51. First stages of surface steel nitriding: X-ray photoelectron spectroscopy and electrical measurements
- Author
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Flori, M., Gruzza, B., Bideux, L., Monier, G., Robert-Goumet, C., and Benamara, Z.
- Subjects
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NITRIDING , *STEEL alloys , *METALLIC surfaces , *X-ray photoelectron spectroscopy , *PHYSICAL measurements , *GLOW discharges , *QUANTITATIVE chemical analysis ,ELECTRIC properties of steel - Abstract
Abstract: Quantitative and qualitative analysis techniques were employed to study the first stages of ultra-high vacuum plasma nitriding of the 42CrMo4 steel. At constant treatment temperature, maintained for all samples at about 360°C, we have established the influence of treatment time on the chemical composition, thickness and electrical properties of the nitrided layer. In this purpose it was used a stacking atomic layer model describing the sample surface, which takes into account the attenuation depth of photoelectrons by the atomic monolayers. So, we have found that after 2h of nitriding in laboratory conditions, 70% of the nitrided layer was composed of iron oxide. Also, I–V measurements indicate an influence of the nitride overlayer with increasing treatment time. [Copyright &y& Elsevier]
- Published
- 2009
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