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Correlation analysis of APXS results on the eastern slope rocks indicate that the Matijevic Hill rocks are overall compositionally distinct from the Shoemaker Formation rocks [6]. Compared to the Shoemaker impactites, Matijevic Hill rocks are higher in Al, Si, and Ni, and lower in Ti, Fe, and Zn. No significant variation is evident in the APXS analyses that indicate the presence of a smectite or other phyllosilicate, as opposed to basaltic rocks. However, APXS data cannot in themselves rule out phyllosilicates. If indeed this material contains smectite, as seen from orbit, it implies that the rock has been isochemically altered to create the phyllosilicate content. The Cl content of the Cape York rocks is relatively high, and whereas the S/Cl ratio in the Burns Formation is 4x higher than in soil, in the Cape York rocks it is lower than in soil. These trends indicate that the alteration processes and types of aqueous salt loads were different between Cape York and Meridiani. In addition, significant deviations from the Martian Mn/Fe ratio are observed in Whitewater Lake coatings and the altered Grasford/Deadwood rocks (Fig. 3). These variations indicate that the redox/pH conditions during alteration of the Shoemaker Formation rocks and the Matijevic Hill rocks were similar, but that the Deadwood/Grasberg unit may have undergone alteration under different conditions, possibly at a later time. The Matijevic Hill outcrops appear to share a common genetic origin. It is not yet clear whether both the Shoemaker impactites and Matijevic Hill rocks are related to the formation of Endeavour Crater, or whether the Matijevic Hill suite represents a prior episode of Martian impact or volcanism. Opportunity continues to investigate both hypotheses.

The Alpha Particle X-ray spectrometer (APXS) on the Curiosity rover in Gale Crater [1] is the 4th such instrument to have landed on Mars [2]. Along the rover's traverse down-section toward Glenelg (through sol 102), the APXS has examined four rocks and one soil [3]. Gale rocks are geochemically diverse and expand the range of Martian rock compositions to include high volatile and alkali contents (up to 3.0 wt% K2O) with high Fe and Mn (up to 29.2% FeO*).

The eolian bedform within Gale Crater referred to as "Rocknest" was investigated by the science instruments of the Curiosity Mars rover. Physical, chemical and mineralogical results are consistent with data collected from soils at other landing sites, suggesting a globally-similar composition. Results from the Curiosity payload from Rocknest should be considered relevant beyond a single, localized region with Gale Crater, providing key insights into planetary scale processes.

The Mars Exploration Rover (MER) Opportunity has been studying Meridiani Planum for five years. On sol 1634 of its mission, Opportunity left Victoria crater after investigating it for approximately 682 sols [1] and is now on a journey towards Endeavour, a 24 km diameter crater about 12 km southeast of Victoria. A priority along the way is the investigation of cobbles, which in the jargon of the MER science team denotes any loose rock fragment larger than a couple of centimeters. Cobbles investigated thus far are of diverse origin [2] and provide the only means to investigate material other than the ubiquitous sulfate-rich outcrop, basaltic sand or hematiterich spherules dubbed blueberries. Some of these cobbles are meteorites [3]. Meteorites on Mars are not just a curiosity that make Mars a more Earth-like planet. Metallic iron in meteorites, for example, may be used as a more sensitive tracer for volatile surface interactions compared to igneous minerals [4]. Between sols 1713 and 1749, including the period of Mars solar conjunction, Opportunity investigated a cobble informally named Santorini. Its chemical and mineralogical composition is very similar to Barberton and Santa Catarina, two cobbles that were identified as meteorites and which are probably related to each other [3]. Santorini was investigated with the rover s Panoramic Camera (Pancam), Microscopic Imager (MI), Alpha-Particle X-ray Spectrometer (APXS) and Moessbauer (MB) spectrometer. The miniature Thermal Emission Spectrometer (mini-TES) was not operational at the time. The Rock Abrasion Tool (RAT) could not be used to brush off potential dust coatings because of unfavorable geometry.

