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Rice serves as a vital staple food, but its accumulation of cadmium (Cd) has sparked widespread concerns regarding food safety and ecosystem security. Here, we conducted a seven-year systematic field experiment in the Xiangjiang River Basin of China, where an integrated governance framework (IGF) was established to ensure rice safety. The IGF, tailored to geographical zoning and pollution gradation, includes targeted soil treatments, crop management strategies, and stakeholder engagement. The quality of both the soil and the crop was improved, with a reduction in soil Cd availability of 36%, and a decrease in Cd in rice grain of 57-78%. This framework not only addresses multiple challenges but also supports sustainable development goals (SDGs 2, 3, 6, 9) by fostering comprehensive synergies among science, policy, and local community participation. Our findings provide empirical guidance for safe rice production in Cd-contaminated areas and provide solid scientific-driven decision support globally., Competing Interests: Competing interests The authors declare no competing interests., (© 2024. The Author(s).)

The pesticide glyphosate has contributed immensely to the ease of farming and high yields. However, the ever-increasing environmental input of pesticides is of particular interest due to several unintended effects on non-target organisms. In soil, the sorption, transport, possible uptake, and effect on plant growth are still not well understood, and much so for the sub-Sahara. Sorption processes are contingent on the soil composition, characteristics, and ambient conditions, and these are becoming increasingly affected by climate change in a way that may alter pesticide fate. Hence, representative sub-Saharan whole soil (WS) treated to eliminate organic matter (OMR) and iron oxides (IOR) was employed to ascertain the contributions of these major constituents to glyphosate sorption processes, as well as ascertain the effect of glyphosate in soil on the growth of Talinum triangulare -waterleaf. Glyphosate sorption for all treatments was rapid with equilibrium at around 720 min. The sorption decreased as pH increased, and was concentration-dependent, gradually increasing with glyphosate concentration. The process was endothermic, and sorption data were better described by the fractal pseudo-second-order and Freundlich adsorption isotherm models, suggesting a complex interplay of interactive sorption forces. The IOR sample (with iron oxide depleted but organic matter intact) exhibited higher sorption than the OMR and WS, highlighting the contribution of organic matter in glyphosate sorption. Hysteresis was high for all samples and increased with temperature. Considering the unregulated usage of glyphosate in the sub-Sahara, the poor sorption, especially in treated soils, observed in this study suggests a high possibility of glyphosate leaching into the aquifer and poisoning of this water source, while the high hysteresis implied the bio-availability of glyphosate in surface soil for plant absorption, hence affecting growth; as confirmed in the waterleaf growth study where growth in the organic-matter/iron-oxide-depleted soils was substantially stunted. Hence, glyphosate affects waterleaf growth, especially in organic-matter/iron-oxide-depleted soils.

China aims to actively control the contamination of globally concerning per- and polyfluoroalkyl substances (PFASs). Evaluation of the current situation can provide a critical reference point for tracking the effectiveness of ongoing progress. Herein, we present the first comprehensive assessment of the spatial variations of 20 legacy and 54 novel PFASs in Chinese background soils in 2021. Novel PFASs were extensively detected in 98.4% of the samples, with 21 species being first reported, which greatly facilitated the appointment of diverse emission sources that aligned with local industrial structures. However, legacy PFASs still dominated the ∑ 74 PFAS profile (median 0.51 ng/g, 0.050-8.33 ng/g). The spatial heterogeneity of soil PFASs was positively driven by economic development and atmospheric deposition, enabling the establishment of predictive models to project the national distribution and temporal trends. Elevated PFAS levels were predominantly distributed in the more industrialized eastern and southern regions, as well as other coastal areas with greater precipitation. ∑ 74 PFAS in surface soils was estimated to increase by 12.9 pg/(g year) over 2002-2021, which would continue alongside economic growth, albeit with greater contributions from novel alternatives. Our work provides comprehensive baseline and predictive data to inform policies toward PFAS control in China.

Irregular waste storage at closed mine sites poses severe environmental problems. This study evaluates the concentrations and effects of trace elements released into the environment by mining activity by analyzing soil, water, and sediment samples taken from a copper mining site. According to the data, acidic mine drainage was the main cause of the high concentrations of trace elements in the soil and sediments, including arsenic (As), cadmium (Cd), lead (Pb), and copper (Cu). The concentrations of As, Cd, Pb, and Cu in soil and sediments were 2734-times, 1189-times, 157-times and 32 times higher, respectively, in comparison to the background values of averaged concentrations of these elements in the upper crust. Geological and statistical studies indicate that the primary constituents of these pollutants are chalcopyrite and pyrite derivatives present in the primary rock structure. Using water analysis data from 2011 to 2020, the release of essential trace element into water was investigated to monitor the environmental effects of acidic mine drainage (AMD) from the closed Kuvarshan copper mine in the Artvin region of Turkey. This study demonstrates that trace elements concentrations may change according to local and seasonal factors and highlights the importance of conducting routine environmental monitoring studies., Competing Interests: Declarations Conflict of interest The authors declare no competing interests., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

In order to determine the priority control elements and sources of heavy metal(loid)s (HMs) pollution in park dust, this study collected dust samples from 25 parks in the urban area of Mianyang City and measured the contents of 10 HMs. Based on Monte Carlo simulation, the probabilistic pollution levels and ecological-health risks of HMs were assessed. We found that the average contents of Zn, Co, Pb, and Cr were much higher than their background values in local soil and were influenced by artificial activities. The pollution assessment found that 5 parks were moderately polluted. The comprehensive pollution of HMs in the dust was mainly caused by Zn and Cr, and industrial source was the main contributor to Zn and Cr pollution. The contribution of As, Co, and Pb to the comprehensive ecological risk was high, accounting for 54.6%. Co, Pb, and As were the priority control HMs of ecological risk, while mixed source and industrial source were the priority control sources. HMs presented potential carcinogenic health risks to both children and adults. The non-carcinogenic risk to adults was within safety level, while some parks showed non-carcinogenic risk to children, which should be paid attention to. The source-specific health risk assessment showed that Cr and As were the priority control HMs for human health, while mixed source and industrial source were the priority control sources., Competing Interests: Declarations Competing interests The authors declare no competing interests.Correspondence and requests for materials should be addressed to X. L., (© 2024. The Author(s).)

Soil trace metal (TM) contamination is a worldwide issue and threatens food production and security. Remediation of cadmium (Cd) and zinc (Zn) contaminated soils by phytoextraction with the Zn/Cd hyperaccumulator Noccaea caerulescens is widely studied but few studies have investigated the efficiency of this technique to reduce Cd and Zn soil-to-crop transfers to subsequent vegetable crops. The vegetable biomonitor rocket Diplotaxis tenuifolia was grown in pots on 13 moderately contaminated soils that had previously been cropped with N. caerulescens. Using mixed-effects models, we show the drivers of rocket biomass, Cd and Zn concentrations. Our models show, for our study soils, the benefit of previous N. caerulescens uptake of Cd and Zn in decreasing Cd and Zn concentrations in a subsequent rocket crop. We also show a slight positive impact of N. caerulescens biomass (and therefore uptake) on rocket growth. Our data show that exchangeable soil concentrations are major drivers of Cd and Zn rocket concentrations. Other soil variables negatively driving rocket Cd and Zn concentrations are NO 3 - content, organic matter content, cation exchange capacity, and soil manganese which stimulate rocket biomass and/or influence TM bioavailability. Rocket D. tenuifolia seems to be a good biomonitor for contaminated soils as it is tolerant to relatively high TM soil concentrations. We demonstrate that 40 % of rockets grown on soils below 2 mg total Cd kg -1 dry soil have foliar Cd concentrations above the European maximum allowed level confirming the need to review soil legal thresholds to protect consumers' health. In conclusion, our study suggests promising use of N. caerulescens phytoextraction for bioavailable contaminant stripping which is all the more interesting given the increasing demand for urban growing spaces., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Thermal remediation is an effective technology for organic contaminant remediation. However, the application of thermal remediation may have negative effects on soil properties and ecological functions, which requires further investigation. Based on a pilot test of electrical resistance heating remediation (ERH), soil samples were collected at different locations after heating for 116 days. Most soil physicochemical properties were less affected by the heating temperature difference. Application of high temperature increased microbial abundance but inhibited alpha diversity of the bacterial community. More significant changes in microbial communities were observed at temperatures above 60 °C. The genera mainly affected by heating temperature included Flavobacteria, Brockia, and S085, while the increase in temperature also inhibited the abundance of nitrochlorobenzene functional genes. At 140 days after the end of the pilot test, the bacterial community affected by thermal remediation could recover effectively, and the recovery of the bacterial community was not affected by temperature difference during the heating period. This study provides valuable field evidence of the long term impact of soil ERH treatment on soil properties and microbial communities, and provides further references for optimization of remediation performance with coupled technologies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Our study provides the most