru. It is part of the Ampato-Sabancaya volcanic complex which sits to the south of the ancient Hualca Hualca volcano and several frequently active faults, thus resulting in complex volcano-tectonic interactions. After 15 years of repose, in 2013, a series of 4 earthquakes with magnitude >4.5 occurred within 24 h, marking the beginning of a new episode of unrest. Several additional swarms of earthquakes occurred in the following years until magmatic eruptive activity started on 6 November 2016. This activity is ongoing as of this writing, with an average of 50 explosions per day. In this study, we present results of multiparametric monitoring of Sabancaya's activity observed during 2013–2020. Seismic data are used to create a one-dimensional seismic velocity model, to catalog, locate, and characterize earthquakes, to detect repeating earthquake families, and to monitor seismic velocity variations by ambient noise cross-correlation. These analyses are complemented by visual and remote sensing observations and ground deformation measurements. All monitored parameters showed significant changes on 6 November 2016, the day of eruption onset, thus dividing the eruptive activity into pre-eruptive and eruptive stages. The unrest is characterized by high levels of seismic activity with hundreds of events detected per day. Volcano-tectonic (VT) earthquakes were dominant during the pre-eruptive period while long-period (LP) events and explosions have been most numerous since the eruption onset. Earthquake locations highlight long-lasting seismogenic zones along multiple previously active regional faults, as well as along newly identified faults. This VT seismicity is mainly distributed in a sector from the northwest to the east of the volcanic complex at distances of up to 30 km from the crater. We focus our analysis on two eruptive episodes: the eruption onset and subsequent crater migration from south to north, and the increase of lava dome extrusion rate in 2019. Both episodes are accompanied by seismic velocity decreases of up to 0.2% and are preceded by a few weeks by bursts of distal VT activity, including numerous repeating earthquakes. These repeated events were located on several remote tectonic faults (5–25 km from the vent). We suggest that these phenomena could be due to the injection of a batch of magma in the deep reservoir and/or conduit, which would generate 1) a pressure wave propagating in the hydrothermal system, triggering the bursts of seismic activity and 2) slow rising of magma by melting old material filling the conduit that eventually produced the eruptive and dome growth acceleration events. • Precise source locations were obtained with new velocity model • Many earthquakes, several with magnitude >4, were located on regional faults • Intense seismic activity results from interactions between magmatic processes, tectonic environment, and hydrothermal system • Bursts and repeaters of VT and dVT events were observed before 2016 eruption onset and 2019 increase of dome extrusion rate • Pore pressure waves triggered remote ruptures [ABSTRACT FROM AUTHOR]

To better understand the recent internal structure of Misti volcano, we determined a 3D S-wave velocity model applying Ambient Noise Tomography (ANT). We used data from 23 broadband and short-period seismic stations temporarily installed at Misti volcano between March and December 2011. This dataset allowed us to obtain empirical Green's functions by cross-correlating seismic ambient noise signals. Then, we retrieved 104 dispersion curves using the frequency-time analysis (FTAN) and, through a non-linear multiscale inversion, we obtained nine 2-D Rayleigh waves group velocity maps for periods in the range 0.7 s - 2 s. Finally, we carried out the depth inversion through a Bayesian transdimensional inversion to obtain a 3-D S-wave velocity model down to 3 km depth. Our study highlights five relevant seismic velocity anomalies. We observed the presence of three high-velocity zones located in the west-northwest, southwest and southeast parts of the crater, that could be related to intrusive bodies possibly associated with the formation of Misti volcano. We also observed two low-velocity anomalies in the volcano's western and central parts, which coincide with previous studies' findings and are related to fractured and weakened materials associated with the external caldera collapse and recent eruption episodes. • The ambient noise tomography of Misti volcano reveals a complex geological structure • The results show the presence of high-velocity anomalies that could be related to dense intrusive complexes of dikes. • Low-velocity zones reveal the presence of structures related to a caldera collapse. • Other low-velocity anomaly could be related to fracture zones produced by repeated eruptive episodes. [ABSTRACT FROM AUTHOR]