153 results on '"Overcharging"'
Search Results
52. Modeling of the charge acceptance of lead–acid batteries
- Author
-
Thele, M., Schiffer, J., Karden, E., Surewaard, E., and Sauer, D.U.
- Subjects
- *
HYBRID electric cars , *IMPEDANCE spectroscopy , *ELECTROCHEMICAL analysis , *CRYSTAL grain boundaries - Abstract
Abstract: This paper presents a model for flooded and VRLA batteries that is parameterized by impedance spectroscopy and includes the overcharging effects to allow charge-acceptance simulations (e.g. for regenerative-braking drive-cycle profiles). The full dynamic behavior and the short-term charge/discharge history is taken into account. This is achieved by a detailed modeling of the sulfate crystal growth and modeling of the internal gas recombination cycle. The model is applicable in the full realistic temperature and current range of automotive applications. For model validation, several load profiles (covering the dynamics and the current range appearing in electrically assisted or hybrid cars) are examined and the charge-acceptance limiting effects are elaborately discussed. The validation measurements have been performed for different types of lead–acid batteries (flooded and VRLA). The model is therefore an important tool for the development of automotive power nets, but it also allows to analyze different charging strategies and energy gains which can be achieved during regenerative-braking. [Copyright &y& Elsevier]
- Published
- 2007
- Full Text
- View/download PDF
53. Experimental and theoretical evidence of overcharging of calcium silicate hydrate
- Author
-
Labbez, Christophe, Nonat, André, Pochard, Isabelle, and Jönsson, Bo
- Subjects
- *
CALCIUM silicates , *VOLUMETRIC analysis , *MONTE Carlo method , *PROPERTIES of matter - Abstract
Abstract: Electrokinetic measurements such as electrophoresis may show an inversion of the effective surface charge of colloidal particle called overcharging. This phenomenon has been studied by various theoretical approaches but up to now very few attempts of confrontation between theory and experiment have been conducted. In this work we report electrophoretic measurements as well as Monte Carlo simulations of the electrokinetic potential for the surface of calcium silicate hydrate (Ch name="sbnd" />H), which is the major constituent of hydrated cement. In the simulations, the surface charge of Ch name="sbnd" />H nanoparticles in equilibrium with the ionic solution is determined by a single site characteristic and electrostatic interactions between all explicit charges at the surface and in the electric double layer. We will show that ordinary electrostatic interactions are enough to describe all experimental observations. Actually, an excellent agreement is found between experimental and simulated results without any fitting parameter, both with respect to surface titration and electrokinetic behaviour. The agreement extends over a wide range of electrostatic coupling, from a weakly charged surface with mainly monovalent counter-ions to a highly charged one with divalent counter-ions. [Copyright &y& Elsevier]
- Published
- 2007
- Full Text
- View/download PDF
54. Overcharging, charge reversal: Chemistry or physics?
- Author
-
Lyklema, Johannes
- Subjects
- *
ELECTROKINETICS , *CHARGE exchange , *ADSORPTION (Chemistry) , *SURFACE chemistry - Abstract
Abstract: Overcharging, also called charge reversal or charge inversion, is the occurrence of electric double layers in which, as measured by electrokinetics or interaction, there is more countercharge than charge on the surface. The trend is that the propensity of overcharging increases with the valency of the counterion. For the interpretation of this phenomenon, disparate explanations have been forwarded and elaborated that, briefly, can be distinguished as “chemical” (specific adsorption, …) and “physical” (ion correlations, …). In the present paper, an analysis of this disparity will be given. In particular, types of experiments will be proposed which can help to discriminate. [Copyright &y& Elsevier]
- Published
- 2006
- Full Text
- View/download PDF
55. The many facets of polyelectrolytes and oppositely charged macroions complex formation
- Author
-
Ulrich, Serge, Seijo, Marianne, and Stoll, Serge
- Subjects
- *
POLYELECTROLYTES , *ELECTROLYTES , *LINE geometry , *MATHEMATICAL transformations - Abstract
Abstract: Various models of the complex formation between polyelectrolyte chains and oppositely charged macroions are reviewed. In recent years, a great deal of knowledge of the multitude of possible polyelectrolyte conformations at the macroion surface has been accumulated, which consequently has led to increasing interest in using such complexes in the design of nanomaterials. This review focuses on key studies relating to the effects of various physico-chemical parameters on complex formation and areas for future research are identified. [Copyright &y& Elsevier]
- Published
- 2006
- Full Text
- View/download PDF
56. Impedance-based overcharging and gassing model for VRLA/AGM batteries
- Author
-
Thele, M., Karden, E., Surewaard, E., and Sauer, D.U.
- Subjects
- *
STORAGE batteries , *SPECTRUM analysis , *PROPERTIES of matter , *INTERMEDIATES (Chemistry) - Abstract
Abstract: This paper presents for the first time an impedance-based non-linear model for lead-acid batteries that is applicable in all operational modes. An overcharging model describes the accumulation and depletion of the dissolved Pb2+ ions. This physical model has been added to the earlier presented model to expand the model validity. To properly represent the charge acceptance during dynamic operation, a concept of “hardening crystals” has been introduced in the model. Moreover, a detailed gassing and oxygen recombination model has been integrated. A realistic simulation of the overcharging behavior is now possible. The mathematical description is given in the paper. Simplifications are introduced that allow for an efficient implementation and for model parameterization in the time domain. A comparison between experimental data and simulation results demonstrates the achieved accuracy. The model enhancement is of major importance to analyze charging strategies especially in partial-cycling operation with limited charging time, e.g. in electrically assisted or hybrid cars and autonomous power supply systems. [Copyright &y& Elsevier]
- Published
- 2006
- Full Text
- View/download PDF
57. The effects of unequal ionic sizes for an electrolyte in a charged slit
- Author
-
Yu, Jiang, Aguilar-Pineda, Gabriel E., Antillón, A., Dong, Shi-Hai, and Lozada-Cassou, M.