comprehensive dataset for high-precision radiogenic isotopes of lead (Pb) in blood for the western European population. It investigates their potential for elucidating the contribution of soil Pb to blood Pb using a human biomonitoring survey involving 81 adults and 4 children living in the urban area of Liège (Belgium). Soils in the area show moderate (median of 360 mg/kg) to high (95th percentile of 1000 mg/kg) Pb concentrations, due to former metal processing activities. Blood lead levels (BLL) measured in the study population are, on average, quantitatively consistent with a ∼ 20 % increase due to the exposure to Pb from soils, as estimated by a single-compartment biokinetic model. Consistently, its isotopic composition does not represent an endmember that fully accounts for the variability of Blood lead isotope (BLI) compositions measured in the study population. While some individuals show more thorogenic BLI ratios (relatively more enriched in 208 Pb), which could be consistent with a greater exposure to local soils and/or by their country of birth, the BLI data mostly follow a trend roughly parallel to the European Standard Lead Pollution (ESLP) line, within the European leaded gasoline field, even two decades after the withdrawal of this source. Differences in BLI are probably associated with factors related to the presence of Pb in dwellings (pipes, paint) and drinking water distribution system, suggesting that the anthropogenic Pb in use, relevant to human exposure, may contain ore components of different origins, including the Australian Pb ore signature., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Petit reports financial support was provided by Walloon Public Service. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)

Due to the wastewater irrigation or biosolid application, per- and polyfluoroalkyl substances (PFASs) have been widely detected in agriculture soil and hence crops or vegetables. Consumption of contaminated crops and vegetables is considered as an important route of human exposure to PFASs. Machine learning (ML) models have been developed to predict PFAS uptake by plants with majority focus on roots. However, ML models for predicting accumulation of PFASs in above ground edible tissues have yet to be investigated. In this study, 811 data points covering 22 PFASs represented by molecular fingerprints and 5 plant categories (namely the root class, leaf class, cereals, legumes, and fruits) were used for model development. The Extreme Gradient Boosting (XGB) model demonstrated the most favorable performance to predict the bioaccumulation factors (BAFs) in all the 4 plant tissues (namely root, leaf, stem, and fruit) achieving coefficients of determination R 2 as 0.82-0.93. Feature importance analysis showed that the top influential factors for BAFs varied among different plant tissues, indicating that model developed for root concentration prediction may not be feasible for above ground parts. The XGB model's performance was further demonstrated by comparing with data from pot experiments measuring BAFs of 12 PFASs in lettuce. The correlation between predicted and measured results was favorable for BAFs in both lettuce roots and leaves with R 2 values of 0.76 and 0.81. This study developed a robust approach to comprehensively understand the uptake of PFASs in both plant roots and above ground parts, offering key insights into PFAS risk assessment and food safety., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Dissolved organic matter (DOM) plays a critical role in driving the development of biogeochemical functions in revegetated metal smelting slag sites, laying a fundamental basis for their sustainable rehabilitation. However, the DOM composition at the molecular level and its interaction with the microbial community in such sites undergoing long-term direct revegetation remain poorly understood. This study investigated the chemodiversity of DOM and its association with the bacterial community in the rhizosphere and non-rhizosphere slags of four plant species (Arundo donax, Broussonetia papyrifera, Cryptomeria fortunei, and Robinia pseudoacacia) planted at a zinc smelting slag site for 10 years. The results indicated that the relative abundance of lipids decreased from 18 % to 5 %, while the relative abundance of tannins and lignins/CRAM-like substances increased from 4 % to 10 % and from 44 % to 64 % in the revegetated slags, respectively. The chemical stability of the organic matter in the rhizosphere slag increased due to the retention of recalcitrant DOM components, such as lignins, aromatics, and tannins. As the diversity and relative abundance of the bacterial community increased, particularly within the Proteobacteria, there was better utilization of recalcitrant components (e.g., lignins/CRAM-like compounds), but this utilization was not invariable. In addition, potential preference associations between specific bacterial OTUs and DOM molecules were observed, possibly stimulated by heavy metal bioavailability. Network analysis revealed complex connectivity and strong interactions between the bacterial community and DOM molecules. These specific interactions between DOM molecules and the bacterial community enable adaptation to the harsh conditions of the slag environment. Overall, these findings provide novel insights into the transformation of DOM chemodiversity at the molecular level at a zinc smelting slag sites undergoing long-term revegetation. This knowledge could serve as a crucial foundation for developing direct revegetation strategies for the sustainable rehabilitation of metal smelting slag sites., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Global water scarcity entailed the use of treated wastewater (TWW) in agriculture, however, this water can vehiculate numerous pollutants into soil and further crops such as microplastics (MPs). To date, few studies had quantified the accumulation of MPs in soils and earthworms after irrigation with TWW as well as their toxicological effects. Hence, the main objective of the present work is to evaluate the toxicity of MPs using Lumbricus sp. earthworms collected from TWW irrigated soils with an increasing gradient of time (5 years, 16 years and 24 years). MPs determination in soil, as well as in earthworms were performed. The intestinal mucus was quantified, and cytotoxicity (Lysosomal membrane stability (LMS), Catalase (CAT) and glutathione-S-Transferase (GST) activities), neurotoxicity (Acetylcholinesterase activity (AChE)) and genotoxicity (Micronuclei frequency (MNi)) biomarker were assessed. Our results revealed that the use of TWW rendered MPs accumulation in earthworms' tissues and induce alteration on the intestinal mucus. An important cytotoxicity time-depending was observed being associated with an increase on genotoxicity. Overall, the present investigation highlights the ecotoxicological risk associated with the use of TWWs as an important driver of MPs and consequently measures are necessary to reduce MPs in wastewater treatment plans to improve this non-conventional water quality., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Selenium (Se)-rich farmland is a valuable and nonrenewable resource for addressing the global challenge of Se deficiency. However, frequent warnings of heavy metal pollution have threatened the safety and legitimacy of Se-rich functional agriculture, eventually damaged public health security. Definitive and judgmental quantitative studies on this hazardous phenomenon are still missing. Relevant reviews published in the past have summarized textual descriptions of the problem, lacking the support of the necessary statistical analysis of the data. Based on the collected publications, the present study evaluated and analyzed the sources, risks and impacts of heavy metal pollution in Se-rich farmland. Concentrations of cadmium (Cd), arsenic, lead and zinc in Se-rich farmland were significantly higher than those in non-Se-rich farmland, especially Cd. Pollution source analyses indicated that Se enrichment and heavy metal pollution occurred simultaneously in farmland, related to Se-heavy metal homology in rocks. According to environmental risk assessment, both serious Cd pollution and the narrow Se concentration range of safety utilization limited the availability of Se-rich farmland. Pollution impact predictions showed that the pollution in Se-rich farmland would result in serious human health risks to consumers and economic losses of 4000 yuan/hm 2 on production side. Tackling Cd pollution was anticipated to recover economic losses (81 %) while lowering the carcinogenic (60 %) and non-carcinogenic (10 %) health risks. Our study also provided recommendations to address heavy metal pollution in Se-rich farmland. The two criteria should be followed by pollution control strategies applied to Se-rich functional agriculture including (i) not affecting the original Se enrichment in plant and (ii) not being interfered by Se in soil-plant systems. This will provide valuable information for Se-rich functional agriculture and public health security., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Arsenic and PAHs impose environmental stress on soil microorganisms, yet their compound effects remain poorly understood. While soil microorganisms possess the ability to metabolize As and PAHs, the mechanisms of microbial response are not fully elucidated. In our study, we established two simulated soil systems using soil collected from Xixi Wetland Park grassland, Hangzhou, China. The As-600 Group was contaminated with 600 mg/kg sodium arsenite, while the As-600-PAHs-30 Group received both 600 mg/kg sodium arsenite and 30 mg/kg PAHs (phenanthrene:fluoranthene:benzo[a]pyrene = 1:1:1). These systems were operated continuously for 270 days, and microbial responses were assessed using high-throughput sequencing and metagenomic analysis. Our findings revealed that compound contamination significantly promoted the abundance of microbial defense-related genes, with general defense genes increasing by 11.07 % ∼ 74.23 % and specific defense genes increasing by 44.13 % ∼ 55.74 %. The dominate species Rhodococcus adopts these general and specific defense mechanisms to resist compound pollution stress and gain ecological niche advantages, making it a candidate strain for soil remediation. Our study contributes to the assessment of ecological damage caused by As and PAHs from a microbial perspective and provides valuable insights for soil remediation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Residual pesticides in agricultural environments, including soil and irrigation water, can be taken up by plants, and thus pose a potential risk to food safety. Although tolfenpyrad has been widely used in tea plantations, limited information is available on its root uptake and fate in tea plants (Camellia sinensis L.). Exploring the mechanisms involved is crucial for understanding the migration and accumulation of tolfenpyrad in tea plants, particularly in the edible parts. In this study, root uptake of tolfenpyrad and its subsequent translocation, distribution, and metabolism in tea