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We report a narrow linewidth and low threshold single-frequency distributed Bragg reflector (DBR) fiber laser at 1120 nm based on a short 1.5 cm long Nd-doped silica fiber which, to the best of our knowledge, is the first demonstration of a Nd-doped fiber-based single-frequency fiber laser with a wavelength greater than 1100 nm. A stable single-longitudinal-mode laser operation with a signal-to-noise ratio greater than 67 dB was verified by a scanning Fabry-Perot interferometer. The laser threshold is as low as 10 mW. The DBR fiber laser has a maximum output power of 15 mW and optical-to-optical efficiency for the launched pump power reaches more than 8%. The narrow linewidth of 71.5 kHz is obtained in such a single-frequency fiber laser (SFFL). Our result is expected to offer an exciting new opportunity to realize high-performance SFFLs above 1100 nm.

Parkinson's disease (PD) is a complex neurodegenerative disease affected by diverse factors, and lipid droplets (LDs) are increasingly recognized as major players in PD because of their relevance to neuron activity. However, long-term dynamic changes of LDs and their relative activity remain unclear. Here, an aggregation-induced emission (AIE) probe named 2-DPAN was prepared and employed to visualize dynamic processes of LDs in a 6-hydroxydopamine model of PD for the first time, and LDs' accumulation-peak/plateau-decrease were confirmed. We further found a close relationship between LDs and variation in mitochondrial activity. Strikingly, the progression of cell death was accelerated by lipase, whereas pre-stimulation of LDs by unsaturated fatty acid-oleic acid decreased the death process by inhibiting excessive reactive oxygen species (ROS) and fatty acid production, thereby protecting mitochondria. The utilization of 2-DPAN demonstrates the importance of LDs in neuronal homeostasis, and effective tuning of LDs may prevent or inhibit PD progression., (Copyright © 2019 The Author(s). Published by Elsevier Inc. All rights reserved.)

Bismuth (Bi)-doped materials are a new family of laser materials, and they usually exhibit extremely broad near-infrared (NIR) luminescence in 1000-1700 nm. Therefore, they can be utilized for a new generation of ultra-broadband tunable laser sources and ultra-broadband fiber amplifier. The broadband characteristics of Bi-active NIR luminescence can meet the needs of special wavelength laser sources that rare-earth-doped lasers cannot provide. However, at present, the Bi-doped NIR luminescence materials are mainly concentrated on glass, while Bi-doped NIR luminescence laser crystals are rarely reported. In this work, a novel Bi-doped crystal Sr 2 B 5 O 9 Cl:Bi is reported with NIR luminescence, which exhibits broadband absorption in ultraviolet and visible regions, and can produce ultra-broadband from red to NIR luminescence covering 600-1600 nm. The results of excitation, emission spectra, and fluorescence lifetime show that the Sr 2 B 5 O 9 Cl:Bi crystal contains three different Bi-active NIR emission centers. This work could enrich our understanding on Bi NIR emission behaviors in crystals. And this material provides a possibility for the development of a new laser source.

The fiber laser in the range of 900-1000 nm is essential to generate the blue fiber laser through frequency doubling for the laser display, laser underwater communications, and laser lighting. Yet, the well-developed three-level Yb-doped fiber laser can only realize the blue-green fiber laser at around 490 nm, which is far from the pure blue area (450 nm). To further achieve the pure blue fiber laser, the Nd-doped fiber has emerged as a proper choice to realize a shorter wavelength laser (<920  nm) through the F 3/2 4→I 9/2 4 transition of Nd 3+ . Here, based on the facile "melt-in-tube" (MIT) method, a novel Nd-doped high alumina and yttria glass @ silica glass hybrid fiber was successfully prepared using the Nd:YAG crystal as the precursor core. The crystal core converts to the amorphous glass state after the drawing process, as evidenced by Raman spectra. The gain coefficient at 915 nm of the hybrid fiber reaches 0.4 dB/cm. Further, the laser oscillation at 915 nm with over 50 dB signal-to-noise ratio was realized by a short 3.5 cm gain fiber. Our results indicate that MIT is a feasible strategy to produce novel fiber for generating fiber laser at special wavelengths.