The Mars Exploration Rover Spirit landed in Gusev crater on Jan. 4, 2004. Spirit has traversed the Gusev crater plains, ascended to the top of Husband Hill, and entered into the Inner Basin of the Columbia Hills. The Athena science payload onboard Spirit has recorded numerous measurements on the chemistry and mineralogy of materials encountered during nearly 2 Mars years of operation within the crater. Rocks and soils have been grouped into classes based upon their unique differences in mineralogy and chemistry [1-3]. Some of the most significant chemical discoveries include the composition of Adirondack class flood basalts [4-6]; high sulfur in Clovis and Peace Class rocks [7,2]; high P and Ti in Wishstone Class rocks [7,2]; composition of alkalic basalts [2,6]; very high S in Paso Robles class soils [7,2], and the possible occurrence of a smectite-like chemical composition in Independence class rocks [8]. Water has played a significant role in the alteration of rocks and soils in the Columbia Hills. The occurrence of goethite and ferric sulfate alone suggests that liquid water was involved in their formation [3]. The pervasively altered materials in Husband Hill outcrops and rocks may have formed by the aqueous alteration of basaltic rocks, volcaniclastic materials, and/or impact ejecta by solutions that were rich in acid-volatile elements [2]. The objective of this paper is to provide an update on the health of the Alpha Particle X-ray Spectrometer (APXS) and to expand the geochemical dataset from sol 470 to sol 1368. Specific objectives are to (1) update the rock and soil classifications, (2) characterize elemental relationships among the major rock and soil classes, and (3) evaluate the involvement of water in the formation or alteration of the materials in these classes.

The Alpha Particle X-ray Spectrometer (APXS) instrument on the Mars Exploration Rover (MER) Spirit measured three targets on or adjacent to Home Plate in Gusev Crater that have unusually high SiO2 concentrations (68% to 91%), unusually low FeO concentrations (1% to 7%, with total Fe as FeO), and unusually high TiO2/FeO ratios (0.2 to 1.2 by weight) [1]. Two targets (Kenosha Comets and Lefty Ganote) are located on high albedo soil (Gertrude Weise) that was exposed by the rover wheels, and one target is a float rock called Fuzzy Smith. Kenosha Comets has the highest SiO2 concentration, lowest FeO concentration, and highest TiO2/FeO ratio. Mineralogical evidence from the MER Miniature Thermal Emission Spectrometer (Mini-TES) suggests that the SiO2 is present as amorphous (noncrystalline) SiO2 at Gertrude Weise and nearby targets [2,3]. Mini-TES data were not acquired for Fuzzy Smith. Home Plate is considered to have an explosive volcanic origin, resulting when basaltic magma came into contact with ground water or ice [4]. Within ~50 m to 1 km of Home Plate are sulfate rich soil deposits (Paso Robles class soils with 22-35% SO3) which are considered to be probable fumarolic and/or hydrothermal deposits associated with the volcanism [5]. We develop the model here, suggested by [5], that the high-silica materials are another manifestation of acid-sulfate processes associated with fumarolic and hydrothermal activity at Home Plate. This is done by analogy with basaltic materials altered by acid sulfate processes on the Island of Hawaii.

Multispectral imaging from the Panoramic Camera (Pancam) instruments on the Mars Exploration Rovers Spirit and Opportunity has provided important new insights about the geology and geologic history of the rover landing sites and traverse locations in Gusev crater and Meridiani Planum. Pancam observations from near-UV to near-IR wavelengths provide limited compositional and mineralogic constraints on the presence abundance, and physical properties of ferric- and ferrous-iron bearing minerals in rocks, soils, and dust at both sites. High resolution and stereo morphologic observations have also helped to infer some aspects of the composition of these materials at both sites. Perhaps most importantly, Pancam observations were often efficiently and effectively used to discover and select the relatively small number of places where in situ measurements were performed by the rover instruments, thus supporting and enabling the much more quantitative mineralogic discoveries made using elemental chemistry and mineralogy data. This chapter summarizes the major compositionally- and mineralogically-relevant results at Gusev and Meridiani derived from Pancam observations. Classes of materials encountered in Gusev crater include outcrop rocks, float rocks, cobbles, clasts, soils, dust, rock grindings, rock coatings, windblown drift deposits, and exhumed whitish/yellowish salty soils. Materials studied in Meridiani Planum include sedimentary outcrop rocks, rock rinds, fracture fills, hematite spherules, cobbles, rock fragments, meteorites, soils, and windblown drift deposits. This chapter also previews the results of a number of coordinated observations between Pancam and other rover-based and Mars-orbital instruments that were designed to provide complementary new information and constraints on the mineralogy and physical properties of martian surface materials.

Home Plate is a layered plateau in Gusev crater on Mars. It is composed of clastic rocks of moderately altered alkali basalt composition, enriched in some highly volatile elements. A coarse-grained lower unit is overlain by a finer-grained upper unit. Textural observations indicate that the lower strata were emplaced in an explosive event, and geochemical considerations favor an explosive volcanic origin over an impact origin. The lower unit likely represents accumulation of pyroclastic materials, while the upper unit may represent eolian reworking of the same pyroclastic materials.

