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It is possible to assess the harm that society suffers as a consequence of groundwater contamination in aquifers. Indexing methodologies are commonly applied to assess the social vulnerability to polluted aquifers. However, they assign weighting and rating values to the different factors involved, which makes them very subjective. This research aims to assess the social vulnerability to groundwater pollution taking into account three factors: the uses of groundwater resources, the exposed population, and the socio-economic losses. In order to eliminate the subjectivity of current indexing methodologies, this work uses a K-means cluster analysis for the assessment of social vulnerability. With this method, a social vulnerability map can be produced with greater objectivity. The proposed methodology is applied to an aquifer located in central Spain, an area with significant agricultural development. Low population density and unproductive zones result in low social vulnerability in most of the area. However, high social vulnerability is observed in the southern sector due to agricultural development, which leads to higher socio-economic variables and demand for groundwater resources. Similarly, high social vulnerability is observed in the northeast, mainly influenced by the groundwater use and the exposed population. These results show that social vulnerability in most of the study area is not very significant for assessing the risk of groundwater contamination, because the damage to the social, environmental, or economic sector is low. However, in the south and northeast of the study area, pesticides and fertilizers should be used with caution, as they significantly increase the risk of groundwater contamination. The K-means clustering method proved to be an objective and reliable option for assessing social vulnerability to groundwater pollution in aquifers. [ABSTRACT FROM AUTHOR]

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A mathematical model of a highly heterogeneous functioning karst aquifer is described. The aquifer is in a high-relief karst massif and, as is common for such locations, data are scarce and there are no borehole, piezometer or pumping-test data. The scarcity of data in this case required a parsimonious approach to ensure that the level of complexity of the model was commensurate with the amount, type and quality of the available data. Parsimony also requires the model to include the minimum essential components that account adequately for the data, which in this and similar cases are the functional dualities of the karst system: duality in recharge, flow and discharge. The model is three-dimensional (3D) in the sense that the aquifer is discretized into 3D voxels, although the flow is one-dimensional (1D) and vertical in the vadose zone, and horizontal and two-dimensional (2D) in the saturated zone. The parsimonious model was designed by coupling a 1D unsaturated gravity-driven flow along the vertical (along each column of voxels that discretize the aquifer) and a 2D unconfined Darcy flow in the saturated zone. In the context of this type of aquifer, preferential recharge through the network of karst conduits implies a rapid rise in the water table, the location and extension of which are model parameters. The karst springs are simulated by drains. The methodology, which is completely general, is illustrated by application to the karst aquifer in the Sierra de las Nieves mountains in southern Spain. [ABSTRACT FROM AUTHOR]

The study presented here is a first qualitative assessment of the occurrence of organic contaminants contemplated and not yet contemplated in European Union environmental legislation in water resources in the little anthropized Guadiaro River basin (70% of its area is covered by natural vegetation), in southern Spain. Water samples were collected from four carbonate aquifers, two detrital aquifers and four surface water courses and were analyzed for (i) 171 organic contaminants, (ii) major ions and (iii) stable isotopes (δ18O H2O , δ2H H2O , δ13C DIC). An environmental risk assessment was conducted through calculation of risk quotients comparing measured concentrations with ecotoxicological data found in the literature. Twenty-five organic contaminants were detected, at least once, including pesticides, pharmaceuticals, drugs of abuse and polycyclic aromatic hydrocarbons (PAHs). Cocaine and its main metabolite were detected in 85% and 95% of water samples, respectively (0.001–0.18 μg/L and 0.004–0.6 μg/L, respectively). Pyrene (PAH) was found in all water samples (0.001–0.015 μg/L) and forest fires were pointed out as a potential diffuse source. Relationship between rivers and aquifers is reflected by the distribution of organic contaminants, essentially the drugs of abuse. Concentration of contaminants were generally higher in groundwater samples, especially from detrital aquifers, potentially due to an accumulation process promoted by irrigation-return flows and by its slow dynamic compared to that of karstic systems. Pyrene concentration was also higher in some springs from karstic aquifers. Hence, calculated risk quotients were in general higher in groundwater, meaning that the threat to surface aquatic systems can grow as aquifers increase their influence on the water courses as the dry season progresses. The relationship between δ13C DIC and most organic contaminants (especially pyrene) reveal the role of the soil as storage media. [Display omitted] • Fires-derived pyrenes could be considered a continuous pressure in the study area • Relation of contaminants and δ13C in water shows the soil's role as storage media • Detrital aquifers are the major indicators of potentially polluting processes • Distribution CECs is independent of environmental protection in the study area. • Risk quotients (RQ) are a good starting point for environmental risk assessment [ABSTRACT FROM AUTHOR]

