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The phenomenon of negative remanent magnetization (NRM) has been observed experimentally in a number of heterogeneous magnetic systems and has been considered anomalous. The existence of NRM in homogenous magnetic materials is still in debate, mainly due to the lack of compelling support from experimental data and a convincing theoretical explanation for its thermodynamic validation. Here we resolve the long-existing controversy by presenting experimental evidence and physical justification that NRM is real in a prototype homogeneous ferromagnetic nanoparticle, an europium sulfide nanoparticle. We provide novel insights into major and minor hysteresis behavior that illuminate the true nature of the observed inverted hysteresis and validate its thermodynamic permissibility and, for the first time, present counterintuitive magnetic aftereffect behavior that is consistent with the mechanism of magnetization reversal, possessing unique capability to identify NRM. The origin and conditions of NRM are explained quantitatively via a wasp-waist model, in combination of energy calculations. [ABSTRACT FROM AUTHOR]

Propellant-plasma interaction has been attracting great interests among most researchers for application to an electrothermal-chemical (ETC) gun. Previous works have shown that propellant-plasma interaction can enhance burning rates due to increased surface erosion of propellants as compared to that of conventional ignition. Plasma radiation and heat convection are the dominant mechanism of energy transfer based on both experimental data and numerical simulation. However, little literatures were reported about a detailed understanding of propellant loading parameters and the plasma flow-field distribution interactions, which is very important in deciding a successful propellant-charge design in ETC guns. The pressure-time curves during interrupted-burning process of different propellants such as triethyeneglycol dinitrate and single-base propellants ignited by plasma were recorded by pressure sensor in interrupted-burning setup. Influence of loading parameters, including loading density, distance between propellants and plasma jet, and propellant holding methods at the same selected location in plasma flow-field on plasma-ignition performance of propellants was discussed based on experimental results. As the loading density of propellants increases, the porosity of the propellant bed becomes small. Moreover, the penetrating depth of plasma into propellant bed shortens. Therefore, the plasma energy attenuates rapidly, and the ignition-delay time of propellants becomes longer. The ignition-delay time is longer when the distance between propellants and plasma jet increases. At the same selected location in plasma flow-held, different holding methods of propellant burning surface to plasma jet have less influence on the ignition, combustion process of propellants, and the ignition-delay time. The matching test results on propellant loading parameters and plasma flow-field distribution interaction play a major role in improving charge configurations at chosen plasma flow-field and understanding plasma-propellant interaction better. [ABSTRACT FROM AUTHOR]

Surface soil moisture (SSM) is a major factor that affects crop growth. Combined microwave and optical data have been widely used to improve the accuracy of SSM retrievals. However, the influence of vegetation indices derived from the red-edge spectral bands of multi-spectral optical data on retrieval accuracy has not been sufficiently analyzed. In this study, we retrieved soil moisture from wheat-covered surfaces using Sentinel-1/2 data. First, a modified water cloud model (WCM) was proposed to remove the influence of vegetation from the backscattering coefficient of the radar data. The vegetation fraction (FV) was then introduced in this WCM, and the vegetation water content (VWC) was calculated using a multiple linear regression model. Subsequently, the support vector regression technique was used to retrieve the SSM. This approach was validated using in situ measurements of wheat fields in Hebi, located in northern Henan Province, China. The key findings of this study are: (1) Based on vegetation indices obtained from Sentinel-2 data, the proposed VWC estimation model effectively eliminated the influence of vegetation; (2) Compared with vertical transmit and horizontal receive (VH) polarization, vertical transmit and vertical receive (VV) polarization was better for detecting changes in SSM key phenological phases of wheat; (3) The validated model indicates that the proposed approach successfully retrieved SSM in the study area using Sentinel-1 and Sentinel-2 data.

Design applications for robust feedback and optimized feedforward control, with confirming results from experiments conducted on the Pennsylvania State University TRIGA reactor, are presented. The combination of feedforward and feedback control techniques complement each other in that robust control offers guaranteed closed-loop stability in the presence of uncertainties, and optimized feedforward offers an approach to achieving performance that is sometimes limited by overly conservative robust feedback control. The design approach taken in this work combines these techniques by first designing robust feedback control. Alternative methods for specifying a low-order linear model and uncertainty specifications, while seeking as much performance as possible, are discussed and evaluated. To achieve desired performance characteristics, the optimized feedforward control is then computed by using the nominal nonlinear plant model that incorporates the robust feedback control. [ABSTRACT FROM AUTHOR]