The chemistry and mineralogy of the sulfate-rich sandstone outcrops at Meridiani Planum, Mars, have been inferred from data obtained by the Opportunity rover of the MER mission and reported in recent publications [1-6]. Here, we provide an update on more recent samples and results derived from this extensive data set.

Uniquely high levels of phosphorus and titanium were observed in several samples [1-3] by the APXS x-ray fluorescence measurements as the MER Spirit rover climbed Husband Hill (Columbia Hills, Gusev crater, Mars). A careful study of many such samples and their geochemical variability has revealed additional elements in this pattern, and that the derived multi-element signature is also unambiguously manifested in several martian meteorites.

The Alpha-Particle-X-ray Spectrometer (APXS) is part of the in situ payload of the Mars Exploration Rovers. It has determined the chemical composition of soils and rocks along the nearly 6 km long traverse of the rover Spirit. The measuring method a combination of PIXE and XRF using Cm244 sources - allowed the unambiguous identification of elemental compositions with high precision. Besides sample triage and quantification of saltforming elements as indicators for aqueous alteration, the APXS also delivered important constraints to mineralogy intruments (i.e., Mossbauer (MB), MiniTES, Pancam) on minerals and rock types. The mineralogy instruments on the other hand provided constraints on minerals used for APXS normative calculations and, e.g. allowed the attribution of S to sulfate, instead of sulfide or elemental sulfur. This abstract gives an updated overview of the data obtained up to our current rover position on sol 720 at the eastern base of the Columbia Hills. We will emphasize elemental correlations that imply the presence of certain minerals that can not be identified by the MER mineralogy instruments.

The cratered plains of Gusev traversed by Spirit are generally low-relief rocky plains dominated by impact and eolian processes. Ubiquitous shallow, soil-filled, circular depressions, called hollows, are modified impact craters. Rocks are dark, fine-grained basalts, and the upper 10 m of the cratered plains appears to be an impact-generated regolith developed over intact basalt flows. Systematic field observations across the cratered plains identified vesicular clasts and rare scoria similar to original lava flow tops, consistent with an upper inflated surface of lava flows with adjacent collapse depressions. Crater and hollow morphometry are consistent with most being secondaries. The size frequency distribution of rocks >0.1 m diameter generally follows exponential functions similar to other landing sites for total rock abundances of 5-35%. Systematic clast counts show that areas with higher rock abundance and more large rocks have higher thermal inertia. Plains with lower thermal inertia have fewer rocks and substantially more pebbles that are well sorted and evenly spaced, similar to a desert pavement or lag. Eolian bed forms (ripples and wind tails) have coarse surface lags, and many are dust covered and thus likely inactive. Deflation of the surface _5-25 cm likely exposed two-toned rocks and elevated ventifacts and transported fines into craters creating the hollows. This observed redistribution yields extremely slow average erosion rates of _0.03 nm/yr and argues for very little long-term net change of the surface and a dry and desiccating environment similar to today's since the Hesperian (or _3 Ga).

The Moessbauer spectrometer on Spirit measured the oxidation state of Fe, identified Fe-bearing phases, and measured relative abundances of Fe among those phases for surface materials on the plains and in the Columbia Hills of Gusev crater. Eight Fe-bearing phases were identified: olivine, pyroxene, ilmenite, magnetite, nanophase ferric oxide (npOx), hematite, goethite, and a Fe(3+)-sulfate. Adirondack basaltic rocks on the plains are nearly unaltered (Fe(3+)/Fe(sub T)<0.2) with Fe from olivine, pyroxene (Ol>Px), and minor npOx and magnetite. Columbia Hills basaltic rocks are nearly unaltered (Peace and Backstay), moderately altered (WoolyPatch, Wishstone, and Keystone), and pervasively altered (e.g., Clovis, Uchben, Watchtower, Keel, and Paros with Fe(3+)/Fe(sub T) approx.0.6-0.9). Fe from pyroxene is greater than Fe from olivine (Ol sometimes absent), and Fe(2+) from Ol+Px is 40-49% and 9-24% for moderately and pervasively altered materials, respectively. Ilmenite (Fe from Ilm approx.3-6%) is present in Backstay, Wishstone, Keystone, and related rocks along with magnetite (Fe from Mt approx. 10-15%). Remaining Fe is present as npOx, hematite, and goethite in variable proportions. Clovis has the highest goethite content (Fe from Gt=40%). Goethite (alpha-FeOOH) is mineralogical evidence for aqueous processes because it has structural hydroxide and is formed under aqueous conditions. Relatively unaltered basaltic soils (Fe(3+)/Fe(sub T) approx. 0.3) occur throughout Gusev crater (approx. 60-80% Fe from Ol+Px, approx. 10-30% from npOx, and approx. 10% from Mt). PasoRobles soil in the Columbia Hills has a unique occurrence of high concentrations of Fe(3+)-sulfate (approx. 65% of Fe). Magnetite is identified as a strongly magnetic phase in Martian soil and dust.