Computer tomography (CT) and magnetic resonance imaging (MRI) are noninvasive cancer imaging methods in clinics. Hence, a material that enables MRI/CT dual-modal imaging-guided therapy is in high demand. Currently, the available materials lack active tumor targeting, deep tumor penetration, and ultralong tumor retention and may lose their imaging elements. To overcome these drawbacks, herein, nanoparticles (NPs) were deveopled by integrating an MRI contrast-enhancing chelated gadolinium (Gd) complex within a doxorubicin (DOX)-loaded protective silica shell as well as a CT imaging/photothermal biocompatible bismuth (Bi) nano-core, which surface-displayed an MCF-7 breast tumor-homing peptide (AREYGTRFSLIGGYR, termed AR); we found that the resultant NPs AR-Bi@SiO 2 -Gd/DOXNPs could home to and penetrate deep into the tumors with the unexpected ultralong retention of at least 14 days (as determined by CT/MRI imaging) and the tumor retention half-life of 104.5 h (as determined by ICP-MS analysis) under the guidance of the AR peptide. These NPs can be further used to image tumors with significantly increased sharp contrasts via both CT and MRI, which are much better than the commercial standard contrast agents; moreover, they significantly inhibit tumor growth via the synergistic action of both Bi-enabled photothermal therapy and DOX-induced chemotherapy. The NPs are cleared by the spleen, liver and kidney and then excreted from the body along with faeces and urine. The precise tumor targeting and ultralong tumor retention of these unique NPs would enable both precise tumor detection for early diagnosis and signal-persistent tumor tracking for monitoring the treatment with only a single injection of these NPs., Competing Interests: Conflicts of interest There are no conflicts to declare.

Narrow band red-emitting Mn 4+ -doped fluoride phosphor is an essential red component of modern white-light-emitting-diode (WLED) devices. Its luminescence has sensitivity to structure and influences the performance of WLED. In this paper, we report a high-performance Mn 4+ phosphor based on a new heterodialkaline fluorogermanate, CsNaGeF 6 :Mn 4+ . As determined by the single-crystal X-ray diffraction analysis, the CsNaGeF 6 compound crystallizes in the orthorhombic crystal system with space group Pbcm (No. 57). Under excitation by 360 and 470 nm photons, CsNaGeF 6 :Mn 4+ emits intense red light near 630 nm with a high quantum yield of 95.6%. The electronic energy levels of the Mn 4+ ion in Cs 2 GeF 6 , Na 2 GeF 6 , and CsNaGeF 6 are calculated using the exchange charge model of crystal-field theory. The local Mn 4+ environment inducing different zero-phonon-line emissions in the structures is probed by electron paramagnetic resonance. The Mn 4+ -doped heterodialkaline fluorogermanate CsNaGeF 6 :Mn 4+ exhibits broader emission as a result of the lowest symmetry. It has higher quantum yield than Na 2 GeF 6 :Mn 4+ and higher spectral luminous efficacy than Cs 2 GeF 6 :Mn 4+ . Given the good thermal stability and efficient luminescence, a prototype warm-WLED device with a color rendering index of 92.5, a correlated color temperature of 3783 K, and a luminous efficacy of 176.3 lm/W has been fabricated by employing the CsNaGeF 6 :Mn 4+ phosphor as the red component. Our results not only reveal that a high-performance Mn 4+ red phosphor is achieved through cationic substitutions but also construct a relationship of performance-structure to guide the design of Mn 4+ phosphors in the future.