seedlings were investigated. The results indicated that the passive transport and apoplastic pathway dominated the root uptake of tolfenpyrad. After uptake, tolfenpyrad distributed predominantly in the cell walls (90.8-92.0 %) of roots, resulting in limited upward translocation in water-soluble fractions through transpirational pull, with translocation factor values far <1 (TF stem/root  = 0.115-0.453 and TF leaf/stem  = 0.039-0.184). Similar accumulation patterns were observed for the carboxylated metabolite PT-CA as well as hydroxylated metabolite PT-OH. Interestingly, the subcellular distribution of PT-CA in stems was much different from that of the parent tolfenpyrad: PT-CA mainly distributed in the stem cell walls (41.72 %) and cell organelles (56.18 %) at 3 h, then gradually transferred into the cell-soluble fractions (33.07 %) after 120 h. Results from the present study indicated limited upward translocation of tolfenpyrad with its main metabolites to leaves. This finding helps to alleviate concerns about environmental residual tolfenpyrad in tea consumption and provides valuable information for the safety evaluation of tolfenpyrad., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The pervasive presence of microplastics has emerged as a pressing global environmental concern, posing threats to food security and human health upon infiltrating agricultural soils. These microplastics primarily originate from agricultural activities, including fertilizer inputs, compost-based soil remediation, irrigation, and atmospheric deposition. Their remarkable durability and resistance to biodegradation contribute to their persistent presence in the environment. Microplastics within agricultural soils have prompted concerns regarding their potential impacts on agricultural practices. Functioning as significant pollutants and carriers of microcontaminants within agricultural ecosystems, microplastics and their accompanying contaminants represent ongoing challenges. Within these soil ecosystems, the fate and transportation of microplastics can detrimentally affect plant growth, microbial communities, and, subsequently, human health via the food chain. Specifically, microplastics interact with soil factors, impacting soil health and functionality. Their high adsorption capacity for hazardous microcontaminants exacerbates soil contamination, leading to increased adverse effects on organisms and human health. Due to their tiny size, microplastic debris is easily ingested by soil organisms and can transfer through the food chain, causing physiological and/or mechanical damage. Additionally, microplastics can affect plant growth and have the potential to accumulate and be transported within plants. Efforts to mitigate these impacts are crucial to safeguarding agricultural sustainability and environmental health. Future research should delve into the long-term impacts of environmental aging processes on microplastic debris within agricultural soil ecosystems from various sources, primarily focusing on food security and human beings., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The photodegradations of three selected neonicotinoid insecticides nitenpyram, thiacloprid, and acetamiprid were investigated in both water and soil samples under natural sunlight, UVA light, and UVB light. The results indicate that these insecticides undergo significant degradations when subjected to sunlight, whether they are in deionized (DI) water, tap water, and DI water containing 100 mg/L humic acids or in soil. The degradation half-lives of nitenpyram, thiacloprid, and acetamiprid in tap water under sunlight were found to be 3.7, 4.7, and 8.9 h, respectively, in DI water 5.4, 6.3, 9.1 h, respectively, in DI water containing 100 mg/L humic acids 3.6, 3.3, 6.5 h, respectively, and in soil 7.5, 7.9, and 15.9 h, respectively. The degradation due to hydrolysis was found insignificant as compared to photodegradation. The examination of the effects of light source revealed that the UVB in the sunlight plays a major role in the photodegradation of these three neonicotinoids, and the effects of UVA and visible light are negligible. The analysis on the degradation products indicated that the nitroguanidine group in these insecticides is unstable and prone to break up under sunlight. A total of nine degradation products were detected, of which the health effects and the fate and transport in the environment need to be further studied., (© 2024. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.)

In recent years, industrial waste and agrochemicals have reduced soil fertility and productivity, significantly impacting food security and ecosystems. In China, areas near red mud deposits from the aluminum industry show severe heavy metal contamination. This study examines agricultural soil near a red mud site in Shanxi Province, analyzing Cd, Cr, Hg, Ni, Pb, As, Cu, and Zn levels and distribution. Geostatistical methods and GIS are utilized to assess heavy metal pollution using the single factor index, the Nemerow integrated index, and the Hakanson potential ecological risk index. Absolute Principal Component Scores-Multiple Linear Regression (APCS-MLR) and Positive Matrix Factorization (PMF) models are used for quantitative analysis of pollution sources. Research indicates that the average concentrations of eight heavy metals exceed the natural background values of Shanxi, placing them at a severe pollution level with moderate ecological risk. Specifically, indices for As, Pb, and Cr are 3.79, 3.38, and 3.26, indicating severe pollution; Cd, Cu, and Hg at 2.36, 2.62, and 3.00 suggest moderate pollution; Ni at 1.87 shows mild pollution, while Zn at 0.97 is not polluted. Hg presents the highest ecological risk with a coefficient of 120.00, followed by Cd (70.69) and As (37.92). Spatial analysis shows significant correlations among Pb, Zn, Cu, and Ni, while Cr, Cd, Hg, and As show greater variability and weaker correlations. Both models identify five main sources: industrial activities, agricultural fertilizers, red mud leachate, energy combustion, and natural geological backgrounds, with respective contribution rates in the APCS-MLR model at 27.7%, 24.6%, 18.1%, 15.2%, and 14.4%, and in the PMF model at 29.2%, 21.5%, 16.9%, 16.7%, and 15.7%. This study offers a scientific basis for controlling soil pollution in the region, filling a literature gap., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

The prevalence of microplastics (MPs) in agricultural ecosystems poses a notable threat to dynamics of soil ecosystems, crop productivity, and global food security. MPs enter agricultural ecosystems from various sources and have considerable impacts on the physiochemical properties soil, soil organisms and microbial communities, and plants. However, the intensity of these impacts can vary with the size, shape, types, and the concentrations of MPs in the soil. Besides, MPs can enter food chain through consummation of crops grown on MPs polluted soils. In this study, we conducted a bibliometric analysis of 1636 publications on the effects of MPs on agricultural ecosystems from 2012 to May 2024. The results revealed a substantial increase in publications over the years, and China, the USA, Germany, and India have emerged as leading countries in this field of research. Social network analysis identified emerging trends and research hotspots. The latest burst keywords were contaminants, biochar, polyethylene microplastics, biodegradable microplastics, antibiotic resistance genes, and quantification. Furthermore, we have summarized the effects of MPs on various components of agricultural ecosystems. By integrating findings from diverse disciplinary perspectives, this study provides a valuable insight into the current knowledge landscape, identifies research gaps, and proposes future research directions to effectively tackle the intricate challenges associated with MPs pollution in agricultural environments., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

The use of organochlorine pesticides (OCPs) in specific regions is still prevalent. Moreover, the impact of past utilization can be observed in the present environmental matrices. The present study monitored the extent of contamination of OCPs in the soil and vegetable samples of Gaya, Bihar, India. For this, 63 soil and vegetable samples were collected from the vegetable cultivated area of Gaya. The collected samples were extracted using a Soxhlet extraction unit and OCPs were analysed with a gas chromatography-mass spectrometry detector. The concentration data generated from the analysis were interpreted using statistical tools and software. Mean concentration (μg/g) of Σ 19 OCPs in soil from residential, agricultural, commercial, and polyhouse sites were 0.69, 2.21, 0.17, and 0.72, respectively. Similarly, in vegetable samples, mean concentration (μg/g) of Σ 19 OCPs were 0.91, 0.96, 1.00, and 0.67, respectively. Among the monitored vegetable types, the concentration of OCPs increased in the order: pods > tubers > leaves > fruits > roots > stem. The bioconcentration factor of 19 OCPs showed that 61.90% of vegetable samples were hyperaccumulators. The results of molecular diagnostic ratio and positive matrix factorization reported the recent inputs of heptachlor, aldrin, endrin and methoxychlor; the past application of dichlorodimethyltrichloroethane (DDT), endosulfan, and chlordane; and the degradation of DDT to its metabolites and aldrin to dieldrin, which make up an overall source profile of OCPs in study area. The study found that incremental lifetime cancer risks and hazard quotients ranged from 6.98 × 10 -8 to 1.31 × 10 -5 and 4.25 × 10 -2 to 4.63 × 10 -1 , respectively in vegetable samples which indicate low to high ILCR and low non-carcinogenic risk to populations exposed to OCPs. The study indicates the long lasting impact of past pesticide use by studying the contamination in soil and vegetables, and raises serious concerns about food safety. The contamination poses direct health risk to consumers related to potential carcinogenic and endocrine disrupting effects. Thus monitoring on the ground level could be a force to modify region specific policies, health, and remediation measures related to exposure to OCPs., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Identifying the source-specific health risks of potentially toxic elements (PTE) in urban park soils is essential for human health protection. However, previous studies have mostly focused on the deterministic source-specific health risks, ignoring the health risk assessment from a probabilistic perspective. To fill this gap, we developed a hybrid model that incorporated machine learning (ML) interpretability into positive matrix factorization (PMF) and probability health risk assessment (PHRA) based on the Monte Carlo simulation. The results indicated that concentrations of soil PTEs except for Mn and Sb were significantly higher than their corresponding background values. Random forest (RF) was regarded as the best ML model to identify key drivers for As, Cd, Cr, Cu, Ni, Pb, and Zn, with R 2 > 0.60, but was less effective