Experimental data for alteration of synthetic Martian basalts at pH=0-1 indicate that chemical fractionations at low pH are vastly different from those observed during terrestrial weathering. Rock analyses from Gusev crater are well described by the relationships apparent from low pH experimental alteration data. A model for rock surface alteration is developed which indicates that a leached alteration zone is present on rock surfaces at Gusev. This zone is not chemically fractionated to a large degree from the underlying rock interior, indicating that the rock surface alteration process has occurred at low fluid-to-rock ratio. The geochemistry of natural rock surfaces analyzed by APXS is consistent with a mixture between adhering soil/dust and the leached alteration zone. The chemistry of rock surfaces analyzed after brushing with the RAT is largely representative of the leached alteration zone. The chemistry of rock surfaces analyzed after grinding with the RAT is largely representative of the interior of the rock, relatively unaffected by the alteration process occurring at the rock surface. Elemental measurements from the Spirit, Opportunity, Pathfinder and Viking 1 landing sites indicate that soil chemistry from widely separated locations is consistent with the low-pH, low fluid to rock ratio alteration relationships developed for Gusev rocks. Soils are affected principally by mobility of FeO and MgO, consistent with alteration of olivine-bearing basalt and subsequent precipitation of FeO and MgO bearing secondary minerals as the primary control on soil geochemistry.

Visible and Near Infrared (VNIR) multispectral observations of rocks made by the Mars Exploration Rover Spirit s Panoramic camera (Pancam) have been analysed using a spectral mixture analysis (SMA) methodology. Scenes have been examined from the Gusev crater plains into the Columbia Hills. Most scenes on the plains and in the Columbia Hills could be modeled as three endmember mixtures of a bright material, rock, and shade. Scenes of rocks disturbed by the rover s Rock Abrasion Tool (RAT) required additional endmembers. In the Columbia Hills there were a number of scenes in which additional rock endmembers were required. The SMA methodology identified relatively dust-free areas on undisturbed rock surfaces, as well as spectrally unique areas on RAT abraded rocks. Spectral parameters from these areas were examined and six spectral classes were identified. These classes are named after a type rock or area and are: Adirondack, Lower West Spur, Clovis, Wishstone, Peace, and Watchtower. These classes are discriminable based, primarily, on near-infrared (NIR) spectral parameters. Clovis and Watchtower class rocks appear more oxidized than Wishstone class rocks and Adirondack basalts based on their having higher 535 nm band depths. Comparison of the spectral parameters of these Gusev crater rocks to parameters of glass-dominated basaltic tuffs indicates correspondence between measurements of Clovis and Watchtower classes, but divergence for the Wishstone class rocks which appear to have a higher fraction of crystalline ferrous iron bearing phases. Despite a high sulfur content, the rock Peace has NIR properties resembling plains basalts.

Iron-rich spherules (>90% Fe2O3 from electron microprobe analyses) approx.10-100 microns in diameter are found within sulfate-rich rocks formed by aqueous, acid-sulfate alteration of basaltic tephra on Mauna Kea volcano, Hawaii. Although some spherules are nearly pure Fe, most have two concentric compositional zones, with the core having a higher Fe/Al ratio than the rim. Oxide totals less than 100% (93-99%) suggest structural H2O and/or /OH. The transmission Moessbauer spectrum of a spherule-rich separate is dominated by a hematite (alpha-Fe2O3) sextet whose peaks are skewed toward zero velocity. Skewing is consistent with Al(3+) for Fe(3+) substitution and structural H2O and/or /OH. The grey color of the spherules implies specular hematite. Whole-rock powder X-ray diffraction spectra are dominated by peaks from smectite and the hydroxy sulfate mineral natroalunite as alteration products and plagioclase feldspar that was present in the precursor basaltic tephra. Whether spherule formation proceeded directly from basaltic material in one event (dissolution of basaltic material and precipitation of hematite spherules) or whether spherule formation required more than one event (formation of Fe-bearing sulfate rock and subsequent hydrolysis to hematite) is not currently constrained. By analogy, a formation pathway for the hematite spherules in sulfate-rich outcrops at Meridiani Planum on Mars (the Burns formation) is aqueous alteration of basaltic precursor material under acid-sulfate conditions. Although hydrothermal conditions are present on Mauna Kea, such conditions may not be required for spherule formation on Mars if the time interval for hydrolysis at lower temperatures is sufficiently long.