We report an unusual thermal response of tellurium (Te) near-infrared (NIR) luminescence in phosphate laser glass, where the luminescence first increases and then decreases with heat-treatment temperatures increasing from 250°C to the glass transition temperature (T g ). This is followed by a distinct revival of Te NIR luminescence at temperatures above T g . This result differs from the scenario in conventional rare-earth (Er 3+ , Nd 3+ , and Yb 3+ )-doped phosphate glasses, where the rare-earth NIR emission decreases with increasing heat-treatment temperature. The difference may originate from conversion between Te 4 and other Te species, which depends on the evolution of the glass structure and molecular motion during the reheating processes, leading to unusual thermal response of Te NIR luminescence. The increase in Te 4 clusters enhances Te NIR emission, indicating that Te NIR luminescence is assigned to the Te 4 cluster, in contrast to previous studies. Heating and cooling cycles between 50°C and 250°C reveal strong dependence of the thermal degradation on glass structure. Te-doped phosphate laser glass with zero thermal degradation can be realized by stabilizing NIR luminescence center Te 4 by adjusting the glass structure with reduced network crosslinking. The superior optical performance has been confirmed in our previous study that the NIR luminescence properties can be well maintained in Te-doped fiber. The findings indicate that Te-doped phosphate glass with unusual thermal responses can potentially be used in fiber laser devices.

Knowledge of site occupation of activators in phosphors is of essential importance for understanding and tailoring their luminescence properties by modifying the host composition. Relative site preference of Eu 2+ for the two distinct types of alkaline earth (AE) sites in Ba 1.9995- x Sr x Eu 0.0005 SiO 4 ( x = 0-1.9) is investigated based on photoluminescence measurements at low temperature. We found that Eu 2+ prefers to be at the 9-coordinated AE2 site at x = 0, 0.5, and 1.0, while at x = 1.5 and 1.9, it also occupies the 10-coordinated AE1 site with comparable preference, which is verified by density functional theory (DFT) calculations. Moreover, by combining low-temperature measurements of the heat capacity, the host band gap, and the Eu 2+ 4f 7 ground level position, the improved thermal stability of Eu 2+ luminescence in the intermediate composition ( x = 1.0) is interpreted as due to an enlarged energy gap between the emitting 5d level and the bottom of the host conduction band (CB), which results in a decreased nonradiative probability of thermal ionization of the 5d electron into the host CB. Radioluminescence properties of the samples under X-ray excitation are finally evaluated, suggesting a great potential scintillator application of the compound in the intermediate composition.

Mechanoluminescent (ML) materials are mechano-optical converters that can emit light under an external mechanical stimulus. All the existing ML materials can only emit light from near ultraviolet to red, which is outside the near-infrared (NIR) windows desired for biomechanical imaging. No studies have been done on doping rare earth (RE) ions with photoluminescence (PL) in the NIR region into a compound to form a ML material that emits NIR light in response to an external force. Here, we show that doping RE ions with a NIR PL into an inorganic compound does not usually result in the formation of a NIR ML material, which can only be achieved in the combination of Nd 3+ ions and a CaZnOS compound among the combinations we studied. The newly discovered NIR ML material (CaZnOS:Nd 3+ ) is biocompatible and can efficiently convert mechanical stress into NIR light over the first and second tissue-penetrating bioimaging window. Its NIR ML emission appeared at a very low force threshold (even when the material was shaken slightly), increased sensitively and linearly with the increase in the force (up to >5 kN), and could penetrate the tissue as deep as >22 mm to enable biomechanical detection. Such a force-responsive behavior is highly reproducible. Hence, CaZnOS:Nd 3+ is a new potential ultrasensitive biomechanical probe and expands the ML application horizons into in vivo bioimaging.