for other soil PTEs (R 2 < 0.49). Specifically, the contributions of the four potential pollution sources were mixed sources, traffic emission, fuel combustion, and building materials, with contribution rate of 24.88%, 30.56%, 28.99%, and 15.56%, respectively. Fuel combustion contributed the most to non-carcinogenic for children (39.45%), male (43.84%), and female (43.76%), and the non-carcinogenic risk could be considered negligible for human. However, building materials was the major contributor to carcinogenic risk for children (36.1%), male (44.9%), and female (43.2%). The integration of the RF model with PMF and PHRA improved the accuracy of the results by identifying and quantifying the specific sources of each soil PTE using the relative importance analysis from the RF model. The results of this study assisted in providing efficient strategies for risk management and control of soil PTEs in Beijing parks., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Staple food is a crucial exposure route for the human intake of potentially toxic elements (PTEs), but it has been neglected in previous human health risk (HHR) studies. Lack of attention to this issue will lead to an underestimation of HHR caused by PTEs. This study establishes a comprehensive regional identification method for health risk assessment (HRA), namely, soil-maize health risk assessment (SMHRA) and applies it to Ziyang, Shaanxi, which is a typical agricultural county. SMHRA considered the exposure pathway of staple food and utilized Monte Carlo simulation to enhance the accuracy of HRA for PTEs. Results indicated the PTE spatial heterogeneity in a soil-maize system. Introducing staple food exposure pathway would increase HHR values and probabilities 1.57-2.80 and 1.53-5.63 times than that when food route was not considered. Overall, the HHR caused by a single PTE was low, which relatively safe. The introduction of food pathway contributed to accurate estimate the HHR of As and Ni, and the risk probabilities ranged from 0.04% to 12.46%. Few areas had high levels of Ni, which pose health risks: approximately 1.8% for children and higher than 0.5% for adults. Both As and Ni had the highest contribution to HHR among all PTEs, with 33.84%-41.56% TNCR caused by As, and 54.73%-56.90% TCR created by Ni, respectively. For human health risk routes, the staple food exhibited the highest contribution to HHR among all exposure routes, with TNCR of 36.15%-56.73% and the TCR of 44.96%-64.28%. Our research imply that dietary intake of PETs must be considered in the human health risk assessment in agricultural environment, which offers the foundation for subsequent environmental risk prevention and control., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Molybdenum (Mo) plays an important role in maintaining plant growth and human health. Assessment studies on the driving factors of Mo migration in soil-crop systems are crucial for ensuring optimal agricultural and human health. The Mo bioconcentration factor (BCF-Mo) is a useful tool for evaluating Mo bioavailability in soil-crop systems. However, the influence pathways and degrees of different environmental factors on BCF-Mo remain poorly understood. In this context, 109 rhizosphere and maize grain samples were collected from the Longitudinal Range-Gorge Region (LRGR) in Linshui County, Sichuan Province, China, and analyzed for the contents of Mo and other soil physiochemical parameters to explore the spatial patterns of BCF-Mo and its driving factors. Areas with the highest BCF-Mo values were mainly observed in the southern and northern parts of the Huaying and Tongluo mountains. The influence degrees of the selected environmental factors in this study followed the order of normalized difference vegetation index (NDVI) < elevation (EL) < mean annual humidity (MAH) < slope (SL) < mean annual temperature (MAT). The MAH and NDVI directly influenced the BCF-Mo values. The EL and MAT mainly indirectly affected the BCF-Mo values by influencing the rhizosphere organic matter (OM) contents, while the SL mainly affected the BCF-Mo values by influencing the rhizosphere pH. Therefore, OM and pH of the rhizosphere were the main influencing factors of BCF-Mo in the study area. In summary, the selected environmental factors mainly exhibited indirect influences on BCF-Mo by directly affecting the physicochemical properties of the rhizosphere., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Herbicides are widely recognized as the most cost-effective solution for weed control, but their extensive use in both urban and agricultural settings raise serious concerns about nontarget effects. We assessed the possible hazards associated with pre-emergence herbicides such as dimethenamid-P, metazachlor, and pyroxasulfone, which are frequently applied in both urban and agricultural soils. The dissipation rate constant values (k day -1 : 0.010-0.024) were positively linked to total organic carbon (TOC), silt, clay, soil pH, and Al and Fe oxides, but negatively correlated with sand content. In contrast, half-life values (DT 50 : 29-69 days) of the herbicides showed negative correlations with TOC, clay, silt, soil pH, and Fe and Al oxides, while sand content showed a positive impact. The selected herbicides showed minimal impact on soil dehydrogenase activity (DHA). Mostly, soils with higher organic matter (OM) content exhibited increased DHA levels, highlighting the role of OM in influencing this soil enzyme across different soils. Assessment of environmental indicators like groundwater ubiquity score (GUS:1.69-6.30) and leachability index (LIX: 0.23-0.97) suggested that the herbicides might reach groundwater, posing potential risks to nontarget biota and food safety. Human non-cancer risk evaluation, in terms of hazard quotient (HQ < 1) and hazard index (HI < 1), suggests minimal or no risks from exposure to soil containing herbicide residues at 50% of the initial concentrations. Our data thus help the stakeholders and regulatory agencies while applying these pre-emergence herbicides in soils and safeguarding human and environmental health., (© 2024. The Author(s).)

Excessive levels of Nickel in the soil can compromise the security of agricultural products, posing a threat to health of human beings; therefore, the repair and treatment of Nickel exceeding the standard levels in soil are particularly critical. Although it is crucial that the potential restoration of Nickel in ensuring the security of both soil and farm produce within karst regions., few studies have been conducted on the potential restoration of large-scale Nickel-contaminated soils. In this study, the soil in Wuming, Guangxi, a typical karst area, was comprehensively studied. 12,547 surface soil samples, 134 deep soil samples and 60 soil profiles were collected systematically. The results showed that the Nickel background value of the surface soil was 34.9 mg/kg, indicating strong background characteristics and high variability. Principal component analysis showed that soil Nickel was primarily derived from natural sources in the geological background and partly derived from agricultural sources. Analysis of variance showed that the Nickel content of the soil was affected by the parent rock, soil type, soil use type, and topography. In addition, the distribution of Nickel in the soil profile increased exponentially with depth. Therefore, the exponential model and multiple integrals were used to derive the formula for the Nickel potential restoration amount at different depth ranges, and the potential restoration amount of soil Nickel was calculated based on different parent material, soil, and land use types. The formula is reasonable and representative and can provide a theoretical basis for the remediation and treatment of Nickel-polluted soil in karst areas., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

An increase in erratic industrial activity has been a major contributing factor to the significant contamination in environmental matrices. This study aimed to ascertain the level of heavy metal contamination in soils in major industrial estates of Tamil Nadu as well as the threats to human health and the environment that concomitant with it. This led to the use of the total reflection X-ray fluorescence (TXRF) spectroscopy technique to analyse 31 soil samples. Thus, the mean heavy metal concentrations were found to be in the ascending order: As < Ni < Pb < V < Cu < Zn < Cl < Mn < Sr < Cr < Al < Fe. Pb, Cr, Cu, As, and Zn have been identified as predominant contaminants in the study area using the conventional pollution indices such as geo-accumulation index (I geo ), contamination factor (CF), and enrichment factor (EF). The magnetic susceptibility measurements indicates that the percentage of frequency dependence of magnetic susceptibility of the studied soil samples varied from 0.88 to 11.15 and that represents the presence of admixture of superparamagnetic (SP) particles in the soil samples. From the results of multivariate statistical analyses, the sources of identified heavy metals were classified as anthropogenic sources (Cr, Cu, Pb, As, and Zn), natural sources (V, Mn, Fe, Ni, and Sr ), and intermediate sources (Al and Cl)., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Microplastic contamination in soil ecosystems is a major environmental concern in the world. The current study aims to explore the extent of microplastic pollution in unregulated village dumpsites in India, focusing on the movement of these pollutants from soil to aquatic environments. Soil samples from eight distinct sites (A to H) in six villages were analyzed for various properties, including pH, bulk density, porosity, water retention capacity, hydraulic conductivity, and particle size distribution. The attenuated total reflection-Fourier-transform infrared spectroscopy (ATR-FTIR) method was used to identify prevalent plastic types. The research classifies microplastics by their shape and color, identifying a wide range of particles such as sheets, fibers, foams, fragments, and films. The study also examines the presence and concentration of microplastics in both soil and sediment samples. It was found that PE and PP microplastics are significantly present across different size fractions. Sample A contains a variety of items in the 1-5 mm size range, mainly PE, while the 0.3-1 mm fraction is largely PP. Samples B to H are mostly composed of PE microplastics in different forms. Sample F is unique with a mix of PE, EPS, and a higher amount of red and blue foam particles in the 0.3-1 mm fraction. Microplastics were quantified using stereomicroscopy, revealing concentrations between 80 and 840 numbers per kilogram in soil and 20 to 60 numbers per kilogram in sediments. The findings emphasize the widespread nature of microplastic pollution across ecosystems and the importance of developing effective strategies for monitoring and mitigating their impact on environmental health and human well-being., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Although extensive research has been conducted on the environmental impact of microplastics (MPs), their