- Subjects
- *
IONS , *ELECTROLYTES , *ANIONS , *CATIONS - Abstract
Abstract: The modified Gouy–Chapman (MGC) theory has been used to study the electrical double layer near two charged plates immersed in a model electrolyte. The effects of assigning to the cations and anions different distances of closest approach to the charged surfaces are examined. The dependence of overcharging and charge reversal on the system parameters such as concentration, ion size and valence, is investigated both inside and outside the charged slit. [Copyright &y& Elsevier]
- Published
- 2006
- Full Text
- View/download PDF
58. Electro-optics of colloid–polyelectrolyte complexes: Counterion release from adsorbed macromolecules
- Author
-
Radeva, Tsetska and Kamburova, Kamelia
- Subjects
- *
ELECTROPHORESIS , *ADSORPTION (Chemistry) , *PARTICLES , *LIGHT scattering - Abstract
Abstract: Complexation between sodium carboxymethylcellulose (NaCMC) and ellipsoidal particles of oppositely charged β-FeOOH is studied using electric light scattering and electrophoresis. We focus on the complex behavior for overcharging of the particle surface. In this case, the fraction of condensed counterions on NaCMC is found to remain unchanged during polymer adsorption onto a weakly charged particle surface. Using the theory of Sens and Joanny, we evaluate the fraction of condensed counterions and compare it with results for nonadsorbed NaCMC. The polarization of condensed counterions along the chain of the adsorbed macromolecule is proved to create the electro-optical effect in suspensions stabilized by NaCMC adsorption. [Copyright &y& Elsevier]
- Published
- 2006
- Full Text
- View/download PDF
59. Strange electrostatics in physics, chemistry, and biology
- Author
-
Levin, Yan
- Subjects
- *
ELECTROSTATICS , *PHYSICS , *CHEMISTRY , *BIOLOGY - Abstract
Abstract: In this paper I will briefly review some curious, and often counterintuitive, results found when the electrostatics and the many-body physics are brought together. The discussion is purely classical, with examples drawn from areas of physics, chemistry, and biology. [Copyright &y& Elsevier]
- Published
- 2005
- Full Text
- View/download PDF
60. Credence goods in the literature: What the past fifteen years have taught us about fraud, incentives, and the role of institutions
- Author
-
Balafoutas, Loukas and Kerschbamer, Rudolf
- Subjects
L15 ,Overtreatment ,I11 ,Expert Services ,D18 ,Fraud ,Undertreatment ,D82 ,D83 ,Overcharging ,ddc:330 ,Credence Goods ,D21 ,D22 - Abstract
We review the literature on credence goods since Dulleck and Kerschbamer (Journal of Economic Literature 44(1), 5-42, 2006). We consider various markets for credence goods and briefly discuss evidence on the extent of fraud. We then review theoretical and empirical contributions on the determinants of seller and consumer behavior in markets for credence goods. The topics include informational asymmetries, pro-social motivations and seller characteristics, as well as several features of the market structure and institutional environment (separation of diagnosis and treatment, liability, verifiability, reputational concerns, competition between experts and second opinions). We also describe recent developments in this area of research (such as the role of investing in more precise diagnostic technologies) and offer an outlook on future questions.
- Published
- 2020
61. Website Development as a Credence Good: A Field Experiment
- Author
-
Appelt, Šimon, Chytilová, Julie, and Špolcová, Dominika
- Subjects
tvorba webových stránek ,overcharging ,"Credence goods" ,předražování ,discrimination ,profesionální služby ,field experiment ,website development ,expert services ,diskriminace ,"field" experiment ,Credence goods - Abstract
There are many markets for credence goods which have been assessed in recent economic research, including taxi services, car mechanics, health care or electronics repairs. How- ever, as no previous research inspects solely an Internet-based environment, the thesis examines the web development market as the representative of a new potential segment of markets for credence goods. In particular, the discrimination in overcharging based on gender or technical experience of a customer is assessed. For this reason, a natural field experiment was designed and subsequently, 341 Czech web developers and IT firms were approached via email to collect the proposed prices for a fictitious E-shop development contract. After the analysis of the outcome variables, the multiple linear regression model with the ordinary least squares (OLS) method was employed. The results suggest that male customers tend to get higher price proposals than women. The second implication is that customers who signalled technical experience in the email inquiry appear to get higher prices than the non-technical customers. However, the outcomes and the differ- ences in proposed prices were not significant among the treatment groups. Other factors, including the number of employees, the region where the company resides and proposed...
- Published
- 2020
62. Primitive models and electrophoresis: an experimental study
- Author
-
Martín-Molina, A., Quesada-Pérez, M., Galisteo-González, F., and Hidalgo-Álvarez, Roque
- Subjects
- *
SURFACE chemistry , *ELECTROKINETICS , *IONS - Abstract
Several theories (developed in the context of the so-called primitive models) argue that the classical Poisson–Boltzmann (PB) approach could fail to describe the electrical double layer in the case of high surface charge densities and/or ionic strengths. Under such conditions, the concentration of counterions in the vicinity of the surface would be larger than expected. What is more, the particle charge could be overcompensated (which is known as overcharging). This would lead to a considerable reduction in the magnitude of the ζ-potential (as compared with PB predictions) and, even, a reversal in its sign. Although these predictions are quite remarkable, these new approaches have been applied just scarcely in practice. Obviously, electrophoresis offers an excellent possibility of testing these theories. Accordingly, we have measured the electrophoretic mobility for latex particles with moderate and large surface charge densities at high ionic strengths. A commercial setup specifically designed for measuring extremely low mobilities has been used. The results have been interpreted with the help of the so-called hyper-netted-chain/mean-spherical approximation (HNC/MSA), a theory that includes ion size effects. In this way, overcharging has been experimentally investigated. Although the HNC/MSA is not a completely successful approach, our analysis suggests that the role of ion size correlations is important, particularly in electrolytes with a counterion valency of 2 or greater. [Copyright &y& Elsevier]
- Published
- 2003
- Full Text
- View/download PDF
63. Influence of electrolyte additives on safety and cycle life of rechargeable lithium cells.
- Author
-
Tobishima, S., Ogino, Y., and Watanabe, Y.