Bi 3+ -activated photonic materials have received increased interest recently because they can be excited effectively with near-ultraviolet (NUV) but not visible light, thereby avoiding the reabsorption among phosphors, which cannot be solved intrinsically by traditional rare earth (e.g., Eu 2+ , Ce 3+ ) phosphors. Such unique property suggests their potential application in NUV chip-based WLEDs. However, few Bi 3+ phosphors exhibit strong excitation peak in NUV, though the excitation tail of some can extend to NUV. Herein, we report a novel yellow-emitting La 3 BWO 9 :Bi 3+ (LBW:Bi 3+ ) phosphor with strong NUV excitation. The photoluminescence (PL) spectroscopy analysis indicates that there are two Bi 3+ luminescent centers in LBW:Bi 3+ phosphor, which is clearly in contradiction with the established hexagonal structure of La 3 BWO 9 with P6 3 space group because only one La site in this structure can accommodate Bi 3+ ions. Combining the luminescent properties of Bi 3+ with Rietveld refinement, La 3 BWO 9 was redefined as a trigonal structure with the lower space group of P3 in which there are two independent crystallographic La sites. In addition, the rationalization of P3 space group was further confirmed by the finding of the reflection (0001) according to the extinction rule. Therefore, the PL behavior of Bi 3+ can act as a complementary tool to determinate the real crystal structure especially when it is hard to distinguish by conventional X-ray diffraction techniques.

Actively targeted hollow nanoparticles may play key roles in precise anti-cancer therapy. Here, unique Cu 39 S 28 hollow nanopeanuts (HNPs) were synthesized via a facile one-step method and the formation mechanism was illustrated. The as-synthesized Cu 39 S 28 HNPs exhibit outstanding photothermal conversion efficiency (41.1%) and drug storage capacity (DOX, 99.5 %). At the same time, the DOX drug loading nanocomposites have shown great sensitive response of release to either pH value or near infrared ray (NIR). In particular, the folic acid (FA) can easily conjugate with the synthesized Cu 39 S 28 HNPs without further modification to get a targeted effect. The FA modified Cu 39 S 28 HNPs showed an efficiently targeting effect in vitro and could considerably enhance the tumor-targeting effect more than 10 times in vivo . Moreover, the synthetical hyperthermia and drug release from Cu 39 S 28 HNPs when under 808 nm laser could significantly improve the therapeutic efficacy compared with photothermal or chemotherapy alone both in vitro and in vivo . The histological studies in main organs also proved the well biocompatibility, while the tumor sites were in seriously destruction due to the accumulation of the nanocomposites and the combined photothermal chemo therapy effect. Therefore, the multi-functional nanocomposites is excellent antitumor agents due to their superb therapy effect in breast cancer.

A kHz-order linewidth controllable 1550 nm single-frequency fiber laser (SFFL) is demonstrated for the first time to our best knowledge. The control of the linewidth is realized by using a low-pass filtered white Gaussian noise (WGN) signal applied on a fiber stretcher in an optical feedback loop. Utilizing WGN signals with different signal amplitudes An and different cutoff frequencies fc, the linewidths are availably controlled in a wide range from 0.8 to 353 kHz. The obtained optical signal-to-noise ratio (OSNR) is more than 72.0 dB, and the relative intensity noise (RIN) at frequency greater than 40 MHz reaches -148.5 dB/Hz which approaches the shot noise limit (-152.9 dB/Hz). This kHz-order linewidth controllable SFFL is meaningful and valuable, for optimizing the receiver sensitivity and bit error rate (BER) performance of the coherent optical communication system based on high-order quadrature amplitude modulation (QAM).

An all-fiber high-power and broad-frequency-band near-shot-noise-limited kHz-linewidth (Δν ~1.7 kHz) single-frequency master-oscillator power amplifier (MOPA) laser at 1.5 μm is demonstrated. To significantly suppress the intensity noise of seed laser and mitigate the detrimental effects of amplified spontaneous emission and stimulated Brillouin scattering in fiber amplifiers, more than 23 W of a stable low noise single-frequency laser output is achieved with a relative intensity noise of < -150 dB/Hz @0.5 mW (near to the shot-noise limit: -152.9 dB/Hz) in the frequency band from 0.1 to 50 MHz. It is believed that the achieved laser performance of ultra-low intensity noise and high-power output make the laser source become a promising candidate in further applications, such as cold atom optical lattice, quantum key distribution, and gravitational wave detection.