effects on microorganisms during the composting process and on the compost-soil system remain unclear. Our research investigates the microbial response to polylactic acid microplastics (PLAMPs) during aerobic composting and examines how compost enriched with PLAMPs affects plants. Our findings reveal that PLAMPs play a dual role in the composting process, influencing microorganisms differently depending on the composting phase. PLAMPs reduce the relative abundance of sensitive bacterial ASVs, specifically those belonging to Limnochordaceae and Enterobacteriaceae, during composting, while increasing the relative abundance of ASVs belonging to Steroidobacteriaceae and Bacillaceae. The impact of PLAMPs on microbial community assembly and niche width was found to be phase-dependent. In the stabilization phase (S5), the presence of PLAMPs caused a shift in the core microbial network from bacterial dominance to fungal dominance, accompanied by heightened microbial antagonism. Additionally, these intricate microbial interactions can be transferred to the soil ecosystem. Our study indicates that composting, as a method of managing PLAMPs, is also influenced by PLAMPs. This influence is transferred to the soil through the use of compost, resulting in severe oxidative stress in plants. Our research is pivotal for devising future strategies for PLAMPs management and predicting the subsequent changes in compost quality and environmental equilibrium., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Arsenic (As) mobilization in paddy fields poses significant health risks, necessitating a thorough understanding of the controlling factors and mechanisms to safeguard human health. We conducted a comprehensive investigation of the soil-porewater-rice system throughout the rice life cycle, focusing on monitoring arsenic distribution and porewater characteristics in typical paddy field plots. Soil pH ranged from 4.79 to 7.98, while porewater pH was weakly alkaline, varying from 7.2 to 7.47. Total arsenic content in paddy soils ranged from 6.8 to 17.2 mg/kg, with arsenic concentrations in porewater during rice growth ranging from 2.97 to 14.85 μg/L. Specifically, arsenite concentrations in porewater ranged from 0.48 to 7.91 μg/L, and arsenate concentrations ranged from 0.73 to 5.83 μg/L. Through principal component analysis (PCA) and analysis of redox factors, we identified that arsenic concentration in porewater is predominantly influenced by the interplay of reduction and desorption processes, contributing 43.5 % collectively. Specifically, the reductive dissolution of iron oxides associated with organic carbon accounted for 23.3 % of arsenic concentration dynamics in porewater. Additionally, arsenic release from the soil followed a sequence starting with nitrate reduction, followed by ferric ion reduction, and subsequently sulfate reduction. Our findings provide valuable insights into the mechanisms governing arsenic mobilization within the paddy soil-porewater-rice system. These insights could inform strategies for irrigation management aimed at mitigating arsenic toxicity and associated health risks., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Hydrazine is volatile and highly toxic, causing severe harm to water, soil, air, and organisms. Therefore, real-time detection and long-term monitoring of hydrazine are crucial for environmental protection and human health. Herein, an "OFF-ON" fluorescent probe 5-((10-ethyl-2-methoxy-10 H-phenothiazin-3-yl)methylene)-2,2-dimethyl-1,3-dioxane-4,6-dione (MPD) for hydrazine detection through a nucleophilic addition reaction was developed. MPD could exclusively identify hydrazine through colorimetric and fluorescent dual-channel responses within 30 s, which also demonstrated high sensitivity (detection limit, 12 nM) and a wide pH range (6 -12). The sensing mechanism of MPD was confirmed using theoretical calculations, where fluorescence was emitted following the recognition of hydrazine because of the disappearance of the photoinduced electron transfer (PET) process. Using a smartphone, MPD enabled the quantitative detection of hydrazine in real water samples and sandy soil. Notably, in the process of detecting hydrazine in actual water samples, the establishment of analytical methods and the completion of rapid quantitative detection only required a smartphone and built-in apps. Additionally, we showed that MPD could recognize hydrazine in various environmental samples, including plants, food, hydrazine vapors, and cells. We believe that the fluorescent probe MPD developed in this study and the established smartphone visualization platform will provide a convenient and effective tool for detecting hydrazine in environmental monitoring, food safety assessment, biological system safety, and other fields., Competing Interests: Declaration of Competing Interest We confirm that the manuscript has been read and approved by all named authors and the order of authors listed in the manuscript has been approved by all of us. We declare that all authors have no conflicts of interest to this work., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Microplastics (MPs) are increasingly entering agricultural soils, often from the breakdown of agricultural plastics (e.g., mulching films). This study investigates the effects of realistic MPs from different mulching films: two conventional polyethylene (PE-1 and PE-2) and two biodegradable (starch-blended polybutylene adipate co-terephthalate; PBAT-BD-1 and PBAT-BD-2). MPs were mixed into Lufa 2.2 soil at a concentration range from 0.005 % to 5 % (w/w dry soil), wide enough to reflect both realistic environmental levels and "worst-case scenarios". Effects on Enchytraeus crypticus reproduction over two generations and six important soil properties were studied. PBAT MPs notably reduced enchytraeid reproduction in the F0 generation, with a maximum decrease of 35.5 ± 9.6 % at 0.5 % concentration. F1 generation was unaffected by PBAT contamination. PE MPs had a more substantial reproductive impact, with up to a 55.3 ± 9.7 % decrease at 5 % PE-1 concentration compared to the control, showing a dose-related effect except for 1 %. Both MP types also significantly affected soil water holding capacity, pH, and total carbon. Other soil properties remained unaffected. Our results highlight the potential negative impacts of MPs originating from real agricultural plastics on soil health and raise concerns about the role of agricultural plastics in sustainable agriculture and food safety., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)

The widespread application of pesticides in China has led to the accumulation of residues in soil. However, few regional studies have fully elucidated the characteristics of pesticide residues in soil (PRS) and the associated risks to the ecosystem and human health on a national level. Therefore, this study aims to compile a dataset on PRS in China from 2006 to 2020 and analyze the interactions and impacts between PRS and the environment. The average concentration of PRS in China was 243.96 μg/kg which was lower than the levels reported in Euro-Americans and other nations. This study revealed PRS in China predominantly originates from organochlorine pesticide residues, with DDTs and HCHs being significant contributors. Despite the high intensity of pesticide application in the Southeast China, PRS concentrations were comparable to those in the Northeast, due to environmental factors that favor pesticide degradation in the Southeast. Both legacy and in-use pesticides were transported by surface runoff or air current, resulting in their accumulation in soil of the lower Yangtze River basin or the piedmont soil of Qinling Mountains, respectively. The average soil environment carrying capacity of PRS in China was -69.5 kg. The ecological risk contributed by PRS in China was mainly at a negligible level. Carcinogenic risks of PRS to adults (4.6 ×10 -4 ) and children (6 ×10 -4 ) exceeded the tolerable thresholds (10 -5 ) by a small margin., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Tire wear particles (TWPs) pollution is widely present in soil, especially in areas severely affected by traffic. Herein, regular variation of fungal biomass with TWPs was found in soils with different distances from the highway. In addition, the concentrations of benzothiazole compounds (BTHs), an important class of rubber vulcanization accelerators, were found to be positively correlated to the TWPs abundance. Sixty days' soil microcosm experiments were conducted to further confirm the adverse effect of TWPs and BTHs on soil fungi. TWPs spiking at 1000 mg/kg, a detectable level in the roadside, resulted in significant reduction of biomass and significant changes of soil fungal community structure, with Eurotium and Polyporales being the sensitive species. BTH+ 2-hydroxybenzothiazole (OHBT) (the dominant BTHs in soil) spiking at 200 ng/kg, the dose equivalent to 1000 mg/kg TWPs pollution, also caused a similar magnitude of soil fungal biomass reduction. Adonis demonstrated no significant difference of fungal community structure between TWPs and BTH+OHBT spiked soil, suggesting the adverse effect of TWPs on soil fungi may be explained by the act of BTHs. Pure culture using the representative soil fungi Eurotium and Polyporales also confirmed that BTHs were the main contributors to the adverse effect of TWPs on soil fungi., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Antibiotics are among the emerging contaminants of greatest concern to the scientific community. However, the occurrence and behaviour of their metabolites in soils have been scarcely studied. To address this research gap, this study investigates the occurrence, sorption, dissipation kinetics, and environmental risk of highly important antibiotics (sulfamethazine, sulfadiazine, sulfamethoxazole, trimethoprim) and their main metabolites in Mediterranean agricultural soils. Batch experiments were conducted under natural conditions for 120 days. Five different dissipation kinetics models were applied to elucidate antibiotics degradation. The sorption isotherms were evaluated by three different models. Most of the antibiotics and metabolites tested showed a good fit with the Linear Isotherm model (R 2 >0.96) and biphasic dissipation kinetic models (R 2 >0.90). The dissipation and the endpoints values (DT 50 and DT 90 ) depended on the soil type properties. A Lixisol soil demonstrated reduced degradation of the investigated compounds. Trimethoprim showed the highest persistence, followed by sulfamethazine, sulfamethoxazole, and sulfadiazine. Parent compounds exhibited lower degradation rates than their metabolites. Remaining antibiotic concentrations were found to be below the predicted no-effect concentration in soil, suggesting that they may not pose a risk to terrestrial biota. This study provides valuable insights into the behaviour of these antibiotics and their metabolites in soil., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)

