1. Poly(acrylic acid)-templated silver nanoclusters as a platform for dual fluorometric turn-on and colorimetric detection of mercury (II) ions
- Author
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Tao, Yu, Lin, Youhui, Huang, Zhenzhen, Ren, Jinsong, and Qu, Xiaogang
- Subjects
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POLYACRYLIC acid , *CHEMICAL templates , *COLLOIDAL silver , *FLUORIMETRY , *ELECTROCHEMICAL sensors , *MERCURY , *METAL ions , *FLUORESCENCE - Abstract
Abstract: An easy prepared fluorescence turn-on and colorimetric dual channel probe was developed for rapid assay of Hg2+ ions with high sensitivity and selectivity by using poly(acrylic acid)-templated silver nanoclusters (PAA-AgNCs). The PAA-AgNCs exhibited weak fluorescence, while upon the addition of Hg2+ ions, AgNCs gives a dramatic increase in fluorescence as a result of the changes of the AgNCs states. The detection limit was estimated to be 2nM, which is much lower than the Hg2+ detection requirement for drinking water of U.S. Environmental Protection Agency, and the turn-on sensing mode offers additional advantage to efficiently reduce background noise. Also, a colorimetric assay of Hg2+ ions can be realized due to the observed absorbance changes of the AgNCs. More importantly, the method was successfully applied to the determination of Hg2+ ions in real water samples, which suggests our proposed method has a great potential of application in environmental monitoring. [Copyright &y& Elsevier]
- Published
- 2012
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