51. Climatic controls on leaf wax hydrogen isotope ratios in terrestrial and marine sediments along a hyperarid to humid gradient.
- Author
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Lugo, Nestor Gaviria, Läuchli, Charlotte, Wittmann, Hella, Bernhard, Anne, Frings, Patrick, Mohtadi, Mahyar, Rach, Oliver, and Sachse, Dirk
- Subjects
HYDROGEN isotopes ,MARINE sediments ,PALEOHYDROLOGY ,PLANT transpiration ,ARID regions ,WAXES ,PLANT-water relationships - Abstract
The hydrogen isotope composition of leaf wax biomarkers (δ
2 Hwax ) is a valuable tool for reconstructing continental paleohydrology, as it serves as a proxy for the hydrogen isotope composition of precipitation (δ2 Hpre ). To yield robust palaeohydrological reconstructions using δ2 Hwax in marine archives, it is necessary to examine the impacts of regional climate on δ2 Hwax and assess the similarity between marine sedimentary δ2 Hwax and the source of continental δ2 Hwax . Here, we examined an aridity gradient from hyperarid to humid along the Chilean coast. We sampled sediments at the outlets of rivers draining into the Pacific, soils within catchments and marine surface sediments adjacent to the outlets of the studied rivers and analyzed the relationship between climatic variables and δ2 Hwax values. We find that apparent fractionation between leaf waxes and source water is relatively constant in humid/semiarid regions (average: −121 ‰). However, it becomes less negative in hyperarid regions (average: −86 ‰) as a result of evapotranspirative processes affecting soil and leaf water2 H enrichment. We also observed that along strong aridity gradients, the2 H enrichment of δ2 Hwax follows a non-linear relationship with water content and water flux variables, driven by strong soil evaporation and plant transpiration. Furthermore, our results indicated that δ2 Hwax values in marine surface sediments largely reflect δ2 Hwax values from the continent, confirming the robustness of marine δ2 Hwax records for paleohydrological reconstructions along the Chilean margin. These findings also highlight the importance of considering the effects of hyperaridity in the interpretation of δ2 Hwax values and pave the way for more quantitative paleohydrological reconstructions using δ2 Hwax . [ABSTRACT FROM AUTHOR]- Published
- 2023
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