- Subjects
LITHIUM cells ,ELECTRIC batteries ,STORAGE batteries ,ELECTROLYTES ,ELECTROCHEMISTRY ,FUEL cells - Abstract
The influence of electrolyte additives on the safety and cycle life of 4V-class lithium cells is examined. The electrolyte solution employed was 1 MI LiClO
4 -propylene carbonate, the most widely used electrolyte in lithium battery research. The additives studied were ten organic aromatic compounds including biphenyl, cyclohexylbenzene and hydrogenated diphenyleneoxide. For safety, focus was given to the overcharging tolerance of the lithium cells. Biphenyl is well-known as an overcharge protection additive. The purpose of this work was to find additives with a higher oxidation potential and longer charge-discharge cycle life than biphenyl. The oxidation potentials and currents of the additives were measured to determine whether or not these compounds work as overcharge protection additives. Charge-discharge cycling efficiencies were examined for lithium metal anodes. The results showed that cyclohexylbenzene and hydrogenated diphenyleneoxide have a higher oxidation potential and a higher lithium cycling efficiency than biphenyl. [ABSTRACT FROM AUTHOR]- Published
- 2003
- Full Text
- View/download PDF
64. Overcharging of ellipsoidal particles by oppositely charged polyelectrolytes
- Author
-
Radeva, Tsetska
- Subjects
- *
POLYELECTROLYTES , *ELLIPSOIDS , *ELECTROOPTICS - Abstract
Electric light scattering method is used to study complexation between polyelectrolyte molecules and oppositely charged ellipsoidal particles. Attention is focused on the charge inversion that occurs when polyelectrolytes of different charge density, chain length and flexibility adsorb on oxide particles in water medium. In particular, we are interested in the similarity observed between the electrical properties of adsorbed and nonadsorbed polymers in regime of the surface charge overcompensation. The electro-optical results show that, at plateau adsorption, the particles assume the charge characteristic of the polymer. The extension of the adsorbed layer into a vertical direction, in which case the overcharging is caused by dangling loops and tails, is supposed to explain this observation. [Copyright &y& Elsevier]
- Published
- 2002
- Full Text
- View/download PDF
65. Overcharging and charge inversion
- Author
-
Saskia Lindhoud and Wiebe M. de Vos
- Subjects
Physics ,Work (thermodynamics) ,Quantitative Biology::Biomolecules ,Charge inversion ,Charge (physics) ,02 engineering and technology ,Surfaces and Interfaces ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrostatics ,01 natural sciences ,Charge reversal ,0104 chemical sciences ,Ion ,Inversion (linguistics) ,Theoretical physics ,General observation ,Colloid and Surface Chemistry ,Overcharging ,Surface charge ,Physical and Theoretical Chemistry ,0210 nano-technology ,Charge regulation ,Sign (mathematics) - Abstract
Both overcharging and charge inversion denote a general observation that the sign of a surface charge can flip in the presence of interacting species such as surfactants, polyelectrolytes, proteins and multivalent ions. Moreover, charge inversion of proteins through charge regulation, is one explanation for protein adsorption to similarly charged surfaces. While overcharging and charge inversion have been long studied, the explanations for these phenomena are often still debated. Broadly these explanations can be categorized as "chemical" where specific attractive interactions are seen as the cause of charge inversion, and "physical" where purely electrostatic interactions and constraints of geometry are used as explanation. In this review, charge inversion is discussed from a very broad viewpoint, where we draw connections between the various explanations proposed for very different systems. Especially, we highlight the work of Johannes Lyklema, who always carefully balanced between the competing chemical and physical explanations, and demonstrated that only few experimental systems allow just a single explanation.
- Published
- 2019
- Full Text
- View/download PDF
66. Automated Timer Socket using Arduino
- Author
-
G. Chakra Mahesh Babu, I. Mahesh Veera Bhadrarao, and M. Venkata Balaji | Ch. Sai Praveen
- Subjects
Automation ,Computer science ,business.industry ,Embedded system ,Arduino ,Overcharging ,Timer ,business ,Electrical Engineering - Abstract
A glace view of our idea is designing a new innovative idea which can monitor the flow of power supply to the existing plug sockets. As in India demand for electricity is increasing day by day, there is a need to implement an idea in order to meet this problem. So not only synthesizing an method to generate the electricity but also a method to save the electricity. Even though there are smart house systems basing on home automation, they only disconnect the electrical or electronic devices form the supply but the power supply to the socket in which the appliance is plugged in can't be stopped. The myth about overcharging your phone is a common one. The amount of charge going into your device shouldnt be an issue as most are smart enough to stop taking a charge once full, just topping up as needed to stay at 100 per cent. The problems occur when the battery overheats, which can cause damage. So.in our paper we are proposing and implementing the automated timer socket using arduino for real time applications. G. Chakra Mahesh Babu | I. Mahesh Veera Bhadrarao | M. Venkata Balaji | Ch. Sai Praveen "Automated Timer Socket using Arduino" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-3 | Issue-3 , April 2019, URL: https://www.ijtsrd.com/papers/ijtsrd23157.pdf
- Published
- 2019
67. Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes
- Author
-
Tian, Minmin [Kobe, JP]
- Published
- 2000
68. Test cells for the investigation of battery reactions at high internal pressures.
- Author
-
Binder, L., Nartey, V., Ghaemi, M., Urdl, P., and Jantscher, W.
- Abstract
Beginning with a construction based on a C-size (LR-14) battery container ('can'), encased in a strong PMMA-support and fitted with a removable cell top equipped with a manometer and a gas-outlet valve, a second and, finally, a more refined third generation cell was developed. The final (3rd generation) design provides additional options for experimental work. For example, the system can be flushed with inert gas; a regulating gas-flow valve has been fitted to feed precisely a gas chromatograph with the gaseous reaction products and a reference electrode to measure anode and cathode potentials individually has also been incorporated. Since AA cells (LR-6) are the dominant monocell battery size, test cells of the second generation were fitted with an adapter to accomodate either a C- or an AA-size. However, the most recent system was designed exclusively for AA-sized cans. The different cell designs are described and examples of their practical application (e.g., overcharge experiments) are given. [ABSTRACT FROM AUTHOR]
- Published
- 1999
- Full Text
- View/download PDF
69. Method for charging a hydrogen getter
- Author
-
Benson, David [Golden, CO]
- Published
- 1998
70. Aging Effects of Current Collectors for the Vanadium Redox Flow Battery
- Author
-
Satola, Barbara
- Subjects
Vanadium Redox Flow Battery ,Electrochemical Cycling ,Overcharging ,VRFB ,X-Ray Computed Microtomography ,Bulk Aging ,Chemical Stability - Published
