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Emerging contaminants such as synthetic musks and UV-filters as ingredients personal care products were widely used in human daily life in Thailand. The occurrence and fate of four synthetic musks and nine UV-filters were investigated in eight full-scale sewage treatment plants (STPs) and their receiving aquatic environments in Bangkok and Pattaya, Thailand. All target compounds were detected in every single sample from STPs and surface water with magnitude from ng/L to μg/L. HHCB-lactone and HMS were found as the predominant musk and UV filter in influent and effluent of STPs, respectively. HHCB-lactone was also found with the highest concentration up to 79501 ng/g (dw) in the sludge. Low removal efficiency range from −37% (HHCB-lactone) to 58% (AHTN) were found for four musks in the STPs. The total emission of Σ 4 musks and Σ 9 UV-filters were estimated to be up to 16.7 mg/person/day and 0.28 mg/person/day by the STPs. Three synthetic musks and seven UV-filters were detected in fish from the receiving river. Concentration and emission of musks and UV filters found in this study from Thailand were much higher than those reported in many other countries worldwide. The preliminary ecological risk assessment showed that Musk xylene, 4-MBC and OC may pose high risk to aquatic organisms in the riverine and estuarine environment in Thailand. Image 1 • Four musks and nine UV filters were 100% detected in eight major STPs and the receiving environments in Thailand. • HHCB-lactone and HMS were found as the predominant musk and UV filter in influent, effluent and receiving water. • The total emission of Σ 4 musks and Σ 9 UV-filters were estimated to be up to 16.7 and 0.28 mg/person/day by the STPs. • Three synthetic musks and seven UV-filters were detected in fish from receiving river. • Musk xylene, 4-MBC, UV-P and OC may pose high risk to aquatic organisms in Thailand. [ABSTRACT FROM AUTHOR]

This study investigated the occurrence and fate of 19 biocides in 8 wastewater treatment plants and receiving aquatic environments (both freshwater and estuarine systems) in Thailand. The predominant compound in wastewater and surface water was methylparaben with the maximum concentration of 15.2 μg/L detected in the receiving river, while in sludge and sediment was triclocarban with the maximum concentration of 8.47 μg/g in sludge. Triclosan was the main contaminants in the fish samples with the maximum concentration of 1.20 μg/g. Similar results of biocides were found in the estuarine system in Pattaya city, with the maximum concentration of 185 ng/L in sea water for methylparaben, and 242 ng/g in estuarine sediment for triclocarban. The aqueous removal rates for the biocides ranged from 15% to 95% in average. The back estimated-usage and total estimated emission of Ʃ19 biocides in Thailand was 279 and 202 tons/year, respectively. Preliminary ecological risk assessment showed that clotrimazole and triclosan could pose high risks to aquatic organisms in the receiving aquatic environments., (Copyright © 2019 Elsevier B.V. All rights reserved.)