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Ocean surface albedo (OSA) is an important factor for the transfer of radiation in the coupled atmosphere-ocean system. By resolving the spectral variations of the reflective properties for incident direct and diffuse solar radiation, we develop an OSA computational scheme to study the impact of ocean biogeochemistry on the air-sea boundary condition of solar radiative transfer in the atmosphere. The new scheme is implemented for the General Circulation Model applications of the shortwave rapid radiative transfer model RRTMG_SW, a radiative transfer model used extensively in regional and global models. We show that a number of OSA schemes lead to underestimated results in comparison with in-situ measurements obtained at a site 25 km east of Virginia Beach. The scheme developed in this study considers multiple influential factors and is robust in terms of the mean absolute percentage error (MAPE) and the root mean square error in comparison with in-situ measurements. Furthermore, the new simulations are highly consistent with the Clouds and the Earth's Radiant Energy System (CERES) OSA distribution on a global scale. However, the theoretical results show slight differences compared with the CERES OSA under all sky conditions and overestimate the OSA in the subpolar Southern Ocean under clear sky conditions. The assumption of a uniform phase function, which neglects the spatial variability of the optical properties of oceanic particles, is largely responsible for the primary source of uncertainties in an OSA scheme. [ABSTRACT FROM AUTHOR]

The coastal Gulf of Mexico (GOM) and Coastal Sea off Korea (CSK) both suffer from human-induced eutrophication. We used a N-mass balance model in two different regions with different nitrogen input sources to estimate organic carbon fluxes and predict future carbon fluxes under different model scenarios. The coastal GOM receives nitrogen predominantly from the Mississippi and Atchafalaya Rivers and atmospheric nitrogen deposition (AN-D) is only a minor component in this region. However, in the CSK, groundwater and atmospheric nitrogen deposition are more important controlling factors. Our model includes the fluxes of nitrogen to the ocean from the atmosphere, groundwater, and rivers, based on observational and literature data, and identifies three zones (brown, green and blue waters) in the coastal GOM and CSK with different productivity and carbon fluxes. Based on our model results, the potential primary production rate in the inner (brown water) zone are more than 2 (GOM) and 1.5 gC m-2 day-1 (CSK). In the middle (green water) zone, potential production is between 0.1 to 2 (GOM) and 0.3 to 1.5 gC m-2 day-1 (CSK). In the offshore (blue water) zone, productivity is less than 0.1 (GOM) and 0.3 (CSK) gC m-2 day-1. Through our model scenario results, overall oxygen demand in the GOM would increase approximately 21 % if we fail to reduce riverine N input, likely increasing considerably the area affected by hypoxia. Comparing the results from the U.S. with those from Korea shows the importance of considering both riverine and atmospheric inputs of nitrogen. This has direct implications for investigating how changes in energy technologies can lead to changes in the production of various atmospheric contaminants that affect air quality, climate and the health of local populations. [ABSTRACT FROM AUTHOR]

Near the vicinity of 30° latitude, the coincidence of the period of sea breeze and the inertial period of the ocean leads to a maximum near-inertial ocean response to sea breeze. This produces a propagating inertial internal (Poincare) wave response that transfers energy laterally away from the coast and provides significant vertical mixing. In this paper, the latitudinal dependence of this wave propagation and its associated vertical mixing are investigated primarily using a nonlinear numerical ocean model. Three-dimensional idealized simulations show that the coastal oceanic response to sea breeze is trapped poleward of 30° latitude; however, it can propagate offshore as Poincare waves equatorward of 30° latitude. Near 30° latitude, the maximum oceanic response to sea breeze moves offshore slowly because of the near-zero group speed of Poincare waves at this latitude. The lateral energy flux convergence plus the energy input from the wind is maximum near the critical latitude, leading to increased local dissipation by vertical mixing. This local dissipation is greatly reduced at other latitudes. The implications of these results for the Gulf of Mexico (GOM) at ∼30°N is considered. Simulations with realistic bathymetry of the GOM confirm that a basinwide ocean response to coastal sea-breeze forcing is established in form of Poincare waves. Enhanced vertical mixing by the sea breeze is shown on the model northern shelf, consistent with observations on the Texas–Louisiana shelf. Comparison of the three-dimensional and one-dimensional models shows some significant limitations of one-dimensional simplified models for sea-breeze simulations near the critical latitude. [ABSTRACT FROM AUTHOR]

The spatial structure and temporal characteristics of sea breeze and the associated coastal ocean response in the northwest Gulf of Mexico are investigated using moored instruments, hydrographic stations, and wind measurements. Near the study area of 30°N, motions in the diurnal–inertial band (DIB) may be significantly enhanced by a near-resonant condition between local inertial and diurnal forcing frequencies. Wavelet analysis is used to quantify the results. Results indicate that diurnal sea-breeze variability peaks in summer and extends at least 300 km offshore with continuous seaward phase propagation. The maximum DIB oceanic response occurs in June when there is a shallow mixed layer, strong stratification, and an approximately 10-day period of continuous sea-breeze forcing. DIB current variance decreases in July and August as the consequence of the deepening of the mixed layer and a more variable phase relationship between the wind and current. River discharge varies interannually and can significantly alter the oceanic response during summer. The “great flood” of the Mississippi River in 1993 deepened the summer mixed layer and reduced the sea-breeze response during that year. Vertically, DIB currents are surface intensified, with a first baroclinic modal structure. The significance of these DIB motions on the shelf is that they can provide considerable vertical mixing in summer, as seen by the suppression of the bulk Richardson number (by a factor of 30) during strong DIB events. This provides a potential mechanism to ventilate seasonally occurring near-bottom hypoxic waters of the coastal ocean. [ABSTRACT FROM AUTHOR]