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The relationship between mafic magmatic enclaves (MMEs) and host granitoids is ongoing debate due to their significant roles in understanding deep magmatisms and geodynamic processes. This paper reports on Early Palaeozoic granitoids and associated MMEs from the Delingha pluton in the South Qilian Accretionary Belt (NW China) to constrain their petrogenesis and draw implications. The MMEs, occurring as ellipsoidal to rounded shapes, are andesitic and have the same crystallization age (~445 Ma) and mineral assemblage as the host granitoids. However, minor isotopic differences between them and compositional and textural disequilibria on minerals (e.g. plagioclase and amphibole) do not support a cumulate origin that the MMEs were formed at earlier stage of the same magmatic system, but forcefully reflect magma hybridization processes between mafic and felsic magmas, during which the hybridized magma was broken up into discrete enclaves by convective motion in the host felsic magma. Accordingly, the primitive compositions of the MMEs likely originated from metasomatized mantle wedge source, while mantle-derived melt underplated and partially melted the lower continental crust to form the host rocks with a certain mantle contribution. Thus, the Delingha pluton is the product of crust-mantle interaction at an active continental margin subduction setting rather than syn-collisional environment, indicating that subduction of the South Qilian Ocean located between the Central Qilian Block and the Oulongbuluke Block may have lasted till to ~445 Ma. [ABSTRACT FROM AUTHOR]