301. Thermal conductivity of Ce3+ doped (Y,Gd)3Al5O12 ceramic phosphor.
- Author
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Wen, Bo, Zhang, Ding-fei, Jiang, Bin, Pan, Fu-sheng, Zhang, Yuhe, and Yang, Liu
- Subjects
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THERMAL conductivity , *YTTRIUM aluminum garnet , *PHOSPHORS , *PHONON scattering , *GADOLINIUM , *URANIUM - Abstract
Ceramic phosphor plates of (Y,Gd) 3 Al 5 O 12 :Ce (or YAG:Ce) are considered better wavelength converters for high power light-emitting-diode (LED) and laser-diode (LD) lighting applications due to their significantly better thermal conductivities and heat resistance as compared to phosphor powder/epoxy films. In this work, we have measured the thermal conductivities of Ce3+ doped (Y 1-x Gd x) 3 Al 5 O 15 (x from 0 to 1) ceramic phosphor plates at temperatures of 296 K and 473 K. As temperature increases from 296 K to 473 K, the thermal conductivities decrease by about 37%. They are also strongly dependent on the concentration of Gd3+, or x in (Y 1-x Gd x) 3 Al 5 O 15. They decrease with x increasing first, reaching a minimum at x between 0.4 and 0.6, and then increase with x as it continues to increase to 1. The dependence of the thermal conductivity on Gd3+ concentration is not linear but a "U" type, suggesting that substitution of Y3+ with Gd3+ may cause extra phonon scattering, resulting in lower thermal conductivities as compared to their intrinsic values. A quantitative relationship between thermal conductivity and Gd3+ concentration is derived for this material system. • Thermal conductivities of (Y 1-x Gd x) 3 Al 5 O 12 :Ce have been measured at 296 K and 473 K. • Substitution of Y3+ with Gd3+ changes thermal conductivities of (Y,Gd) 3 Al 5 O 12 :Ce. • Quantitative relationship of thermal conductivity vs Gd concentration is established. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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