Polychlorinated biphenyls (PCBs) constitute a typical example of persistent organic pollutants (POPs) that have been detected globally in most environmental media. Soil serves as a critical reservoir for PCBs. This research is aimed at evaluating the potential exposure and associated health risks posed by soil-laden PCBs to humans during outdoor activities on public playgrounds and parks within the southern zone of Ghana where limited studies have been undertaken. Surface soils collected from 56 sites were processed and analyzed for seven indicator PCBs in soil particle sizes less than 63 µm. A multi-residual analytical approach for the simultaneous analysis of PCBs and polycyclic aromatic hydrocarbons (PAHs) via gas chromatography tandem mass spectrometry was utilized. The results indicated that the concentration of PCBs ranged from 0.26 to 24.00 µg/kg with an average total concentration of 1.86 ± 3.23 µg/kg which is below the environment guideline threshold of 1.3 mg/kg stipulated by the Canadian Council of Ministers for residential playgrounds/parkland soils. Multivariate analysis showed that the sources of the PCBs could be attributed predominantly to historical release, atmospheric transfer, and deposition. The excess lifetime cancer risks posed to children and adults are less than 10 -6 thereby implying the existence of low carcinogenic health risk to the human populace within the southern zone of Ghana. Thus, the conduct of outdoor activities at the public playgrounds/parks within these highly populated areas poses no significant risk to human health., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Recent years have witnessed a dramatic increase in global plastic production, leading to heightened concerns over microplastics (MPs) contamination as a significant environmental challenge. MP particles are ubiquitously distributed across both continental and marine ecosystems. Given the paucity of research on MPs in Thailand, particularly regarding MPs contamination in terrestrial environments, this study focused on investigating the distribution and characteristics of MPs in a landfill area. We collected 15 soil samples, 2 leachate samples, and 7 groundwater samples from both inside and outside a municipal landfill situated in the urbanized coastal region of Rayong Province. Our findings revealed variability in MPs concentration across different sample types. In soil, the MP count ranged from 240 to 26,100 pieces per kg of dry soil, 58.71 % of all sample sizes are lower than 0.5 mm. Similarly, the size found in the leachate sample, and the average MP in the leachate samples was 139 pieces per liter of MPs. The groundwater samples showed a fluctuation in MPs count from 18 to 94 pieces per liter, and the size of MPs ranged mostly from 0.5 to 1 mm. The predominant forms of MPs identified were sheets, followed by fragments, fibers, and granules. According to μ-FTIR analysis, the majority of the MPs were composed of polyethylene and polypropylene, commonly used in plastic packaging and ropes. The observed high concentrations and extensive distribution of MP contamination underscore the urgency for further studies and effective management strategies to mitigate the adverse impacts of this pollution on various organisms and ecosystems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Sulfonamides, the most frequent antibacterial agent, are widely used due to their low cost and excellent antibacterial effect. With the emergence of the environment, the potential hazard to the ecological environment has attracted the great attention of humans. Based on matrix solid-phase dispersion coupled with high-performance liquid chromatography-tandem mass spectrometry, an accurate, fast, and sensitive analytical method was developed for the determination of sulfonamides (SAs) in soil. Several influencing factors including the type of dispersants, the ratio of sample-to-sorbent, eluents, and solvent volume were investigated, and the matrix effects were evaluated. Under optimized conditions, the calibration curves exhibited excellent linearity with correlation coefficients (r) exceeding 0.996. The limit of detection (based on signal-to-noise ratio [S/N] = 3) and limit of quantification (based on S/N = 10) were 0.024-0.058 and 0.079-0.195 µg/kg, respectively. The recoveries ranging from 70.12% to 123.63% were obtained with a relative standard deviation of less than 15% at three levels (20, 40, and 200 µg/kg). The developed method was successfully applied to analyze 13 SAs at trace levels in a real soil sample. This proposed method would be an alternative and suitable for routine application in the future owing to its rapidity, sensitivity, and affordability., (© 2024 Wiley‐VCH GmbH.)

The current study assessed the contamination levels and associated ecological and health risks due to hazardous trace elements in soils from Awanda and Mvengue, located in the vicinity of the Lolodorf uranium deposit in Southern Cameroon. Qualitative and quantitative analyses of the soil samples were performed using energy-dispersive X-ray spectrometry. The results indicated that the mean concentrations of metallic and trace elements in soil samples increased in the following order: U < As < Th < Pb < Cu < Ni < Zn < Cr < Mn < Fe < Al. The average concentrations of U, As, Th, Pb, Cu, Ni, Zn, Cr, Mn, Fe, and Al ranged between 0.9-3, 2.9-3.8, 9.2-15, 13.1-20.3, 11.5-42.5, 31.1-60.7, 42.9-91.6, 94.50-170.9, 100.45-500.57, 4874.8-88340 and 226147.5-324240.0 mg/kg, respectively. The contamination levels of trace elements were assessed and the human health risk of chemical elements was determined. The investigated elements' average contamination factors (CF) results showed the highest mean CF recorded for Al followed by Cr, Th, Pb, Zn, Cu, Ni, Fe, U, Mn, and As. Furthermore, the findings showed that 90% of soil samples can be classified as considerably contaminated with Al, 100%, and 60% as moderately contaminated with Cr and Th, respectively. The Geo-accumulation indices of Mn, Cr, Th, U, Ni, Zn, Cu, As, and Pb were lower than 1, suggesting low contamination levels for these elements. The ecological factors and risk indices indicated a low ecological risk in the investigated area. In terms of human health risk, ingestion was identified as the primary pathway for both carcinogenic and non-carcinogenic risks, with children found to be more exposed to both risks than adults. Al, Cr, and Fe were found to be the main contributors to non-carcinogenic health risks, while Cr and Ni were the main contributors to carcinogenic health risks., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Effective solid waste management is a critical environmental challenge, particularly in rapidly growing Global South countries like Nigeria. This issue is exacerbated by burgeoning populations, lax waste regulations, and the widespread practice of open dumping. The deterioration of soil quality and alteration of water quality are major consequences of open waste dumping, posing significant environmental and public health risks. This study aims to assess the environmental risk and pollution status of soil and water resources near major dumpsites in Lagos. It aims to offer insights that can inform targeted interventions and policy measures not only in Lagos but also in comparable urban settings worldwide. Results indicated that important soil parameters, including TN (11.89-13.83 mg/kg), pH (6.45-7.35), sulfate (36.71-39.49 mg/kg), phosphate (9.31-14.39 mg/kg), and electrical conductivity (342-566 µS/cm), were significantly affected by the dumpsites. Additionally, concentrations of heavy metals varied, with some exceeding permissible limits set by international standards, highlighting the environmental challenges posed by improper waste disposal in urban settings like Lagos. The analyzed parameters for water were mostly within acceptable limits, indicating a lesser impact of the waste dump on water resources. Water samples from boreholes and hand-dug wells near three dumpsites showed that pH, TDS, and heavy metal concentrations were mostly within WHO limits, with borehole water deemed safe for drinking and hand-dug wells suitable for cleaning. To alleviate the environmental impacts of open dumpsites, it is recommended to implement effective waste segregation, recycling programs, controlled landfilling, and investment in waste treatment technologies, along with regular water quality monitoring to prevent further pollution and protect public health. While these measures offer opportunities, they also face significant challenges due to financial and land constraints. Therefore, strong public awareness, infrastructure investment, and government commitment are essential, along with coordinated efforts among the government, private sector, and communities., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Landfills pose a global issue for soil functionality and health, especially in underdeveloped nations where limited resources impede the adoption of comprehensive waste management policies, such as waste processing and sorting techniques. Leachate emissions from waste landfills are a cause for concern, primarily due to their toxic effect if left uncontrolled in the environment, and the potential for waste storage sites to produce leachate for hundreds of years after closure. Few efforts have been made to improve waste collection and disposal facilities in the world, especially in developing countries. This research aims to investigate the influence of waste leachate on soil health indicators in natural woodland and rangeland ecological systems in a semi-arid mountainous region in the north of Iran. Based on results, forest unpolluted sites (2008) exhibited the highest values of nutrient elements in litter and root components. Landfills led to a rise in soil bulk density and a simultaneous decrease in soil organic matter (SOM), porosity, aggregate stability, particulate organic carbon and nitrogen (POC and PON), as well as available nutrients, ammonium (NH 4 + ) and nitrate (NO 3 - ) levels. Additionally, microbial parameters (respiration and biomass) and enzymes (urease, acid phosphatase, arylsulfatase and invertase) experienced a decrease in areas affected by the landfill sites over time of 2008-2023. Forest and rangeland landfill sites (2023) sites had lower density and biomass of the three earthworm groups. Acari, Collembola, nematodes, protozoans, fungi and bacteria were also reduced in landfill sites (nearly 1-2 times more in uncontaminated forest and rangeland sites). Lumbricus terrestris earthworms exhibited a clear presence in all the studied sites, and this demonstrates the ability of this earthworm species to be active in severe pollution conditions. The spatial pattern of soil cadmium and lead changes indicates the high variance of these characteristics under the influence of landfills in the study sites. Finally, the soil health indicators (according to soil physical, chemical, and biological parameters) decreased from forest unpolluted sites in 2008 to rangeland landfill sites in 2023, which is linked to the release of landfill leachate. These results are noteworthy for all countries and governments that rely on natural ecosystems for waste management without engineering operations