- 2019
71. Trivalent ion overcharging on electrified graphene.
- Author
-
Carr AJ, Lee SS, and Uysal A
- Abstract
The structure of the electrical double layer (EDL) formed near graphene in aqueous environments strongly impacts its performance for a plethora of applications, including capacitive deionization. In particular, adsorption and organization of multivalent counterions near the graphene interface can promote nonclassical behaviors of EDL including overcharging followed by co-ion adsorption. In this paper, we characterize the EDL formed near an electrified graphene interface in dilute aqueous YCl
3 solution using in situ high resolution x-ray reflectivity (also known as crystal truncation rod) and resonant anomalous x-ray reflectivity (RAXR). These interface-specific techniques reveal the electron density profiles with molecular-scale resolution. We find that yttrium ions (Y3+ ) readily adsorb to the negatively charged graphene surface to form an extended ion profile. This ion distribution resembles a classical diffuse layer but with a significantly high ion coverage, i.e., 1 Y3+ per 11.4 ± 1.6 Å2 , compared to the value calculated from the capacitance measured by cyclic voltammetry (1 Y3+ per ∼240 Å2 ). Such overcharging can be explained by co-adsorption of chloride that effectively screens the excess positive charge. The adsorbed Y3+ profile also shows a molecular-scale gap (⩾5 Å) from the top graphene surfaces, which is attributed to the presence of intervening water molecules between the adsorbents and adsorbates as well as the lack of inner-sphere surface complexation on chemically inert graphene. We also demonstrate controlled adsorption by varying the applied potential and reveal consistent Y3+ ion position with respect to the surface and increasing cation coverage with increasing the magnitude of the negative potential. This is the first experimental description of a model graphene-aqueous system with controlled potential and provides important insights into the application of graphene-based systems for enhanced and selective ion separations., (© 2022 IOP Publishing Ltd.)- Published
- 2022
- Full Text
- View/download PDF
72. Coagulation by multivalent counterions and the Schulze–Hardy rule
- Author
-
Lyklema, Johannes
- Subjects
- *
COAGULATION , *HYDROPHOBIC compounds , *IONS , *COLLOIDS , *STATISTICAL correlation , *COMPLEX compounds , *WATER - Abstract
Abstract: Starting from a number of empirical papers by Matijević et al., the issue of coagulation of hydrophobic colloids by multivalent inorganic counterions is revisited. More recent information is also considered, and some important trends are confirmed and made more quantitative. It can be concluded that the high coagulating power of multivalent ions is mostly not a direct result of their high valence but caused by their propensity of building complexes with water that adsorb specifically. This mechanism requires a revision of the Schulze–Hardy rule interpretations. In addition, this finding helps to define conditions where overcharging by multivalent counterions can be attributed to ion correlations. [Copyright &y& Elsevier]
- Published
- 2013
- Full Text
- View/download PDF
73. Organized Crime, or Shoplifting While Black? Evidence from Texas on Police Discretion in Organized Retail Theft Arrests.
- Author
-
Braun, Michael, Rosenthal, Jeremy, and Therrian, Kyle
- Subjects
ORGANIZED crime ,SHOPLIFTING ,OFFENSES against property ,AFRICAN Americans ,ARREST ,CORRUPTION - Abstract
Among women arrested for petty shoplifting in Texas, blacks are more likely than whites to face a more serious charge of organized retail theft instead of property theft, with the racial disparity being greater for police departments serving more affluent cities. [ABSTRACT FROM AUTHOR]
- Published
- 2018
74. Women
- Author
-
Constable, Nicole, author
- Published
- 2014
- Full Text
- View/download PDF
75. Model charged cylindrical nanopore in a colloidal dispersion: charge reversal, overcharging and double overcharging
- Author
-
E. González-Tovar and M. Lozada-Cassou
- Subjects
Materials science ,batteries ,Physics and Astronomy (miscellaneous) ,Ionic bonding ,FOS: Physical sciences ,02 engineering and technology ,Condensed Matter - Soft Condensed Matter ,010402 general chemistry ,01 natural sciences ,Molecular physics ,double overcharging ,Mesoscale and Nanoscale Physics (cond-mat.mes-hall) ,Surface charge ,overcharging ,vesicles ,Quantitative Biology::Biomolecules ,Physics::Biological Physics ,Condensed Matter - Mesoscale and Nanoscale Physics ,Vesicle ,Charge density ,Charge (physics) ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Integral equation ,lcsh:QC1-999 ,0104 chemical sciences ,Condensed Matter::Soft Condensed Matter ,Nanopore ,Membrane ,Soft Condensed Matter (cond-mat.soft) ,0210 nano-technology ,lcsh:Physics ,energy - Abstract
Using the hypernetted-chain/mean spherical approximation (HNC/MSA) integral equations we study the electrical double layer inside and outside a model charged cylindrical vesicle (nanopore) immersed into a primitive model macroions solution, so that the macroions are only present outside the nanopore, i.e., the vesicle wall is impermeable only to the external macroions. We calculate the ionic and local linear charge density profiles inside and outside the vesicle, and find that the correlation between the inside and outside ionic distributions causes the phenomena of overcharging (also referred to as surface charge amplification) and/or charge reversal. This is the first time overcharging is predicted in an electrical double layer of cylindrical geometry. We also report the new phenomenon of double overcharging. The present results can be of consequence for relevant systems in physical-chemistry, energy storage and biology, e.g., nanofilters, capacitors and cell membranes., 10 pages, 4 figures
- Published
- 2017
76. Ireland's Ulster Bank Hit With $45 Million Fine For Overcharging On Mortgages–But It's Not The First To Be Punished.
- Author
-
Ghosh, Palash
- Subjects
FINES (Penalties) ,BANKING industry ,MONEYLENDERS ,MORTGAGES - Abstract
The fine on Ireland's Ulster Bank was only the latest in a long running saga of lenders being punished for overcharging mortgage borrowers. [ABSTRACT FROM AUTHOR]
- Published
- 2021
77. Abnormal Overcharging during Lithium-Ether Co-Intercalation in a Graphite System: Formation of Shuttling Species by the Reduction of the TFSI Anion.
- Author
-
Kim CY, Lee GH, So HA, Shin KH, and Lee YJ
- Abstract
Materializing an ultrafast charging system is one of the crucial technologies for next-generation Li-ion batteries (LIBs). Among many studies aimed at achieving fast charging systems, Li-ether solvent cointercalation into the graphite electrodes in LIB has been identified as a novel concept for achieving high power performance because this system does not consist of the sluggish desolvation step and a resistive solid-electrolyte interface (SEI) layer. Interestingly, while studying the Li-ether solvent cointercalation into graphite electrodes, employing lithium bis-trifluoromethane sulfonimide (LiTFSI) as the Li salt, we observed an abnormal overcharging phenomenon. Here, we screened the specific conditions, under which the abnormal overcharging occurred, and revealed that this abnormal overcharging was attributable to the shuttling mechanism. The formation of shuttling species could have been derived by the reduction of TFSI
- anion. With this understanding of the underlying mechanism, we efficiently suppressed the abnormal overcharging by adding LiNO3 to the electrolyte. The shuttling and resulting overcharging could be prevented by the synergistic contributions of LiNO3 and Sx Oy , dissolved in the electrolyte, to the formation of a dense solid LiSx Oy SEI layer on Li-metal. We expect that this work could be a great reference in analyzing many unsolved phenomena in systems utilizing TFSI- .- Published
- 2020
- Full Text
- View/download PDF
78. Conditions Leading to Polyelectrolyte Complex Overcharging in Solution: Complexation of Poly(acrylate) Anion with Poly(allylammonium) Cation
- Author
-
Jasmina Salopek, Tomislav Kremer, Davor Kovačević, and Josip Požar
- Subjects
Isothermal microcalorimetry ,Flocculation ,Acrylate ,Polymers and Plastics ,Organic Chemistry ,Inorganic chemistry ,Ionic bonding ,02 engineering and technology ,Electrolyte ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Polyelectrolyte ,overcharging ,polyelectrolyte complexes ,poly(acrylate) anion ,poly(allylammonium) cation ,electrokinetics ,dynamic light scattering ,microcalorimetry ,0104 chemical sciences ,Inorganic Chemistry ,Electrokinetic phenomena ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Titration ,0210 nano-technology - Abstract
Complexation between poly(acrylate) (PA) and poly(allylammonium) (PAH) macroions at pH = 7.0 was studied by means of electrokinetics, microcalorimetry and DLS. At low polyelectrolyte concentrations and no electrolyte present strong overcharging of primary nanocomplexes occurred. In contrast, the increase in polyelectrolyte concentration led to flocculation taking place near the equivalence. The nanocomplex charge reversal was also achieved in the high polymer concentration regime by the abrupt instead of stepwise titrant addition. The procedure was successfully used in the case of several other polyion pairs. The presence of electrolyte affected the PAH-PA interpolyelectrolyte neutralization considerably, leading to ion- specific aggregation and extrinsic charge compensation. The complexation energetics was weakly influenced by ionic conditions. To the best of our knowledge, the reported results are the first direct evidence for primary complex overcharging. Their rationalization explains why interpolyelectrolyte neutralization in solution and at surfaces usually results with formation of neutral and charged products respectively.