Comprehensive analyses of remote sensing data during the three-year effort to select the Mars Exploration Rover landing sites at Gusev crater and at Meridiani Planum correctly predicted the atmospheric density profile during entry and descent and the safe and trafficable surfaces explored by the two rovers. The Gusev crater site was correctly predicted to be a low-relief surface that was less rocky than the Viking landing sites but comparably dusty. A dark, lowalbedo, flat plain composed of basaltic sand and haematite with very few rocks was expected and found at Meridiani Planum. These results argue that future efforts to select safe landing sites based on existing and acquired remote sensing data will be successful. In contrast, geological interpretations of the sites based on remote sensing data were less certain and less successful, which emphasizes the inherent ambiguities in understanding surface geology from remotely sensed data and the uncertainty in predicting exactly what materials will be available for study at a landing site.

Spirit landed on the floor of Gusev Crater and conducted initial operations on soil covered, rock-strewn cratered plains underlain by olivine-bearing basalts. Plains surface rocks are covered by wind-blown dust and show evidence for surface enrichment of soluble species as vein and void-filling materials and coatings. The surface enrichment is the result of a minor amount of transport and deposition by aqueous processes. Layered granular deposits were discovered in the Columbia Hills, with outcrops that tend to dip conformably with the topography. The granular rocks are interpreted to be volcanic ash and/or impact ejecta deposits that have been modified by aqueous fluids during and/or after emplacement. Soils consist of basaltic deposits that are weakly cohesive, relatively poorly sorted, and covered by a veneer of wind blown dust. The soils have been homogenized by wind transport over at least the several kilometer length scale traversed by the rover. Mobilization of soluble species has occurred within at least two soil deposits examined. The presence of mono-layers of coarse sand on wind-blown bedforms, together with even spacing of granule-sized surface clasts, suggest that some of the soil surfaces encountered by Spirit have not been modified by wind for some time. On the other hand, dust deposits on the surface and rover deck have changed during the course of the mission. Detection of dust devils, monitoring of the dust opacity and lower boundary layer, and coordinated experiments with orbiters provided new insights into atmosphere-surface dynamics.

During its exploration within Gusev crater between sol 01 and sol 158, the Spirit rover dug three trenches (Fig. 1) to expose the subsurface regolith [1, 2, 9]. Laguna trench (approx. 6 cm deep, approx.203 m from the rim of Bonneville crater) was dug in Laguna Hollow at the boundary of the impact ejecta from Bonneville crater and the surrounding plains. The Big Hole trench (approx. 6-7 cm deep) and The Boroughs trench (approx. 11 cm deep) were dug in the plains between the Bonneville crater and the Columbia Hills (approx.556 m and approx.1698 m from the rim of Bonneville crater respectively). The top, wall and floor regolith of the three trenches were investigated using the entire set of Athena scientific instruments [10].

Analyses of outcrops created by the impact craters Endurance, Fram and Eagle reveal the broad lateral continuity of chemical sediments at the Meridiani Planum exploration site on Mars. Approximately ten mineralogical components are implied in these salt-rich silicic sediments, from measurements by instruments on the Opportunity rover. Compositional trends in an apparently intact vertical stratigraphic sequence at the Karatepe West ingress point at Endurance crater are consistent with non-uniform deposition or with subsequent migration of mobile salt components, dominated by sulfates of magnesium. Striking variations in Cl and enrichments of Br, combined with diversity in sulfate species, provide further evidence of episodes during which temperatures, pH, and water to rock ratios underwent significant change. To first order, the sedimentary sequence examined to date is consistent with a uniform reference composition, modified by movement of major sulfates upward and of minor chlorides downward. This reference composition has similarities to martian soils, supplemented by sulfate anion and the alteration products of mafic igneous minerals. Lesser cementation in lower stratigraphic units is reflected in decreased energies for grinding with the Rock Abrasion Tool. Survival of soluble salts in exposed outcrop is most easily explained by absence of episodes of liquid H2O in this region since the time of crater formation.