In urban, industrial, and agricultural areas, a vast array of contaminants may be found because they are introduced into the aquifers by different recharge sources. The emerging contaminants (ECs) correspond to unregulated contaminants, which may be candidates for future regulation depending on the results of research into their potential effects on health and on monitoring data regarding their occurrence. ECs frequently found in wastewater, such as acetaminophen, carbamazepine, primidone, and sulfamethoxazole, may be good indicators of the introduction of the reclaimed water to the aquifers. The resistance of the ECs to removal in wastewater treatment plants (WWTPs) causes them to be appropriate sewage markers. Plana de Castellón (Spain) is a coastal area that has been characterized by intensive citrus agriculture since the 1970s. Traditionally, in the southern sector of Plana de Castellón, 100% of irrigation water comes from groundwater. In recent years, local farmers have been using a mixture of groundwater and reclaimed water from wastewater treatment plants (WWTPs) to irrigate the citrus. The aims of the present study were: (i) to assess the occurrences, spatial distributions, and concentrations of selected ECs, including 32 antibiotics, 8 UV filters, and 2 nonsteroidal anti-inflammatory drugs, in groundwater in a common agricultural context; (ii) to identify the recharge (pollution) sources acting as the origin of the ECs, and (iii) to suggest ECs as indicators of reclaimed water arrival in detrital heterogeneous aquifers. The obtained data provided relevant information for the management of water resources and elucidated the fate and behavior of emerging contaminants in similar contexts. [ABSTRACT FROM AUTHOR]

Nitrate is one of the most common groundwater contaminants in rural areas. In this work, the presence of high levels of nitrate in groundwater of the aquifers of the west part of Hoya de Huesca County (NE Spain) has been studied by coupling hydrogeological information with water sampling techniques through a wide areal sampling of 90 surface water and groundwater points belonging to several aquifers. The results showed a general hydrochemistry of calcium carbonate to calcium sulfate waters. Unlike other case studies in Mediterranean areas, in which nitrate pollution was associated with irrigated crops, the highest concentrations in the present study were found in dry farming areas in which winter cereal is grown. A monthly nitrate level monitoring, conducted in 21 selected points between 2016 and 2017, showed that the nitrate evolution pattern followed the N fertilizer application schedules in the sampling points in which the highest concentrations were recorded, whereas an annual regularity could be observed in the sampling points with low nitrate levels. The compilation of data for 16 selected points since 1990 shows that the problem is persistent and points to the need of implementing new aquifer pollution control measures, since the ones currently in force have not been successful. [ABSTRACT FROM AUTHOR]

The article presents the abstract of the paper "Impact of Pig Slurry on Soil Properties, Water Salinization, Nitrate Leaching and Crop Yield in a Four-Year Experiment in Central Spain," by J. A. Diezl, P. Hernaizl, M. J. Muñoz, A. de la Torre and A. Vallejo, which was published in the December 2004 issue of the periodical "Soil Use and Management." An accumulation of salts and a risk of aquifer pollution due to nitrate leaching and salinization may result from repeated application of pig slurry to agricultural soils. The study examined the effects of applying optimal and excessive rates of pig slurry on soil salinization, nitrate leaching and groundwater pollution.