- Published
- 2016
- Full Text
- View/download PDF
79. Circuit relay board for charging batteries using a microcontroller
- Author
-
Štor, Anthea and Vražić, Mario
- Subjects
litij ionska baterija ,prepunjavanje ,cycle life ,životni vijek ,PCB ,Li-Ion ,TEHNIČKE ZNANOSTI. Elektrotehnika ,sustav upravljanja baterijama ,sustav upravljanja baterijama, litij ionska baterija, prepunjavanje, životni vijek, relej, tiskana pločica ,relay ,relej ,TECHNICAL SCIENCES. Electrical Engineering ,BMS ,tiskana pločica ,overcharging - Abstract
Zbog potrebe za većom korisnošću i duljim životnim vijekom baterija koristi se sustav upravljanja baterijama. To posebice vrijedi za litij ionske baterije, koje zbog svoje osjetljivosti na prepunjavanje i pretjerano pražnjenje zahtijevaju strogi nadzor u svrhu produživanja životnog vijeka. Sustav upravljanja zasnovan je na ideji punjenja svih ćelija istovremeno dok se jedna od ćelija ne napuni na maksimalni dozvoljeni napon, a onda se prelazi na pojedinačno punjenje ćelija. Kao dio tog sustava, zadatak je bio izraditi relejnu pločicu koja omogućuje da mikrokontroler upravlja punjenjem ćelija strujom do maksimalno 30 A. Pločica također služi i za mjerenje napona na ćelijama. U ovom radu su navedene komponente koje se nalaze na pločici uz obrazloženje zašto su one stavljene na pločicu. Također, dokumentiran je postupak izrade same pločice. Battery management system is used because of the need for greater and longer cycle life of the batteries. This is especially true for lithium ion batteries , which because of its sensitivity to overcharging and over-discharge require strict control in order to prolong the life of the battery . The management system is based on the idea of charging the battery until one cell is filled to the maximum permitted voltage, and then switches to charging cells separately . As part of that system, the task was to circuit relay board that allows microcontroller manages charging cells with current that is up to 30A. The board also serves to measure the voltage on the cells. In this document, components that are on the board are listed and explained. There is documented process of making PCB, too.
- Published
- 2015
80. Fraud in Fee-for-Service and Managed Care: Different Sides of the Same Coin
- Author
-
Leap, Terry L., author
- Published
- 2011
- Full Text
- View/download PDF
81. What drives fraud in a credence goods market? Evidence from a field study
- Author
-
Rasch, Alexander and Waibel, Christian
- Subjects
Betrug ,L15 ,Asymmetric information ,Economics ,Fraud ,Kfz-Gewerbe ,Auto repair market ,Credence goods ,Expert ,Overcharging ,D82 ,Wettbewerb ,Instandhaltung ,Firmenimage ,ddc:330 ,Deutschland ,Anreiz ,Vertrauensgüter - Abstract
This paper investigates the impact of four key economic variables on an expert firm’s incentive to defraud its customers in a credence goods market: the level of competition, the expert firm’s financial situation, its competence, and its reputational concerns. We use and complement the dataset of a na-tionwide field study conducted by the German Automobile Association that regularly checks the reliability of garages in Germany. We find that more in-tense competition and high competence lower firms’ incentive to overcharge. A low concern for reputation and a critical financial situation increase the incentive to overcharge., Economics Working Paper Series, 13/179
- Published
- 2015
82. 宇宙用電源技術の研究
- Author
-
Kuwajima, Saburo, Kanno, Koichi, Kusawake, Hiroaki, Sone, Yoshitsugu, Liu, Xingjiang, 桑島 三郎, 菅野 浩一, 艸分 宏昌, 曽根 理嗣, Kuwajima, Saburo, Kanno, Koichi, Kusawake, Hiroaki, Sone, Yoshitsugu, Liu, Xingjiang, 桑島 三郎, 菅野 浩一, 艸分 宏昌, and 曽根 理嗣
- Abstract
NASDA Special Publication, 宇宙開発事業団特別報告
- Published
- 2015
83. What drives fraud in a credence goods market? Evidence from a field study
- Author
-
Alexander Rasch and Christian Waibel
- Subjects
Statistics and Probability ,Economics and Econometrics ,Overcharge ,Asymmetric information ,Auto repair market ,Credence goods ,Expert ,Fraud ,Overcharging ,Field (Bourdieu) ,media_common.quotation_subject ,05 social sciences ,jel:D82 ,Competition (economics) ,Credence good ,Commerce ,Information asymmetry ,Incentive ,Asymmetric information,Auto repair market,Credence goods,Expert,Fraud,Overcharging ,jel:L15 ,0502 economics and business ,Business ,050207 economics ,Statistics, Probability and Uncertainty ,Competence (human resources) ,Social Sciences (miscellaneous) ,Industrial organization ,050205 econometrics ,Reputation ,media_common - Abstract
This paper investigates the impact of four key economic variables on an expert firm's incentive to defraud its customers in a credence goods market: the level of competition, the expert firm's financial situation, its competence, and its reputational concerns. We use and complement the dataset of a nationwide field study conducted by the German Automobile Association that regularly checks the reliability of garages in Germany. We find that more intense competition and high competence lower a firm's incentive to overcharge. A low concern for reputation and a critical financial situation increase the incentive to overcharge.
