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This research is concerned with the investigation of Egyptian and Egyptianizing artifacts dating back to the period comprised between the 10th century BC and the first half of 6th century BC, which were found in some archaeological sites of eastern-central Sicily. The examined Aegyptiaca include thirt-four items consisting of scarabs, funerary statuettes, figurines and unguentaria, which are mostly preserved at the regional archeology museum "Paolo Orsi" in Syracuse and, only in part, at the regional Aeolian museum "Luigi Bernabò Brea" in the Lipari island. Some of the investigated objects are made of faience (a glazed non-clay ceramic material, coated with an alkali-based glaze), while some others are in steatite or other stones. Through the chemical investigation of the selected artifacts, the study aims to extend the compositional dataset available on Aegyptiaca, as well as to identify the colorants used for the preparation of the investigated glazes. For such a scope, non-destructive bulk chemical analyses through portable x-ray fluorescence spectrometry (pXRF) were carried out on both the bodies and the overlying coloured glazes. A rather variable chemical composition was found in terms of both bodies and glazes, thus pointing to the use of different recipes and/or workshops for the investigated artifacts. The results obtained demonstrate the validity of this analytical technique in revealing the elemental composition of artifacts belonging to museum collections. [ABSTRACT FROM AUTHOR]