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The paper reports the results of an experimental investigation aimed at evaluating the role of hydrodynamic conditions on generation and main properties of granular biomass grown under aerobic conditions in a periodic packed bed reactor. During the start-up period, the trend of the hydrodynamic shear forces, calculated by a methodology previous developed by authors, provided a key for explaining the process of biomass granulation. The granular biomass was characterized by a high density (i.e., 70-120 gVSS/Lbiomass) that permitted to achieve a biomass concentration such high as 20-38 gVSS/Lbed. The biomass density increased with the increase of shear forces. The EPS (Extracellular Polymeric Substances) content of the biomass (5-7% of the total organic matter) was not affected by hydrodynamic shear forces as well as the biomass protein content. Periodic packed bed reactor applied to a municipal wastewater showed performances very satisfactory with high efficiencies removal (around 90%) for both COD and ammonia, up to an applied organic loading value of 5.7 kgCOD/m3.d, and negligible sludge production.

This is the second of two papers each dealing with a specific technological option for replacing the Fenton's reagent with simpler processes for treating industrial wastewater. In particular, the paper reports the results of an investigation aimed to check, at lab scale, the effectiveness of an alternative wastewater treatment combining biological degradation and chemical oxidation with ozone. The treatment was carried out in a lab scale hybrid reactor fed with the biological stage effluent of a plant treating the wastewater of a large tanning district in Central Italy whose residual COD result still higher than the Italian COD Maximum Allowable Concentration (MAC) value (i.e., 160 mgO2/L) The results are very promising, considering that a removal efficiency of 41% (as COD) has been achieved by treating an influent characterized by a COD content fully biorefractory. In addition, the proposed treatment presents the significant advantage of no additional sludge production, as happens with commonly utilized tertiary processes (i.e. Fenton), that is characterized by high chemical sludge production.