The resistance to thermal quenching is an essential factor in evaluating the performance of luminescent materials for application in white light emitting diodes (WLEDs). In this work, we studied the site occupancy preference and thermal quenching of luminescence in β-Ca 2 P 2 O 7 :Bi 2+ red phosphor at low (10-300 K) and high temperatures (303-573 K). In β-Ca 2 P 2 O 7 , the host lattice has four different calcium sites, at which Bi 2+ dopant can be located. After comparing the change of bond energy when the Bi 2+ ions are incorporated into the four calcium sites, we found out that Bi 2+ would preferentially occupy the smaller energy variation sites Ci(2) and Ci(1) in this compound, which can be assigned to Bi(2) and Bi(1), respectively. Surprisingly, we noticed that the variation of emission intensity is different under different excitations when the temperature changes from 10 to 300 K. When exciting into the typical absorption of Bi(1) sites at 419 nm, the emission intensity at 300 K remains only 38% as compared to that at 10 K, while exciting into typical Bi(2) absorption at 460 nm, the emission intensity increases to 110%. When further increasing the temperature from 303 to 573 K, we observed a similar phenomenon, and the emission at 460 nm excitation starts to quench at 453 K. The emission intensity at 573 K still remains 86.1% of that at 303 K. This might be attributed to the Bi(2) → Bi(1) energy transfer. It is also evidenced by the time-resolved emission spectra and lifetime values. This work gives new insights into better understanding luminescent behaviors of Bi 2+ -doped materials with multiple cation sites. This should be helpful in the future when designing the bismuth doped phosphor for WLEDs with better resistance to thermal quenching.

We investigated the frequency noise in the distributed Bragg reflector single-frequency fiber laser (DBR-SFFL) theoretically and experimentally. A complete theoretical analysis is demonstrated by considering the energy-transfer upconversion (ETU) process and establishing linkages between the frequency noise and the relative intensity noise (RIN) of the DBR-SFFL. The experimental results of the diverse DBR-SFFLs in different working conditions are in good agreement with the theoretical analyses. These investigations are beneficial to optimizing frequency noise property to promote the wide application of the DBR-SFFLs. The proposed results can be generally applicable to the short-linear-cavity SFFL with centimeters order of the cavity length.

Following pioneering work, solution-processable Mn 4+ -activated fluoride pigments, such as A 2 BF 6 (A = Na, K, Rb, Cs; A 2 = Ba, Zn; B = Si, Ge, Ti, Zr, Sn), have attracted considerable attention as highly promising red phosphors for warm white light-emitting diodes (W-LEDs). To date, these fluoride pigments have been synthesized via traditional chemical routes with HF solution. However, in addition to the possible dangers of hypertoxic HF, the uncontrolled precipitation of fluorides and the extensive processing steps produce large morphological variations, resulting in a wide variation in the LED performance of the resulting devices, which hampers their prospects for practical applications. Here, we demonstrate a prototype W-LED with K 3 AlF 6 :Mn 4+ as the red light component via an efficient and water-processable cation-exchange green route. The prototype already shows an efficient luminous efficacy (LE) beyond 190 lm/W, along with an excellent color rendering index (Ra = 84) and a lower correlated color temperature (CCT = 3665 K). We find that the Mn 4+ ions at the distorted octahedral sites in K 3 AlF 6 :Mn 4+ can produce a high photoluminescence thermal and color stability, and higher quantum efficiency (QE) (internal QE (IQE) of 88% and external QE (EQE) of 50.6%.) that are in turn responsible for the realization of a high LE by the warm W-LEDs. Our findings indicate that the water-processed K 3 AlF 6 may be a highly suitable candidate for fabricating high-performance warm W-LEDs.