or technical intervention. Furthermore, both governments and stakeholders must implement effective waste management systems. The research offers valuable information that can assist decision-makers engaged in sustainable solid waste management in Iran and comparable areas. Besides that, it is highly recommended to prioritize recycling and phytoremediation processes. Ultimately, worldwide efforts to achieve environmental sustainability need a significant focus on the effective management of hazardous waste. Consequently, investigations covering this topic should be continued, as they allow the evaluation of the environmental effects of the gradual accumulation of pollution in soils surrounding uncontrolled municipal solid waste landfills., Competing Interests: Declaration of competing interest The authors declare that they have no conflict of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The interactive effects of Se (Na 2 SeO 3 ) and ammonium fertilizers ((NH 4 ) 2 SO 4 and NH 4 Cl) on the growth and quality of maize (Zea mays L.) in mercury (Hg)-contaminated soil were studied under different water conditions. This study determined how two nutrient sources (Se and NH 4 + -N) interacted to improve the yield, quality, and safety of maize to ensure food security and quality assurance under the stress of heavy metal Hg. The experiment was conducted under two irrigation conditions: W1 (complete irrigation condition, 60-70% of water-holding capacity) and W2 (restricted irrigation condition, 40-50% of water-holding capacity). The combined treatment of Se and ammonium fertilizers significantly improved the growth of maize and the quality of grain in Hg-polluted soil. When Na 2 SeO 3 and (NH 4 ) 2 SO 4 were combined, the growth and quality of maize increased the highest among all treatments. The interaction between Na 2 SeO 3 and ammonium fertilizers significantly affected the available Hg/methylmercury (MeHg) content in soil and the Hg/MeHg concentration in maize. NH 4 Cl significantly increased the content of available Hg/MeHg in soil and increased the accumulation of Hg/MeHg in maize tissues due to Cl - . However, the treatments containing Na 2 SeO 3 or (NH 4 ) 2 SO 4 significantly reduced the content of available Hg/MeHg in soil, reduced the accumulation of Hg/MeHg in maize tissues, and significantly reduced the possible health risks to human beings. The treatments containing Na 2 SeO 3 or (NH 4 ) 2 SO 4 promoted maize growth by increasing the Se content in maize tissues and reducing the Hg/MeHg content, relieving the stress induced by Hg, and increasing the nutrient content. The combined treatment of Na 2 SeO 3 and (NH 4 ) 2 SO 4 had the best effect in this experiment. This study also showed that this strategy is helpful in reducing the opportunities for consumers to accumulate Hg/MeHg by eating maize and its derivatives, thus ensuring food safety. Se and ammonium fertilizer can be used together to increase maize yield and develop agricultural production in Hg-polluted areas, which may have a significant impact on global food production. In addition, this simple method can help farmers manage soil affected by heavy metal pollution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The soil environment is a primary destination for contaminants such as microplastics (MPs) and heavy metals (HMs), which are frequently detected simultaneously. The long-term coexistence of MPs and HMs in the soil necessitates unavoidable interactions, affecting their environmental chemical behavior and bioavailability. These co-contaminants pose potential threats to soil organism growth and reproduction, crop productivity, food security, and may jeopardize human health via the food chain. This paper summarizes the sources and trends of MPs in the soil environment, along with the mechanisms and current research status of MP adsorption or desorption of HMs. Additionally, this paper reviews factors affecting HM adsorption on MPs, including MP properties, HM chemical properties, and other environmental factors. Lastly, the effects of MPs and HMs on soil ecology and human health are summarized. The interaction mechanisms and potential biological effects of their co-contamination require further exploration. Future research should delve deeper into the ecotoxic effects of MP-HM co-contamination at cellular and molecular levels, to provide a comprehensive reference for understanding the environmental behavior of their co-contamination in soil., Competing Interests: Declaration of Competing Interest The authors declared that they have no conflicts of interest to this work. We declare that we do not have any commercial or associative interest that represents a conflict of interest in connection with the work submitted., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Sewage sludge, a byproduct of wastewater treatment, poses serious environmental and health risks due to its content of organic contaminants, heavy metals, and pathogenic microorganisms. With the growing global production of municipal wastewater, finding effective methods for managing and disposing of sewage sludge has become increasingly urgent. Traditional methods such as land disposal, dumping, and incineration have limitations and environmental drawbacks. However, recent advancements have shown promise in the valorization of sewage sludge, particularly through pyrolysis, which converts it into biochar for use in soil amendment and pollutant mitigation. This study aims to characterize and fractionate phosphate-amended sewage sludge biochar produced at 300 °C, 400 °C, and 500 °C, and to evaluate its potential use in soil-plant systems. It examines nutrient bioavailability in soil after the addition of this biochar and its effects on plant growth. The pyrolysis process resulted in biochar with high alkalinity (7.2-11.1), ash content ranging from 56.9% to 87.3%, and significant phosphorus retention, with phosphorus concentrations increasing with pyrolysis temperature (5.35%-9.38%). Phosphorus fractionation showed a shift toward more stable fractions particularly at 500 °C. Soil incubation experiments indicated increased phosphorus availability with HCl-extractable P showing a high extraction efficiency of up to 94.95%. In plant growth experiments, the amended biochar significantly enhanced growth, with corn showing an increase of up to 28.8% and wheat showing an increase of up to 86% compared to the control in the first four weeks after emergence. These findings indicate that phosphate-amended sewage sludge biochar enhances nutrient availability and supports plant growth, providing a sustainable solution for sewage sludge management, contributing to soil improvement and carbon sequestration, thereby addressing global environmental challenges., Competing Interests: Declaration of competing interest No known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Trace element dynamics in the soil-plant system depends on multiple parameters, including chelating organic compounds from natural or synthetic organic matters. In this study, we evaluated the influence of one of the most common pesticides-glyphosate-on the mobility of trace elements considering contrasted soils (uncontaminated, anthropogenically contaminated, and naturally-enriched) in a greenhouse experiment. Four modalities have been tested: one control without any application, two with different glyphosate doses (1 and 3 times the authorised field dose), and one with compost addition to evaluate its potential ability to mitigate the impact of glyphosate on trace element mobility. Both, trace element and glyphosate concentrations were measured in the soil solutions and trace element contents were determined in plants at the end of the experiment. The results showed that, although glyphosate concentrations rapidly decreased in soil solutions, glyphosate application still influenced the transfer of trace elements to both soil solution (up to 12-times higher) and plant (up to 5.2-times higher). This influence was highly dependent on both the specific elements and the type of soils considered. For instance, in uncontaminated soils, glyphosate especially increased the mobilization of Mn, Co, Zn, Mo, and Pb to soil solution. This effect diminished of 2.5 times on average with increasing soil contamination. A similar trend was observed for the transfer of trace elements from soil to plant (i.e., on average 2.2-times lower in the most contaminated compared to the uncontaminated soil). However, in the naturally-enriched soil, opposing trends were noticed between soil solution and plant. The impact of compost addition on the transfer of trace elements to plants remains unclear: compost enhanced the transfer of trace elements to soil solution in uncontaminated and naturally-enriched soils likely due to trace element input through the compost, but decreased the transfer in anthropogenically-contaminated soils likely due to adsorption processes. Therefore, glyphosate could potentially increase the exposure of trace elements through food consumption and their transfer to the ecosystem, particularly in uncontaminated and weakly contaminated soils. In highly contaminated soils, compost could mitigate the glyphosate-induced enhancement of trace element mobility to soil solution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Global concern continues to mount regarding the accumulation of microplastics (MPs) in soil. However, little is known about how various types of MPs influence the properties of soil ecosystems. Here, we evaluated the effects of six different types of MPs, including low-density polyethylene (LDPE), polyamide (PA), polystyrene (PS), polyhydroxy-alkanoates (PHA), polybutadiene styrene (PBS), and polylactide (PLA), on soil physicochemical properties, enzyme activities, and microbial communities. At the end of a 230-day soil incubation, we observed significant changes in soil moisture content, soil organic carbon, pH, NH 4 + -N, NO 3 - -N, and available phosphorus. The addition of MPs had a significant influence on the activities of soil β-glucosidase, acid phosphatase, urease, and fluorescein diacetate hydrolase, with effects varying with MP type. Results of 16S rRNA gene high throughput sequencing showed that MP exposure had little effect on soil microbial alpha diversity, but that PHA contamination significantly reduced ACE, Chao1, and Shannon index values. MP contamination also altered soil microbial community composition. In particular, the relative abundance of Firmicutes increased significantly while the relative abundance of Actinobacteriota, Proteobacteria (especially the nitrogen-fixing rhizobia), and Acidobacteriota decreased following exposure to PHA. Redundancy analysis showed that acid phosphatase and pH were the two main environmental factors affecting bacterial community structure at the phylum and order levels. Furthermore, Tax4Fun2 analysis found that MP treatment disrupted fundamental bacterial metabolic pathways. Our findings indicate that different types of MPs can affect soil fertility, bacterial community structure, and function in various ways, and highlight that biodegradable