- Published
- 2013
84. Price Competition and Reputation in Credence Goods Markets: Experimental Evidence
- Author
-
Wanda Mimra, Christian Waibel, and Alexander Rasch
- Subjects
TheoryofComputation_MISCELLANEOUS ,Economics and Econometrics ,media_common.quotation_subject ,jel:D82 ,05 social sciences ,Customer information ,Competition (economics) ,Microeconomics ,Credence good ,Incentive ,jel:L15 ,0502 economics and business ,Economics ,Expert ,Fraud ,Price competition ,Reputation ,Overcharging ,Undertreatment ,Quality (business) ,Business ,050207 economics ,Finance ,Industrial organization ,050205 econometrics ,media_common - Abstract
In credence goods markets, experts have better information about the appropriate quality of treatment than their customers. Because experts provide both the diagnosis and the treatment, there is opportunity for fraud. We experimentally investigate how the intensity of price competition and the level of customer information about past expert behavior influence experts' incentives to defraud their customers when experts can build up reputation. We show that the level of fraud is significantly higher under price competition than when prices are fixed, as the price decline under a competitive-price regime inhibits quality competition. More customer information does not necessarily reduce the level of fraud.
- Published
- 2013
- Full Text
- View/download PDF
85. Charging and aggregation of negatively charged colloidal latex particles in the presence of multivalent oligoamine cations
- Author
-
Michal Borkovec, Amin Sadeghpour, Damian Citherlet, Anna Polomska, and Istvan Szilagyi
- Subjects
Electrophoresis ,Latex ,Analytical chemistry ,Double layer forces ,Biomaterials ,Colloid ,symbols.namesake ,Colloid and Surface Chemistry ,Dynamic light scattering ,Valence (chemistry) ,Coagulation ,Chemistry ,Dynamic light cattering ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Condensed Matter::Soft Condensed Matter ,Chemical physics ,Overcharging ,ddc:540 ,symbols ,DLVO theory ,DLVO ,Amine gas treating ,van der Waals force ,Oligoamine - Abstract
Charging and aggregation of negatively charged carboxyl latex particles in the presence of positively charged linear oligoamines containing 1-6 amine groups were investigated by electrophoretic mobility and dynamic light scattering. The oligoamines of low valence resemble simple inert salts and destabilize the suspensions by screening their charge. The oligoamines of higher valence induce overcharging at low concentrations, whereby destabilization is triggered by charge neutralization. At higher concentrations, destabilization is also induced by screening. The onset of first fast aggregation regime scales with the inverse six power of the valence in agreement with the Schulze-Hardy rule. The aggregation rates can be relatively well described by the DLVO theory which indicates that the interactions are governed by van der Waals and electrostatic double layer forces.
- Published
- 2013
86. Second-Degree Moral Hazard in a Real-World Credence Goods Market
- Author
-
Balafoutas, Loukas, Kerschbamer, Rudolf, and Sutter, Matthias
- Subjects
C93 ,moral hazard ,D82 ,overtreatment ,asymmetric information ,ddc:330 ,Natural field experiment ,credence goods ,overcharging ,taxi - Abstract
Empirical literature on moral hazard focuses exclusively on the direct impact of asymmetric information on market outcomes, thus ignoring possible repercussions. We present a field experiment in which we consider a phenomenon that we call second-degree moral hazard - the tendency of the supply side in a market to react to anticipated moral hazard on the demand side by increasing the extent or the price of the service. In the market for taxi rides, our moral hazard manipulation consists of some passengers explicitly stating that their expenses will be reimbursed by their employer. This has an economically important and statistically significant positive effect on the likelihood of overcharging, with passengers in that treatment being about 13% more likely to pay higher-than-justified prices for a given ride. This indicates that second-degree moral hazard may have a substantial impact on service provision in a credence goods market.
- Published
- 2013
87. Overcharging in biological systems: reversal of electrophoretic mobility of aqueous polyaspartate by multivalent cations
- Author
-
Pavel Jungwirth, Jan Heyda, Anna Kubíčková, Erik Wernersson, Tomáš Křížek, Mario Vazdar, and Pavel Coufal
- Subjects
chemistry.chemical_classification ,Aqueous solution ,Static Electricity ,General Physics and Astronomy ,Salt (chemistry) ,Electrophoresis, Capillary ,Water ,Peptide ,Hydrogen-Ion Concentration ,Ion ,Solutions ,Electrophoresis ,Electrolytes ,Capillary electrophoresis ,chemistry ,Models, Chemical ,Chemical physics ,Cations ,Chemical specificity ,Static electricity ,multivalent cations ,electrophoresis ,overcharging ,molecular dynamics ,Metropolis Monte Carlo ,Peptides - Abstract
Charge reversal as an extreme case of charge compensation is directly observed by capillary electrophoresis for a negatively charged peptide in aqueous solutions of trivalent cations. Atomistic and coarse-grained simulations provide molecular interpretation of this eff ect showing that it is largely of electrostatic origin with a minor contribution of chemical speci ficity of the salt ions.
- Published
- 2012
88. Une analyse économique de la tarification des actes en médecine générale : quelles conséquences éthiques ?
- Author
-
Abécassis, P., Jean-Paul Domin, Domin, Jean-Paul, Centre d'Economie de l'Université Paris Nord (CEPN), LABEX ICCA, Université Paris 13 (UP13)-Université Sorbonne Nouvelle - Paris 3-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP)-Université Sorbonne Paris Nord-Université Paris 13 (UP13)-Université Sorbonne Nouvelle - Paris 3-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP)-Université Sorbonne Paris Nord-Centre National de la Recherche Scientifique (CNRS), Recherches en Économie Gestion AgroRessources Durabilité Santé- EA 6292 (REGARDS), Université de Reims Champagne-Ardenne (URCA)-Maison des Sciences Humaines de Champagne-Ardenne (MSH-URCA), Université de Reims Champagne-Ardenne (URCA)-Université de Reims Champagne-Ardenne (URCA), and Université de Montréal. Faculté des arts et des sciences. Centre de recherche en éthique
- Subjects
Ethics ,Economics ,Dépassements d'honoraires ,Actes gratuits ,Free care ,Primary care ,[SHS.ECO]Humanities and Social Sciences/Economics and Finance ,Philosophie ,Économie ,Médecine ambulatoire ,Philosophy ,Overcharging ,[SHS.ECO] Humanities and Social Sciences/Economics and Finance ,ComputingMilieux_MISCELLANEOUS ,Éthique - Abstract
Cet article s'interroge sur les pratiques tarifaires des médecins généralistes libéraux français et notamment de la succession d'actes gratuits et de dépassements d'honoraires. Il soutient l'hypothèse selon laquelle la marchandisation du système de soins se traduit par une différence (à la hausse ou à la baisse) par rapport au tarif conventionnel. La marchandisation se répercute par une augmentation des tarifs spécifiques et creuse l'écart entre le prix "juste" selon le médecin et le tarif conventionnel.