A surface relaxation model is established to study the elastic properties of nanoscale structures. This model predicts coordination-dependent strain at the surface and thickness-dependent stiffness of a material. Several atomic layers at the surface endure a significant strain gradient, which is dominated by the intrinsic properties of the material. The stiffness of low-dimensional materials is enhanced by surface relaxation effect. Surface effects on strong structures, including honeycomb structure and octet-truss structure with a high stiffness-to-weight ratio, are discussed. For these structures assembled with nanobeams, the Young’s modulus decreases with decreasing size of the struts. The coupling between Young’s modulus and relative density can be scaled down by engineering tensile strain on the struts. [ABSTRACT FROM AUTHOR]

Europium chalcogenides (EuX, X = O, S, Se, Te), a class of prototypical Heisenberg magnetic semiconductors, exhibit intriguing properties in optics, magnetism, and magneto-optics at the nanoscale, and have broad application potential in optical/magnetic sensors, spintronics, optical isolators, etc. EuX nanocrystals (NCs) exhibit enhanced properties, such as high saturation magnetization, a strong magneto-optic effect (Faraday rotation), and high magneto resistance, which are all unanimously dependent on the NC’s size, shape, and surface information. In this report, we give an overview of the fundamental properties of bulk EuX, and illustrate the quantum confinement effects on the optical, magnetic and magneto-optical properties of EuX nanostructures. We then focus on doping and self-assembly—two efficient methods that enhance magnetic properties by manipulating magnetic coupling in EuX nanostructures. In particular, we look towards future research on Eu2+ NCs, which along with the overview provides an up-to-date platform for evaluating the fundamental properties and application potential of Eu-based semiconductors. [ABSTRACT FROM AUTHOR]

One-dimensional (1D) nanocrystals, such as nanorods and nanowires, have received extensive attention in the nanomaterials field due to their large surface areas and 1D confined transport properties. Oriented attachment (OA) is now recognized as a major growth mechanism for efficiently synthesizing 1D nanocrystals. Recently, atomic layer deposition (ALD) has been modified to be a powerful vapor-phase technique with which to synthesize 1D OA nanorods/nanowires with high efficiency and quality by increasing the temperature and purging time. In this invited mini-review, we look into the advantages of OA and high-temperature ALD, and investigate the potential of employing the OA growth mechanism for the synthesis of 1D nanocrystals via modified ALD, aiming to provide guidance to researchers in the fields of both OA and ALD for efficient synthesis of 1D nanocrystals. [ABSTRACT FROM AUTHOR]

The soluble fraction of atmospheric transition metals is particularly associated with health effects such as reactive oxygen species compared to total metals. However, direct measurements of the soluble fraction are restricted to sampling and detection units in sequence burdened with a compromise between time resolution and system bulkiness. Here, we propose the concept of aerosol-into-liquid capture and detection, which allowed one-step particle capture and detection via the Janus-membrane electrode at the gas–liquid interface, enabling active enrichment and enhanced mass transport of metal ions. The integrated aerodynamic/electrochemical system was capable of capturing airborne particles with a cutoff size down to 50 nm and detecting Pb(II) with a limit of detection of 95.7 ng. The proposed concept can pave the way for cost-effective and miniaturized systems, for the capture and detection of airborne soluble metals in air quality monitoring, especially for abrupt air pollution events with high airborne metal concentrations (e.g., wildfires and fireworks). [ABSTRACT FROM AUTHOR]

A novel one-step solvothermal synthesis of stable colloidal EuS nanocrystals (NCs) is reported. The EuS NCs were synthesized in oleylamine directly from europium oleate and diethylammonium diethyldithiocarbamate in the presence of dodecanethiol and phenanthroline. The formation of single crystalline monodisperse EuS NCs, with sizes finely controlled by synthetic conditions, was confirmed by x-ray diffraction and high resolution transmission electron microscopy analysis. The exciton transition of EuS NCs blue-shifts to higher energies with decreasing particle sizes, as revealed by optical absorption and photoluminescence measurements. The feasibility of synthesizing monocrystalline EuS nanorods by solvothermal synthesis was also demonstrated, making them potentially viable materials for device applications. [ABSTRACT FROM AUTHOR]