MPs may alter soil bacterial communities more than conventional MPs., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Temperature rising and seawater intrusion are expected to influence the hydrologic regime and redox conditions in coastal soil, and the fate and mechanisms of biogeochemical cycling of Arsenic (As) in the specific environment are poorly understood. This work was carried out in an anaerobic operating chamber by adding sulfate to simulate seawater intrusion under various temperature. Results demonstrated the microbial community diversity was influenced by temperature and the highest Shannon and lowest Simpson index were found at 28 °C. Firmicutes was the dominant bacteria, accounting for 81.16%-93.99%. Desulfosporosinus, with the proportion increasing with temperature, showed a significantly positive correlation with S 2- for sulfate addition treatments. Actually, transformation of As was meditated by the concentration and valence of sulfur and iron in soil. The dissimilatory reduction of arsenic-bearing Fe oxides occurring in the initial stage, is suspected to be the primary driver of As release. Then, concentration of As declined in aqueous phase due to the reduction of sulfate, and the proportion of residual speciation of As in solid phase increased with temperature, ranging from 6.78% to 27.70%. The results displayed the reducing condition due to seawater intrusion and temperature change could regulate the release and sequestration of As in the coastal soil., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Toxic metal contamination in soils poses significant hazards to the environment and human health; thus, quantitative assessment of the sources and risks of metal contaminants are urgently needed. A hybrid model that integrates the positive matrix factorization (PMF) and random forest (RF) methods was proposed to quantify the sources of toxic metals in soils by combining diverse environmental variables (source proxies) in this study. In addition, a health risk assessment and Monte Carlo simulations were integrated to estimate the source-oriented stochastic health risk. The results suggested that, except for Ni, which exhibited moderate contamination, other toxic metals (As, Cd, Cr, Hg and Pb) presented slight contamination. Four sources (agricultural activities loaded heavily by As, atmospheric deposition loaded heavily by Hg and Pb, natural sources and mining activities loaded heavily by Cr and Ni, and industrial activities loaded heavily by Cd) were defined and explained 23.44 %, 26.65 %, 30.13 % and 19.78 % of the total variance in toxic metals, respectively. The principal route of exposure (i.e., ingestion), the population at highest risk (i.e., children), and the most hazard-inducing metals (i.e., As and Cr) were determined. Agricultural activities and the combination of natural sources and mining activities demonstrated certain degrees of noncarcinogenic risk to children, with exceedance ratios of 2.20 % and 2.56 %, respectively. Additionally, the combination of natural sources and mining activities demonstrated probabilities for significant carcinogenic risk to adults and children of 0.59 % and 3.76 %, respectively. To reduce the health risks of toxic metals in soils and to protect food and ecological safety, strict regulations should be established to control the discharge of waste from mining and agricultural activities., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Given the research situation of toxic metals (TMs) pollution in farmland soil, it is very critical to study the clay influence on TMs environmental behavior to meet the aim of lowering TMs pollution. This research explores the association among clay minerals and TMs and the health risks in TMs combined polluted farmland of northern China. In this study, agricultural soil, wheat grain, and atmospheric sediments from nonferrous metal smelting (NMS) areas were collected and investigated to determine the effect of clay minerals on TMs. The results show that the content ranges of Cd (0.199 mg/kg ∼1.98 × 10 2  mg/kg), Pb (0.228 × 10 2  mg/kg ∼ 4.87 × 10 3  mg/kg), Cu (0.187 × 10 2  mg/kg ∼ 4.57 × 10 3  mg/kg), and Zn (0.559 × 10 2  mg/kg ∼ 3.04 × 10 3  mg/kg) in the agricultural soil. In particular, Cd has reached heavy pollution by the high pollution index (6.74). The findings indicate that Cd and Pb in wheat grain were influenced by their exchangeable fractions in soil, according to a significant relationship between Cd and Pb in soil and wheat grain. XRD-SEM suggests that TMs come from atmospheric sediments associated with NMS emissions by microsphere signatures with surface burn marks. Meanwhile, Geographical detector indicated that clay was the primary contributor to spatial distribution of Cd and Pb. In addition, XRD results showed that I/S (a mixed layer of illite and smectite), illite, chlorite, and kaolinite co-existed. Whereas the clay minerals with this ratio did not demonstrate better adsorption capacities for Cd and Pb due to the Cd percentage of the residual fraction being less than 9%. The result of negative correlation between exchangeable Cd and clay minerals implies that illite, chlorite, and kaolinite may preferentially adsorb Cd and Pb. It is similar to the relationship between Cd and Pb in wheat grain and illite, chlorite, and kaolinite. In addition, the health assessment result show that the negative correlation between clay minerals and the noncarcinogenic hazard quotient (HQ) and indicate that clay minerals could reduce the noncarcinogenic risk of Pb and Cd for children. Our findings provide a potential mechanism and application of clay minerals for the remediation of soil contaminated with TMs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Tailings pond poses a serious threat to the surrounding environment. This study aimed to explore the current status and mechanism of Hippophae rhamnoides (H. rhamnoides) restoration in the Zhoutaizi magnetite tailings pond in Chengde city by analyzing the physicochemical properties, heavy metal content, and microbial community characteristics of the rhizosphere soil of H. rhamnoides. Rhizosphere soil samples were collected from the planting areas (10 m, 50 m, and 80 m) at distances of 10, 50, and 80 m from the mountain, the dead plants areas (D) at a distance of 80 m from the mountain, and the unplanted areas (U) in the center of the Zhoutaizi magnetite tailings pond. The available manganese (Mn) content in groups 10 m, 50 m, 80 m, and D was higher than in group U (p< 0.05). Mn contributed to the relative abundances of Articulospora, Mortierella, Minimedusa, and Knufia, but negatively correlated with that of Fusarium and Cistella (p< 0.05). These results indicated that H. rhamnoides can improve soil quality and microbial community structure by increasing Mn content. The Chao and Ace indices in groups 10 m, 50 m, 80 m and D were higher than in group U (p< 0.05), implying that H. rhamnoides can increase the total number of soil microbial species. The electrical conductivity (EC) of groups D and U was higher than that of the other groups (p< 0.05). EC was positively correlated with Cistella, while negatively correlated with Minimedusa and Knufia (p< 0.05). Therefore, we speculated that the increase of harmful bacteria and the decrease of beneficial bacteria caused by high EC were one of the reasons for H. rhamnoides death. In short, H. rhamnoides can be used to some extent for restoring magnetite tailings pond, but high EC is the main obstacle to its restoration. This study provides a theoretical basis for the construction of green mines., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Soil degradation poses a significant challenge to Egypt's agriculture, making resource optimization essential. Nanobiochar presents a promising solution for pollutant removal; however, its low yields may hinder commercialization. This study investigates the production of biochar from sugarcane bagasse and olive mill waste, focusing on its composition, morphology, and effectiveness in soil immobilization. Advanced techniques like SEM, TEM, and FTIR were used to characterize the nanobiochar, highlighting its potential as a sustainable solution to soil contamination. The study revealed that ZnCl2 treatment significantly lowers pH, while KOH modification raises it. Surface morphology analysis showed that SCB biochar exhibited a highly porous structure, while OMW biochar had less porous edges and irregular oval-shaped pores. The effects of biochar activation on the availability of heavy metals like Ni, Pb, and Mo (in mg.Kg -1 ) were also examined. Ni concentrations decreased from 1.27 mg.Kg -1 in untreated biochar (NA) to 0.78 mg.Kg -1 in KOH-treated biochar (KA) and 0.67 mg.Kg -1 in ZnCl2-treated biochar (ZnA). Pb levels dropped from 7.7 mg.Kg -1 in NA to 5.2 mg.Kg -1 in KA and slightly to 4.74 mg.Kg -1 in ZnA. Mo showed a similar trend, with the highest concentration in NA at 1.21 mg.Kg -1 , followed by 0.88 mg.Kg -1 in KA and 0.75 mg.Kg -1 in ZnA. Overall, OMW nanobiochar demonstrated a greener, more sustainable solution to soil contamination compared to SCB nanobiochar., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Metal contamination in soil poses environmental and health risks requiring effective remediation strategies. This study introduces an innovative approach of synergistically employing biochar and bacterial inoculum of Serratia marcescens to address toxic metal (TM) contamination. Physicochemical, enzymatic, and microbial analyses were conducted, employing integrated biomarker response (IBR) and machine-learning approaches for toxicity estimation. The combined application significantly reduced the Cd, Cr, and Pb concentrations by 71.6, 31.2, and 57.1%, respectively, while the Cu concentration increased by 85% in the individual Serratia marcescens treatment. Biochar enhanced microbial biomass by 33-44% after 25 days. Noteworthy physicochemical improvements included a 44.7% increase in organic content and a decrease in pH and electrical conductivity. The K⁺ and Ca 2 ⁺ concentrations increased by 196.9 and 21.6%, respectively, while the Mg 2 ⁺ content decreased by 86.4%. Network analysis revealed intricate relationships, displaying direct and indirect negative correlations between metals and soil physicochemical parameters. The IBR index values indicated effective mitigation of TM toxicity in Serratia marcescens and biochar with individual and combined treatments. Binary classification demonstrated high sensitivity (80.1%) and specificity (80.5%) in identifying TM-contaminated soil. These findings indicate significant biochar- and Serratia marcescens-induced impacts on toxic metal availability, physicochemical properties, and enzymatic activities in metal-contaminated soil, suggesting that blending soil with biochar and microorganisms is an effective remediation strategy., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:Mazhar Iqbal, Tayyab Ashfaq Butt, Ahmed Abdullah Alawi Al-Naghi, Enamur Rahim Latifee, Omar Ali Saad Algassem reports financial support was provided by University of Ha'il. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)