- Published
- 2012
89. Charging and stability of anionic latex particles in the presence of linear poly(ethylene imine)
- Author
-
Istvan Szilagyi, Michal Borkovec, José Hierrezuelo, and Dana Rosická
- Subjects
Electrophoresis ,Coagulation ,Molar mass ,Imine ,Flocculation ,Polyethylenimine ,Charged particle ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Biomaterials ,Aggregation ,chemistry.chemical_compound ,Colloid ,Colloid and Surface Chemistry ,Isoelectric point ,chemistry ,Dynamic light scattering ,Chemical engineering ,Overcharging ,ddc:540 ,Polymer chemistry ,Particle - Abstract
Charging properties and colloidal stability of negatively charged polystyrene latex particles were investigated in the presence of linear poly(ethylene imine) (LPEI) of different molecular masses by electrophoresis and dynamic light scattering (DLS). Electrophoretic mobility measurements illustrate that LPEI strongly adsorbs on these particles leading to charge neutralization at isoelectric point (IEP) and charge reversal. Time-resolved DLS experiments indicate that the aggregation of the latex particles is rapid near the IEP and slows down away from this point. Surprisingly, the colloidal stability does not depend on the molecular mass, which indicates that the adsorbed LPEI layer is rather homogeneous.
- Published
- 2011
90. Fraktografie hřídele turbodmychadla
- Author
-
Pokorný, Jan, Seidel, Aleš, Pokorný, Jan, and Seidel, Aleš
- Abstract
Tato bakalářská práce se zabývá způsoby přeplňování pístových spalovacích motorů a stručnou historií. Jejich konstrukcí, výhodami a nevýhodami. Praktickým úkolem bylo zjistit, proč došlo u turbodmychadla k přerušení jeho hřídele. K tomu bylo nutné provést fraktografii lomu a zjistit zatížení hřídele, což se projevilo jako nejtěžší část celé práce., This bachelor thesis deals with the ways of supercharging internal combustion engines and brief history. Their constructions, advantages and disadvantages. The practical task was to find out why in turbocharger was broken his shaft. To do this it was necessary to do a fractography of fracture and find load of the shaft, which proved to be the hardest part of the whole work., Katedra dopravních prostředků a diagnostiky, Při obhajobě student komisi seznámil s bakalářskou prací, ve které řešil problematiku přeplňování spalovacích motorů. Zaměřil se také diagnostikou správné funkce turbodmychadla, aby se zjistila správná funkce plnící tlaku, který může mít úzkou souvislost s rostoucím zatížením hřídele turbodmychdla. Na otázky vedoucího práce i členů komise odpovídal věcně správně., Dokončená práce s úspěšnou obhajobou
- Published
- 2014
91. Do various methods of charging lawyers’ fees influence the speed and the style of civil proceedings? Examples from Croatian and comparative law and practice
- Author
-
Jelinić, Zvonimir
- Subjects
Lawyers' fees ,tariff system ,overcharging ,representation before courts ,court fee schedules - Abstract
The presentation was highlighting several discrepancies of the contemporary Croatian lawyers' fee system with respect to the newest amendments of the Law on the Legal Profession.
- Published
- 2010
92. Second-degree moral hazard in a real-world credence goods market
- Abstract
Empirical literature on moral hazard focuses exclusively on the direct impact of asymmetric information on market outcomes, thus ignoring possible repercussions. We present a field experiment in which we consider a phenomenon that we call second-degree moral hazard – the tendency of the supply side in a market to react to anticipated moral hazard on the demand side by increasing the extent or the price of the service. In the market for taxi rides, our moral hazard manipulation consists of some passengers explicitly stating that their expenses will be reimbursed by their employer. This has an economically important and statistically significant positive effect on the likelihood of overcharging, with passengers in that treatment being about 13% more likely to pay higher-than-justified prices for a given ride. This indicates that second-degree moral hazard may have a substantial impact on service provision in a credence goods market.
- Published
- 2013
93. Second-degree moral hazard in a real-world credence goods market
- Abstract
Empirical literature on moral hazard focuses exclusively on the direct impact of asymmetric information on market outcomes, thus ignoring possible repercussions. We present a field experiment in which we consider a phenomenon that we call second-degree moral hazard – the tendency of the supply side in a market to react to anticipated moral hazard on the demand side by increasing the extent or the price of the service. In the market for taxi rides, our moral hazard manipulation consists of some passengers explicitly stating that their expenses will be reimbursed by their employer. This has an economically important and statistically significant positive effect on the likelihood of overcharging, with passengers in that treatment being about 13% more likely to pay higher-than-justified prices for a given ride. This indicates that second-degree moral hazard may have a substantial impact on service provision in a credence goods market.
- Published
- 2013
94. Second-degree moral hazard in a real-world credence goods market
- Abstract
Empirical literature on moral hazard focuses exclusively on the direct impact of asymmetric information on market outcomes, thus ignoring possible repercussions. We present a field experiment in which we consider a phenomenon that we call second-degree moral hazard – the tendency of the supply side in a market to react to anticipated moral hazard on the demand side by increasing the extent or the price of the service. In the market for taxi rides, our moral hazard manipulation consists of some passengers explicitly stating that their expenses will be reimbursed by their employer. This has an economically important and statistically significant positive effect on the likelihood of overcharging, with passengers in that treatment being about 13% more likely to pay higher-than-justified prices for a given ride. This indicates that second-degree moral hazard may have a substantial impact on service provision in a credence goods market.
- Published
- 2013
95. Second-degree moral hazard in a real-world credence goods market
- Abstract
Empirical literature on moral hazard focuses exclusively on the direct impact of asymmetric information on market outcomes, thus ignoring possible repercussions. We present a field experiment in which we consider a phenomenon that we call second-degree moral hazard – the tendency of the supply side in a market to react to anticipated moral hazard on the demand side by increasing the extent or the price of the service. In the market for taxi rides, our moral hazard manipulation consists of some passengers explicitly stating that their expenses will be reimbursed by their employer. This has an economically important and statistically significant positive effect on the likelihood of overcharging, with passengers in that treatment being about 13% more likely to pay higher-than-justified prices for a given ride. This indicates that second-degree moral hazard may have a substantial impact on service provision in a credence goods market.
