1,060 results on '"Rauchfuss, Thomas B."'
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52. Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates
53. Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-propanedithiolate Ligand
54. Synthetic Models for Bioorganometallic Reaction Centers
55. Third-order nonlinear optical properties of sulfur-rich compounds
56. Dehydrogenative route to metallo dithiolenes: the reaction of zinc polysulfides and alkenes
57. Binding of alkenes to ReS4-
58. Alkali metal-templated assembly of cyanometalate 'boxes' (NEt4)3(M(Cp*Rh(CN)3)4(Mo(CO)3)4) (M = K, Cs). Selective binding of Cs+
59. [Me 8Pt 4ReS 4] − and related PtMe 2-containing clusters derived from tetrathiorhenate
60. A polymeric binary titanium(IV) sulfide and its conversion to molecular Lewis base adducts
61. Synthesis of Transition Metal Dithiolenes
62. Effect of ancillary ligands on the reactivity and structure of zinc polysulfido complexes
63. Studies on the electroactive heterocycles C(sub6)S(sub8)(super0/2-) and C(sub6)S(sub6)O(sub2)(super0/2-) and related metal complexes
64. Functionalization of Cp4Fe4(CO)4: contrasts and comparisons with ferrocene
65. Sulfido-persulfido equilibria in sulfur-rich metal clusters: the case of (C5Me5)3RhRu2Ssub4sup2+
66. Iron sulfido derivatives of the fullerenes C60 and C70
67. Structural and mechanistic studies on ion insertion into the molecular box {[CpCo(CN) 3] 4[Cp*Ru] 4}
68. Biosynthesis of the [FeFe] hydrogenase H-cluster via a synthetic [Fe(II)(CN)(CO)2(cysteinate)]− complex.
69. Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation.
70. Pairwise mobility of metal-metal bonds in (MeC5H4)4Ru4S3(SMe)(super n+)
71. One step closer to structural models of HDS catalysts: thienyl-oxo complexes of Re(V)
72. Binary carbon sulfides based on the alpha-C3S5 subunit and related C-S-O, C-S-Cl, and C-S-N compounds
73. Mobile metal-metal bonds: studies on mixed valence Ir3 and Ir4 clusters
74. Synthetic and structural studies on (RC5H4)4Ru4E(sub 4)(super 0/2+) (E = S, Se, Te): mobile metal-metal bonds within a mixed-valence Ru(IV)/Ru(III) cluster
75. Arene vs thiophene reduction in the system (C6R6)Ru(C4R4S)2+ and the protonation of eta4-thiophene ligands
76. Base hydrolysis of coordinated thiophene in (C5R5)Rh(C4Me4S)2+: nucleophilic attack at divalent sulfur and the reversible cleavage of C-S bonds
77. Electronic structure of metal chalcogen cubane clusters: photoelectron spectroscopic, electrochemical, and theoretical studies of (eta-C5H4Me TiS)4, (eta-C5H4Me VS)4, (eta-C5H5 CrO)4, (eta-C5H4Me CrO)4, (eta-C5H4Me CrS)4, (eta-C5H4Me CrSe)4, (eta-C5H4 super i Pr MoS)4, and (eta-C5H4 super i Pr MoSe)4
78. Synthetic studies on the CpRu-PPh3-(Se2) system: redox interconversions of Ru2(Se2)2 cores
79. Redistribution of reduced thiophene ligands in the conversion of (C5R5)Rh(eta4-C4Me4S) to ((C5R5)Rh)3(eta4,eta1-C4Me4S)2
80. Acid—Base Chemistry of Transition-Metal—π-Thiophene Complexes
81. Vibrational Perturbation of the [FeFe] Hydrogenase H‑Cluster Revealed by 13C2H‑ADT Labeling.
82. The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO) 2 (CN)] organometallic precursor
83. Iron Carbide–Sulfide Carbonyl Clusters
84. Redox and “Antioxidant” Properties of Fe2(μ-SH)2(CO)4(PPh3)2
85. Synthetic Designs and Structural Investigations of Biomimetic Ni–Fe Thiolates
86. Binary Carbon Sulfides: Unusual Molecules and Materials
87. Computational and Experimental Investigations of the Fe2(μ‑S2)/Fe2(μ-S)2 Equilibrium.
88. New class of diiron dithiolates related to the Fe-only hydrogenase active site: synthesis and characterization of [Fe(sub)2(SR)(sub)2(CNMe)(sub)7](sup)2+
89. New class of ruthenium sulfide clusters: Ru (sub)4 S (sub)6 (PPh (sub)3) (sub)4, Ru (sub)5 S (sub)6 (PPh (sub)3) (sub)5, and Ru (sub)6 S (sub)8 (PPh (sub)3) (sub)6
90. A new synthesis of tetrathiooxalate and its conversion to C3S5(super 2-) and C4S6(super 2-)
91. Reaction Coordinate Leading to H2Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory
92. Sterically Stabilized Terminal Hydride of a Diiron Dithiolate
93. Reactions of [Fe6C(CO)14(S)]2–: Cluster Growth, Redox, Sulfiding.
94. The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO)2(CN)] organometallic precursor.
95. Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation
96. Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C–S Bond Homolysis in a Mixed Valence Diiron Dithiolate
97. A [RuRu] Analogue of an [FeFe]‐Hydrogenase Traps the Key Hydride Intermediate of the Catalytic Cycle
98. Sterically Stabilized Terminal Hydride of a Diiron Dithiolate
99. Ni(ii) complexes of the phosphine-oxime Ph2PC6H4-2-CHNOH
100. Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory
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