The Mars Exploration Rovers each carry a set of Magnetic Properties Experiments designed to investigate the properties of the air-borne dust in the Martian atmosphere. It is a preferred interpretation of previous experiments (Viking 1 & 2, 1976 and Mars Pathfinder, 1997) that the airborne dust in the Martian atmosphere is primarily composed by composite silicate particles containing one or more highly magnetic minerals as a minor constituent, this minor constituent probably being dominated by the mineral maghemite (gamma-Fe2O3). The ultimate goal of the magnetic properties experiments on the Mars Exploration Rover mission is to provide some information/constraints on whether the dust is formed by volcanic, meteoritic, aqueous, or other processes. In detail, the objectives are: a) To identify the magnetic mineral(s) in the dust, soil and rocks on Mars. b) To establish if the magnetic material is present in the form of nanosized (d < 10 nm) superparamagnetic crystallites embedded in the micrometer sized airborne dust part icles. c) To establish if the magnets are culling a subset of strongly magnetic particles or if essentially all particles of the airborne dust are sufficiently magnetic to be attracted by the magnets. d) Detect compositional differences between the airborne dust and the soil and rock sites which are investigated at two landing sites. To accomplish these goals the Mars Exploration Rovers each carry a set of permanent magnets of several different strengths and sizes. Each magnet has its own specific objective.

The Mars Exploration Rovers carry four Panoramic Camera (Pancam) instruments (two per rover) that have obtained high resolution multispectral and stereoscopic images for studies of the geology, mineralogy, and surface and atmospheric physical properties at both rover landing sites. The Pancams are also providing significant mission support measurements for the rovers, including Sun-finding for rover navigation, hazard identification and digital terrain modeling to help guide long-term rover traverse decisions, high resolution imaging to help guide the selection of in situ sampling targets, and acquisition of education and public outreach imaging products.

The Panoramic Camera System (Pancam) is part of the Athena science payload to be launched to Mars in 2003 on NASA's twin Mars Exploration Rover (MER) missions. The Pancam imaging system on each rover consists of two major components: a pair of digital CCD cameras, and the Pancam Mast Assembly (PMA), which provides the azimuth and elevation actuation for the cameras as well as a 1.5 meter high vantage point from which to image. Pancam is a multispectral, stereoscopic, panoramic imaging system, with a field of regard provided by the PMA that extends across 360 of azimuth and from zenith to nadir, providing a complete view of the scene around the rover.

We present an overview of the results from the NEAR (Near Earth Asteroid Rendezvous)-Shoemaker remote sensing X-Ray/Gamma-Ray Spectrometer experiment for more than a year of operation in orbit and on the surface of 433 Eros. Additional information is contained in the original extended abstract.

Results of May 2000 field testing of the FIDO prototype Mars rover are summarized. Tests included remote science operations and simulated aspects of the Athena payload for 2003 MER (Mars Exploration Rovers). Additional information is contained in the original extended abstract.

The Mars Microbeam Raman Spectrometer can identify minerals in situ, determine rock types and textures, provide some mineral chemistry, detect organic and biogenic materials, and identify bound water. Additional information is contained in the original extended abstract.

We look into the possibility that Callisto's accretional history straddled the time during which Jupiter opened a gap in the solar nebula and occurred over an extended period from a very extended very low density disk. Additional information is contained in the original extended abstract.

Status of the NEAR X-ray/gamma-ray spectrometer, end of mission status. Additional information is contained in the original extended abstract.

The Gamma-Ray Spectrometer (GRS) is one of the instruments on the Mars Surveyor 2001 Orbiter, which is part of NASA's Mars-Surveyor program. The GRS is really an instrument suite consisting of the GRS, a neutron spectrometer (NS), and a high-energy neutron detector (FIEND). Each of these instruments/sensors are remotely mounted at different locations on the spacecraft and connect to a central electronics box. The GRS will achieve global mapping of the elemental composition of the surface and the abundance of hydrogen in the shallow subsurface. It is an updated design using the same technology as the lost Mars Observer mission. The Martian surface is continuously bombarded by cosmic ray particles; their interactions with the constituents of the soil produces nuclear reaction cascades with fast neutrons being the main secondaries. Those neutrons interact in turn with the nuclei of the elements that make up the soil and they eventually get slowed to thermal energies. In this process they leave the nuclei in an excited state that decays via the emission of characteristic gamma rays. All these processes are precisely known and have been simulated by means of numerical models. Thus, remote gamma-ray spectroscopy is a useful method for quantitatively measuring the geochemical composition of the surface down to a few tens of g/sq cm. Additional information is contained in original extended abstract.