- Published
- 2013
96. Experimental and theoretical evidence of overcharging of calcium silicate hydrate
- Author
-
André Nonat, Christophe Labbez, Isabelle Pochard, Bo Jönsson, Laboratoire Interdisciplinaire Carnot de Bourgogne (LICB), Université de Bourgogne (UB)-Centre National de la Recherche Scientifique (CNRS), Theoretical Chemistry (THEORETICAL CHEMISTRY), Chemical Center, Laboratoire Interdisciplinaire Carnot de Bourgogne ( LICB ), Centre National de la Recherche Scientifique ( CNRS ) -Université de Bourgogne ( UB ), and Theoretical Chemistry ( THEORETICAL CHEMISTRY )
- Subjects
Surface Properties ,Analytical chemistry ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Biomaterials ,Electrokinetic phenomena ,chemistry.chemical_compound ,Colloid and Surface Chemistry ,Zeta potential ,Electrochemistry ,Surface charge ,Colloids ,Calcium silicate hydrate ,Particle Size ,Monte Carlo simulation ,Range (particle radiation) ,Physics::Biological Physics ,Quantitative Biology::Biomolecules ,Silicates ,Water ,Calcium Compounds ,021001 nanoscience & nanotechnology ,Electrostatics ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,[ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph] ,Electrophoresis ,Kinetics ,chemistry ,Models, Chemical ,Chemical physics ,Surface charge titration ,Overcharging ,Calcium silicate ,Nanoparticles ,[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph] ,0210 nano-technology ,Monte Carlo Method - Abstract
International audience; Electrokinetic measurements such as electrophoresis may show an inversion of the effective surface charge of colloidal particle called overcharging. This phenomenon has been studied by various theoretical approaches but up to now very few attempts of confrontation between theory and experiment have been conducted. In this work we report electrophoretic measurements as well as Monte Carlo simulations of the electrokinetic potential for the surface of calcium silicate hydrate (Csingle bondSsingle bondH), which is the major constituent of hydrated cement. In the simulations, the surface charge of Csingle bondSsingle bondH nanoparticles in equilibrium with the ionic solution is determined by a single site characteristic and electrostatic interactions between all explicit charges at the surface and in the electric double layer. We will show that ordinary electrostatic interactions are enough to describe all experimental observations. Actually, an excellent agreement is found between experimental and simulated results without any fitting parameter, both with respect to surface titration and electrokinetic behaviour. The agreement extends over a wide range of electrostatic coupling, from a weakly charged surface with mainly monovalent counter-ions to a highly charged one with divalent counter-ions.
- Published
- 2007
- Full Text
- View/download PDF
97. Electrical Double Layer on Silver Iodide and Overcharging in the Presence of Hydrolyzable Cations
- Author
-
Johannes Lyklema and Tatiana Golub
- Subjects
inorganic chemicals ,electrical double layer ,silver iodide ,surface charge ,overcharging ,charge reversal ,hydrolysis at interfaces - Abstract
Previous studies on the surface charge and electrokinetic charge on silver iodide as a function of the pAg in the presence of some monovalent and trivalent cations as the counterions were extended to include the influence of pH. The main reason for this study was to investigate the possible propensity of overcharging by adsorption of hydrolyzed counterions. It was found that for K+ as the counterion the double layer properties could be well represented in terms of a simple Gouy-Stern model, without accounting for hydrolysis. However, with Al3+ or La3+ as the counterions, adsorption of hydrolyzed species takes place when the pH is high enough, leading to electrokinetic charge reversal.
- Published
- 2007
98. The many facets of polyelectrolytes and oppositely charged macroions complex formation
- Author
-
Marianne Seijo, Serge Ulrich, and Serge Stoll
- Subjects
Polymers and Plastics ,Chemistry ,Complex formation ,Nanotechnology ,Surfaces and Interfaces ,Polyelectrolyte ,Polyelectrolytes ,Weak and strong polyelectrolytes ,Colloid and Surface Chemistry ,polyelectrolyte conformations ,complex formation ,Overcharging ,ddc:540 ,Macroion ,Macroions ,Physical and Theoretical Chemistry ,Monte Carlo - Abstract
A review. Various models of the complex formation between polyelectrolyte chains and oppositely charged macroions are reviewed. In recent years, a great deal of knowledge of the multitude of possible polyelectrolyte conformations at the macroion surface has been accumulated, which consequently has led to increasing interest in using such complexes in the design of nanomaterials. This review focuses on key studies relating to the effects of various physico-chem. parameters on complex formation and areas for future research are identified.
- Published
- 2006
99. "Make Him an Offer He Can't Refuse"-- Mezzanatto Waivers as Lynchpin of Prosecutorial Overreach
- Author
-
Mueller, Christopher B.
- Subjects
- plea bargaining, waivers, Mezzanatto, Rules of Evidence, impeachment, overcharging, overincarceration, overcriminalization, prosecutors, exclusionary principles, Contracts, Courts, Criminal Procedure, Evidence, Supreme Court of the United States
- Abstract
Plea bargaining is the dominant means of disposing of criminal charges in the United States, in both state and federal courts. This administrative mechanism has become a system that is grossly abusive of individual rights, leading to many well-known maladies of the criminal justice system, which include overcharging, overincarceration, convictions on charges that would likely fail at trial, and even conviction of “factually innocent” persons. Instrumental in the abuses of plea bargaining is the so-called Mezzanatto waiver, which takes its name from a 1995 Supreme Court decision that approved the practice of getting defendants to agree that anything they say in negotiations with prosecutors can be admitted against them if a trial ensues, despite Evidence Rule 410, which provides that such statements are inadmissible. These waivers, which are largely overlooked in the vast literature that criticizes plea bargaining, are in fact lynchpins in a system that is horrifying to contemplate. These waivers mean that the very act of negotiation almost guarantees conviction of something, imposing one-sided risks on defendants that can only benefit prosecutors. They amount to a kind of palpable unfairness that the system tolerates. They not only contribute to the maladies described above, but they produce rulings (if a trial goes forward) that admit unreliable statements. There are many reasons why these waivers should be disapproved, including policy arguments (they are unfair, produce bad results and unreliable statements) and arguments based on contract law, on Rule 410 itself, on a widely-recognized but seldom enforced “unitary” principle, and – finally – on the “Mezzanatto proviso” (a widely ignored term in the decision itself). This Article explores the origins and operation of Mezzanatto waivers, examines and expounds the reasons for disapproving them and taking a new direction, and offers a reply to standard arguments that prosecutors need them (they really do not and have other means to hold defendants to their bargains).
- Published
- 2017
100. Overcharge tolerant high-temperature cells and batteries
- Author
-
Nelson, Paul [Wheaton, IL]
- Published
- 1989
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.