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302. A novel scandium ortho-methoxynitrosobenzene-dimer complex: mechanistic implications for the nitroso-Diels-Alder reaction.

Author

Lightfoot AP, Pritchard RG, Wan H, Warren JE, and Whiting A

Abstract

Arylnitroso dienophiles exist in equilibrium with their dimeric counterparts, which in turn form stable bidentate complexes with scandium(III) triflate and react with cyclohexadiene to give the corresponding Diels-Alder adduct at the same rate as the normal thermal process.

Published
2002
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