The Mars Surveyor program requires tools for martian surface exploration, including remote sensing, in-situ sensing, and sample collection. The Athena Mars rover payload is a suite of scientific instruments and sample collection tools designed to: (1) Provide color stereo imaging of martian surface environments, and remotely-sensed point discrimination of mineralogical composition; (2) Determine the elemental and mineralogical composition of martian surface materials; (3) Determine the fine-scale textural properties of these materials; and (4) Collect and store samples. The Athena payload is designed to be implemented on a long-range rover such as the one now under consideration for the 2003 Mars opportunity. The payload is at a high state of maturity, and most of the instruments have now been built for flight.

The Mars 2003 Mission may include a rover to acquire remote sensing and in-situ measurements of surface materials, including rock surfaces that have been cleared of dust and coatings by use of an abrasion tool. Mars Sample Return Missions for 2005 and beyond may include rovers with remote sensing and in-situ measurement capabilities. Further, these mobility platforms may have systems to drill into rocks and collect cores, acquire soil samples, and place the rock and soil samples in ascent vehicles. The point of this abstract is to document that these operations have already been shown to be tractable based on continuing field trials of the FIDO Mars prototype rover.

During field trials in the Mojave Desert, the Mars Sample Return (MSR) prototype rover, FIDO, simulated sampling and exploration activities with a science payload similar to what will be on the MSR rover, validating the mission operations approach.

The Mars Surveyor Program 2001 Mission will carry instruments on the orbiter, lander and rover that will support synergistic observations and experiments to address important scientific questions regarding the local bedrock and soils. The martian surface is covered in varying degrees by fine materials less than a few mms in size. Viking and Pathfinder images of the surface indicate that soils at those sites are composed of fine particles. Wheel tracks from the Sojourner rover suggest that soil deposits are composed of particles <40 mm. Viking images show that dunes are common in many areas on Mars and new MOC images indicate that dunes occur nearly everywhere. Dunes on Mars are thought to be composed of 250-500 microns particles based upon Viking IRTM data and Mars wind tunnel experiments. If martian dunes are composed of sand particles > 100 microns and soils are dominated by <10 micron particles, then where are the intermediate grain sizes? Have they been wom away through prolonged transport over the eons? Were they never generated to begin with? Or are they simply less easy to identify because do they not form distinctive geomorphic features such as dunes or uniform mantles that tend to assume superposition in the soil structure?

The Athena Precursor Experiment (APEX) is a suite of scientific instruments for the Mars Surveyor Program 2001 (MSP'01) lander. The major elements of the APEX pay load are: (1) Pancam/Mini-TES, a combined stereo color imager and mid-infrared point spectrometer. (2) An Alpha-Proton-X-Ray Spectrometer (APXS) for in-situ elemental analysis. (3) A Mossbauer Spectrometer for in-situ determination of the mineralogy of Fe-bearing rocks and soils. (4) A Magnet Array that can separate magnetic soil particles from non-magnetic ones.

A 13-day long duration balloon flight carrying a germanium detector was flown from Williams Field, Antartica in December 1992. After recovery of the payload the activity induced in the detector was measured.

The MESUR mission will place a network of small, robust landers on the Martian surface, making a coordinated set of observations for at least one Martian year. MESUR presents some major challenges for development of instruments, instrument deployment systems, and on board data processing techniques. The instrument payload has not yet been selected, but the straw man payload is (1) a three-axis seismometer; (2) a meteorology package that senses pressure, temperature, wind speed and direction, humidity, and sky brightness; (3) an alphaproton-X-ray spectrometer (APXS); (4) a thermal analysis/evolved gas analysis (TA/EGA) instrument; (5) a descent imager, (6) a panoramic surface imager; (7) an atmospheric structure instrument (ASI) that senses pressure, temperature, and acceleration during descent to the surface; and (8) radio science. Because of the large number of landers to be sent (about 16), all these instruments must be very lightweight. All but the descent imager and the ASI must survive landing loads that may approach 100 g. The meteorology package, seismometer, and surface imager must be able to survive on the surface for at least one Martian year. The seismometer requires deployment off the lander body. The panoramic imager and some components of the meteorology package require deployment above the lander body. The APXS must be placed directly against one or more rocks near the lander, prompting consideration of a micro rover for deployment of this instrument. The TA/EGA requires a system to acquire, contain, and heat a soil sample. Both the imagers and, especially, the seismometer will be capable of producing large volumes of data, and will require use of sophisticated data compression techniques.

