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Surface sediment samples collected off the Huanghe (Yellow) River mouth during the period 2007-2009 were analyzed for major and trace element concentrations. Concentrations of 16 elements were measured using X-ray fluorescence spectrometry. Results demonstrate that sediment grain size is the dominant factor controlling the spatial variations of elemental concentrations. Correlation and cluster analyses allowed classification of the study area into four geochemical regions: Regions I and III are characterized by high concentrations of AlO, FeO, MgO, NaO, KO, Cr, Cu, Mn, Ni, Pb, V, and Zn, and contain fine-grained sediments with mean grain size ( M)<22 μm; and; Regions II and IV contain mostly coarse-grained sediments, and are characterized by high concentrations of SiO, NaO, and Zr. The sediment entering the sea from the Huanghe River and its tributaries is enriched in Ca. Thus, the Ca/Al ratio was used as an indicator of the proportion of sediments in the study area that originated from the Huanghe River. Ca/Al ratios decrease from Regions I and II (located in the nearshore zone of the Huanghe River delta) to Regions III and IV (distributed in the offshore zone of the northern Huanghe River delta, southern and southeastern Laizhou Bay area). [ABSTRACT FROM AUTHOR]

Abstract: Two gravity cores collected off the modern Huanghe (Yellow River) delta in the southern Bohai Sea were analyzed for grain size, the total organic carbon (TOC)/total nitrogen (TN) ratio, color diffraction, magnetic susceptibility, 14C dating and 137Cs and 210Pb isotope contents to clarify changes in the sedimentary environment during the Holocene. In particular, the effect of natural and artificial river-course shifts of the Huanghe on the Bohai Sea sediment was investigated. A peat layer, scouring surface and sharp changes in the grain size, TOC/TN ratio, sediment color (L ⁎, a ⁎) and magnetic susceptibility were identified and are likely to be due to the early-Holocene sea-level rise resulting in environmental changes from coastal to shelf environments in the Bohai Sea. After the sea level reached its maximum at 6–7kaBP, the lateral shifts in the river course of the Huanghe formed 10 superlobes, and superlobe 7 (11–1048 AD) and superlobe 10 (1855–present) of the Huanghe delta affected the core sites. The northern site of BH-239 has been more affected by the Huanghe since the middle Holocene. Notably, in the superlobe 10 period, the reshaping of the northern Huanghe delta due to an artificial river-course shift from northward to eastward in 1976 (e.g., a∼10km shoreline retreat due to coastal erosion) was recorded in the core sediments, particularly in terms of the TOC/TN ratio, sediment color (L ⁎ and a ⁎) and magnetic susceptibility, owing to the huge sediment supply from coastal erosion of the former river mouth area. [Copyright &y& Elsevier]