Based on a self-injection locking scheme and the nonlinear amplification effect of a semiconductor optical amplifier, a low intensity noise amplified ultrashort cavity single-frequency fiber laser at 978 nm is demonstrated with a final output power of > 230 mW and a broad temperature range of > 15 °C for single-longitudinal-mode operation. The effective cavity length of the fiber oscillator is less than 6 mm, comprising a 3.5-mm-long highly Yb 3+ -doped phosphate fiber and a pair of fiber Bragg gratings. For the frequency range from 1.8 to 10 MHz, the relative intensity noise close to -150 dB/Hz is achieved. The signal-to-noise ratio of > 68 dB and the laser linewidth of < 10 kHz are obtained. Such narrow linewidth low noise 978 nm laser is promising, as the high-performance pump source or the efficient blue and UV light sources after nonlinear frequency conversion.

A spectrally clean kHz-linewidth single-polarization single-frequency distributed Bragg reflector Yb-doped phosphate fiber (YPF) laser at 1120 nm (> 1100 nm) for the first time is demonstrated. By enhancing the reflectivity of output fiber Bragg grating and optimizing the length of YPF to implement the effective ASE suppression and single-longitudinal-mode long-wavelength lasing, a stable output power of over 62 mW is achieved from a 31-mm-long highly YPF with a linewidth of 5.7 kHz. The signal to noise ratio of > 67 dB, the polarization extinction ratio of > 25 dB, and the relative intensity noise of < -150 dB/Hz for the frequencies above 10.0 MHz are obtained in such single-frequency fiber laser. This narrow linewidth fiber laser is an ideal laser source to generate the coherent single-frequency 560 nm light via frequency doubling for biochemical analysis application.

For application of bismuth laser glasses in either fiber amplifier or laser, their performance stability in long run should be understood especially in extreme conditions. However, so far, there are few reports on it. Here, we found, after the cycle experiments on heating and cooling, that the proper increase of lithium content in lithium tantalum silicate laser glass can lead to unusual anti-thermal degradation of bismuth NIR luminescence, which completely differs from the scenario in germanate glass. FTIR, 29 Si MAS NMR spectra, absorption and dynamic photoluminescence spectra are employed to unravel how this happens. The results illustrate that it should be due to the decrease of polymerization of silicate glass network, which in turn allows the regeneration at 250°C, and therefore, the content increase of bismuth NIR emission centers. In the meanwhile, we noticed though Bi luminescence can be thermally quenched its peak does not shift along with temperature, which seldom appears in laser materials. The unique property might guarantee the unshift of Bi fiber laser wavelength once such glass was made into fiber devices even as the environmental temperature changes. The role of lithium is discussed in the evolution of glass structures, the suppression of glass heterogeneity, and the thermal stability of Bi luminescence, and it should be helpful to design homogeneous silicate laser glass with outstanding thermal stability.