Person search has long been treated as a crucial and challenging task to support deeper insight in personalized summarization and personality discovery. Traditional methods, e.g., person re-identification and face recognition techniques, which profile video characters based on visual information, are often limited by relatively fixed poses or small variation of viewpoints and suffer from more realistic scenes with high motion complexity (e.g., movies). At the same time, long videos such as movies often have logical story lines and are composed of continuously developmental plots. In this situation, different persons usually meet on a specific occasion, in which informative social cues are performed. We notice that these social cues could semantically profile their personality and benefit person search task in two aspects. First, persons with certain relationships usually co-occur in short intervals; in case one of them is easier to be identified, the social relation cues extracted from their co-occurrences could further benefit the identification for the harder ones. Second, social relations could reveal the association between certain scenes and characters (e.g., classmate relationship may only exist among students), which could narrow down candidates into certain persons with a specific relationship. In this way, high-level social relation cues could improve the effectiveness of person search. Along this line, in this article, we propose a social context-aware framework, which fuses visual and social contexts to profile persons in more semantic perspectives and better deal with person search task in complex scenarios. Specifically, we first segment videos into several independent scene units and abstract out social contexts within these scene units. Then, we construct inner-personal links through a graph formulation operation for each scene unit, in which both visual cues and relation cues are considered. Finally, we perform a relation-aware label propagation to identify characters' occurrences, combining low-level semantic cues (i.e., visual cues) and high-level semantic cues (i.e., relation cues) to further enhance the accuracy. Experiments on real-world datasets validate that our solution outperforms several competitive baselines. [ABSTRACT FROM AUTHOR]

Abstract: Mesoporous titanium dioxide films were fabricated on titanium plates by the micro-plasma oxidation method. To increase the photo-catalytic activity of the films, Eu(NO3)3 of different concentrations were added to the H2SO4 electrolyte solution. Eu incorporation was found in the porous titania films. Furthermore, Na2SiO3 of different concentrations was also added to the electrolyte solution, which led to Si incorporation into the film as well. A model textile industry pollutant (Rhodamine B) was used to study the photo-catalytic properties of the modified films. The photo-catalytic activity of these films turned out to be improved by the additives to the electrolyte solution. The enhanced photo-catalytic activity might result from (i) the increased porosity, producing more reactive sites to absorb and oxide pollutants; (ii) electron trapping at Eu sites suppressing the e−/h+ pair recombination, therefore, improving the photo-catalytic processes. [Copyright &y& Elsevier]

Objective: To explore the mechanism of Dangua Fang (, DGR) in multi-target and multi-method regulation of glycolipid metabolism based on phosphoproteomics., Methods: Sprague-Dawley rats with normal glucose levels were randomly divided into three groups, including a conventional diet control group (Group A), high-fat-high-sugar diet model group (Group B), and DGR group (Group C, high-fat-high-sugar diet containing 20.5 g DGR). After 10 weeks of intervention, the fasting blood glucose (FBG), 2 h blood glucose [PBG; using the oral glucose tolerance test (OGTT)], hemoglobin A1c (HbA1c), plasma total cholesterol (TC), and triglycerides (TG) were tested, and the livers of rats were removed to calculate the liver index. Then, hepatic portal TG were tested using the Gross permanent optimization-participatiory action planning enzymatic method and phosphoproteomics was performed using liquid chromatography with tandem mass spectrometry (LC-MS/MS) analysis followed by database search and bioinformatics analysis. Finally, cell experiments were used to verify the results of phosphoproteomics. Phosphorylated mitogen-activated protein kinase kinase kinase kinase 4 (MAP4k4) and phosphorylated adducin 1 (ADD1) were detected using western blotting., Results: DGR effectively reduced PBG, TG, and the liver index (P < 0.05), and significantly decreased HbA1c, TC, and hepatic portal TG (P < 0.01), showed significant hematoxylin and eosin (HE) staining, red oil O staining, and Masson staining of liver tissue. The total spectrum was 805 334, matched spectrum was 260 471, accounting for accounting 32.3%, peptides were 19 995, modified peptides were 14 671, identified proteins were 4601, quantifiable proteins were 4417, identified sites were 15 749, and quantified sites were 14659. Based on the threshold of expression fold change ( > 1.2), DGR up-regulated the modification of 228 phosphorylation sites involving 204 corresponding function proteins, and down-regulated the modification of 358 phosphorylation sites involving 358 corresponding function proteins, which included correcting 75 phosphorylation sites involving 64 corresponding function proteins relating to glycolipid metabolism. Therefore, DGR improved biological tissue processes, including information storage and processing, cellular processes and signaling, and metabolism. The metabolic functions regulated by DGR mainly include energy production and conversion, carbohydrate transport and metabolism, lipid transport and metabolism, inorganic ion transport and metabolism, secondary metabolite biosynthesis, transport, and catabolism. In vitro phosphorylation validation based on cell experiments showed that the change trends in the phosphorylation level of MAP4k4 and ADD1 were consistent with that of previous phosphoproteomics studies., Conclusion: DGR extensively corrects the modification of phosphorylation sites to improve corresponding glycolipid metabolism-related protein expression in rats with glycolipid metabolism disorders, thereby regulating glycolipid metabolism through a multi-target and multi-method process.