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The Qixiashan Pb–Zn deposit, Jiangsu Province ( 1212011220678 ), is hosted in Huanglong Formation limestones and is one of the largest Pb–Zn deposits in the Lower Yangtze region, China, which is an important Cu–Pb–Zn metallogenic belt. Here we report in situ sulfur isotopic analyses of sulfides using LA - ICP - MS method, together with fluid inclusion data. Three types of pyrite mineralization were identified in the host rocks and ores, corresponding to three genetic stages: (1) fine-grained framboidal or colloform pyrite hosted in limestone (Py1); (2) fine-grained euhedral–subhedral pyrite (Py2) associated with brown sphalerite (Sph1), occurring as massive sulfide ores; and (3) coarse-grained euhedral–subhedral pyrite (Py3) associated with yellow–brown sphalerite (Sph2) in breccia-type or massive ores. Stages 2 and 3 constitute the main Pb–Zn-forming event. Depending on the stage in which they were formed, the sulfides exhibit different sulfur isotope values, implying different ore-forming processes. The Stage 1 Py1 was formed by bacterial sulfate reduction and yields extremely low δ 34 S values, in the range −14.39‰ to −3.08‰. Stage 2 Py2 and Sph1 have δ 34 S values ranging from 6.5‰ to 9.4‰ and from 5.0‰ to 8.3‰, respectively. Stage 3 Py3 and Sph2 have δ 34 S values of 1.3‰ to 3.2‰ and −0.05‰ to 2.5‰, respectively. The δ 34 S value of pyrite is greater than that of sphalerite for each coexisting pyrite–sphalerite pair, indicating that sulfur isotope equilibrium was reached between these minerals. The total δ 34 S values and formation temperatures of the ore fluids in Stages 2 and 3 were 9.4‰ and 173 °C–279 °C, and 2.3‰ and 195 °C–328 °C, respectively. The high total δ 34 S in Stage 2 ore fluids was a result of the interaction of magmatic fluids with marine sulfur, whereas the low total δ 34 S in Stage 3 ore fluids reveal that these fluids were derived from magmatic water only. Two-phase liquid-rich aqueous inclusions in Stage 2 sphalerite (Sph1) yield homogenization temperatures and salinities of 182 °C–284 °C and 0.9–8.8 wt% NaCl equivalent, respectively. Such inclusions in Stage 3 sphalerite (Sph2) yielded higher homogenization temperatures (207 °C–306 °C) and higher salinities (0.4–12.3 wt% NaCl equivalent), suggesting an increase in magmatic–hydrothermal activity from Stage 2 to 3. Such high-salinity fluids may be produced by magmatic water exsolving from a concealed intrusion beneath the Qixiashan ore district. On the basis of ore fluid temperatures and total δ 34 S values, sulfides in Stage 2 (δ 34 S = 9.4‰, T = ~250 °C) are inferred to have precipitated under conditions of pH 2–6 and log f O 2 −38 to −33, and sulfides in Stage 3 (δ 34 S = 2.3‰, T = ~350 °C) are inferred to have precipitated under conditions of pH 2–6 and log f O 2 −31 to −27. The textural, fluid inclusion, and sulfur isotopic evidence indicate that the Qixiashan Pb–Zn orebody is a hybrid deposit (rather than a SEDEX or magmatic–hydrothermal deposit) that formed by syngenetic sedimentary deposition and hydrothermal overprinting. [ABSTRACT FROM AUTHOR]

Fluid-inclusion and stable isotope studies were carried out on five types of Mesozoic (Yanshanian) hydrothermal copper-gold deposits in the lower Yangtze River Valley. Deposits include (1) copper in cryptoexplosive breccia pipes, (2) skarn copper, (3) porphyry copper, (4) high-temperature quartz vein-type copper and gold, and (5) medium-lower temperature fracture zone gold. This research has allowed a comparison between various types of ore-forming fluids. Melt-fluid inclusions in garnet from the matrix of the breccia pipe at the Shizishan copper deposit reveal the existence of a water-rich magma. In all deposit types, fluid temperatures and salinities were higher at early stages and generally decreased with time. Magmatic water is dominant in the high-temperature ore-forming fluids, whereas meteoric water was involved only in the medium-lower temperature Xiaomiaoshan gold deposit and in the post-mineralization stage of the Shaxi porphyry copper deposit. Fluid boiling played an important role in the mineralization of most deposits, particularly at Shizishan, where multi-stage boiling was associated with the formation of cryptoexplosive breccia, skarn, quartz-sulphide, and quartz-carbonate-sulphide stages. Boiling of an aqueous magmatic fluid system at high temperatures reflects the release of crystallization heat and increase of total volume of the magma-fluid system, and hence it can be referred to as active boiling. On the contrary, boiling of a fluid at lower temperatures is typically triggered by pressure release due to fracturing or dilation in the surrounding rocks, and is thus referred to as passive boiling. In general, passive boiling occurs more commonly at the higher levels of a hydrothermal mineral system and at later stages of the ore-forming process. [ABSTRACT FROM AUTHOR]