Phosphors with an efficient yellow-emitting color play a crucial role in phosphor-converted white LEDs (pc-WLEDs), but popular yellow phosphors such as YAG:Ce or Eu(2+) -doped (oxy)nitrides cannot smoothly meet this seemingly simple requirement due to their strong absorptions in the visible range. Herein, we report a novel yellow-emitting LuVO(4) :Bi(3+) phosphor that can solve this shortcoming. The emission from LuVO(4) :Bi(3+) shows a peak at 576 nm with a quantum efficiency (QE) of up to 68 %, good resistance to thermal quenching (T(50 %) =573 K), and no severe thermal degradation after heating-cooling cycles upon UV excitation. The yellow emission, as verified by X-ray photoelectron spectra (XPS), originates from the ((3)P(0),(3)P(1))→(1) S0 transitions of Bi(3+). Increasing the temperature from 10 to 300 K produces a temperature-dependent energy-transfer process between VO(4)(3-) groups and Bi(3+), and further heating of the samples to 573 K intensifies the emission. However, it subsequently weakens, accompanied by blueshifts of the emission peaks. This abnormal anti-thermal quenching can be ascribed to temperature-dependent energy transfer from VO(4)(3-) groups to Bi(3+), a population redistribution between the excited states of (3)P(0) and (3)P(1) upon thermal stimulation, and discharge of electrons trapped in defects with a trap depth of 359 K. Device fabrication with the as-prepared phosphor LuVO(4) :Bi(3+) has proved that it can act as a good yellow phosphor for pc-WLEDs., (© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Closo-deltahedral Bi(5)(3+) cluster in Bi(5)(GaCl(4))(3), which can be synthesized in benzene by oxidizing bismuth metal either with BiCl(3) or GaCl(3), respectively, can absorb ultraviolet, visible and infrared lights, and luminesce superbroadly in near to mid infrared (NMIR) spectral range from 1 to 3μm at room temperature. Slight geometry change of the cluster can lead to the redshift of emission peak. These observations may initialize the development of Bi-based NMIR light sources with superbroad emission spectrum, where Bi(5)(3+) or similar polycationic species act as activators. Disputable crystal structure of Bi(5)(GaCl(4))(3) was redefined by classic Rietveld refining analysis. Consistent with crystallographic data, excitation, emission, temporal decay and time-resolved infrared emission spectra all reveal only one type of luminescent centers, viz. Bi(5)(3+), in the compound. And a new absorption of Bi(5)(3+) was found at ~1100nm.

We report on the spectroscopic properties of Pr(3+)-doped boro-phosphate, boro-germo-silicate and tellurite glasses. The stimulated absorption and emission cross sections were estimated. Only one emission at 596 nm and 605 nm is observed in Pr(3+)-doped boro-phosphate and boro-germo-silicate glasses, respectively, while three emissions at 605 nm, 612 nm and 645 nm are observed in Pr(3+)-doped tellurite glass when excited at 467 nm. The fluorescence lifetime at 600 nm in Pr(3+)-doped boro-phosphate, boro-germo-silicate and tellurite glasses is 137 μs, 73 μs and 51 μs, respectively. The emissions from Pr(3+)-doped boro-phosphate, boro-germo-silicate and tellurite glasses show different decay behaviors and can be well explained by multiphonon relaxation theory., (Copyright © 2012 Elsevier B.V. All rights reserved.)

Ultrabroad near-infrared (NIR) photoluminescence from Ni2+-centers in nanocrystalline Ba-Al titanate glass ceramics was studied by temperature-dependent static and dynamic photoluminescence spectroscopy in the regime of 10 to 300 K. Photoluminescence covers the spectral range of about 1100 nm to >1600 nm with a typical bandwidth (FWHM) greater than 300 nm. For UV-LED excitation at 352 nm, an internal quantum efficiency of 65% is obtained. The excited state lifetime τ at room temperature is 39 μs. The stimulated emission cross section σ(em) is 8.5×10(-20) cm2, resulting in a practical figure of merit, σ(em) * τ, of 3.3×10(-24) cm2 s at room temperature. These properties suggest suitability as a broadband gain medium for tunable lasers and optical amplifiers.

Superbroad near-to-mid infrared (NIR-MIR) photoluminescence was observed from Bi5(AlCl4)3 at room temperature, spanning the spectral range of about 1000 to 4000 nm. On the basis of structural considerations and dynamic analyses, Bi5(3+) clusters were identified as the optically active species, inherently differing from the species which is typically believed to be active in NIR-emitting Bi-doped glasses. In comparison to most other NIR-luminescent Bi-doped materials, the MIR-part of the luminescence spectrum is still present at room temperature. Emission intensity and excited state lifetime were found to exhibit abnormal temperature dependence, where the former increases with temperature up to a critical value of about 150 K. This behavior is related to a temperature-dependent overlap between ground state and excited states. The observed stabilization of MIR photoemission at room temperature may be a starting point for the development of Bi-based NIR-MIR light sources with superbroad emission spectrum, where Bi5(3+) or similar polycationic species act as optical gain medium.