The Clementine Mission is being built and flown by the Naval Research Laboratory under the sponsorship of the Strategic Defense Initiative Organization of the United States Department of Defense in joint-cooperation with NASA, and will explore the Moon and the near-Earth asteroid (NEA) 1620 Geographos with lightweight sensors developed by the Lawrence Livermore National Laboratory. A NASA Science Team for this mission will be selected by way of a NRA in April 1993. The instrument suite includes imaging cameras that cover a spectral range from the near-ultraviolet to the mid-infrared, a laser ranger, and, potentially, a charged particle telescope. To be launched in early 1994, Clementine will be in lunar orbit from February through May 1994, at which time it will depart the Moon for a flyby of 1620 Geographos in August 1994. This mission represents an outstanding opportunity for scientists interested in the Moon and asteroids. It is anticipated that the data returned from this mission will permit: an assessment of global lunar crustal heterogeneity and a resolution of less than 1 km; an assessment of the lithologic heterogeneity of Geographos at a scale of 100 m or better; and an assessment of surface processes on Geographos on the order of 10 m. The basic mission of Clementine and some of the key scientific questions that will be addressed are described. Additional material on the Clementine mission, its data handling and processing, and its instrument suite is presented elsewhere.

The Mars Observer gamma ray spectrometer will return data related to the elemental composition of Mars. The instrument has both a gamma ray spectrometer and several neutron detectors. The gamma ray spectrometer will return a spectrum nominally every 20 s from Mars permitting a map of the elemental abundances to be made. The gamma rays are emitted from nuclei involved in radioactive decay, from nuclei formed by capture of a thermal neutron, and from nuclei put in an excited state by a fast-neutron interaction. The gamma rays come from an average depth of the order of a few tens of centimeters. The spectrum will show sharp emission lines whose intensity determines the concentration of the element and whose energy identifies the element. The neutron detectors, using the fact that the orbital velocity of the Mars Observer spacecraft is similar to the velocity of thermal neutrons, determine both the thermal and epithermal neutron flux. By combining the results from both techniques it is possible to map the depth dependence of hydrogen in the upper meter as well. These data permit a variety of Martian geoscience problems to be addressed including the crust and mantle composition, weathering processes, volcanism, and the volatile reservoirs and processes.

Coronae on Venus are large, generally circular surface features that have distinctive tectonic, volcanic, and topographic expressions. They range in diameter from less than 200 km to at least 1000 km. Data from the Magellan spacecraft have now allowed complete global mapping of the spatial distribution of coronae on the planet. Unlike impact craters, which show a random (i.e., Poisson) spatial distribution, the distribution of coronae appears to be nonrandom. We investigate the distribution here in detail, and explore its implications in terms of mantle convection and surface modification processes.

The relative abundances of H2O and CO2 and their latitude, longitude, and depth profiles on Mars sensitively reflect, as well as help control, past and present Martian climate patterns. Seasonal variations of their distributions at high latitudes also reflect and help control global weather patterns and erosion through surface weathering. A combined analysis of gamma ray line and neutron flux maps constructed from data measured using the Mars Observer Gamma Ray Spectrometer (MOGRS) should allow a determination of seasonal changes in both the horizontal and vertical structure of CO2 ice that covers the north polar cap during winter and the south polar cap throughout the year and both the horizontal and vertical structure of residual H2O ice within the top meter of the surface that was predicted from Viking observations to exist primarily at high latitudes. Particularly important in this regard will be maps of thermal and epithermal neutron fluxes measured using the MOGRS anticoincidence shield, the intensity of the hydrogen, neutron capture gamma ray line at 2.223 MeV, the intensity of a capture gamma ray line as 1.725 MeV from iron, and the intensity of an inelastic scatter gamma ray line as 1.779 MeV from silicon.

A number of possible morphologic indicators of ground ice on Mars are discussed, with emphasis on rampart craters and terrain softening. Geologic evidence indicates that the Martian surface has been substantially modified by the action of liquid water, and that much of that water still resides beneath the surface as ground ice. Calculations of the thermodynamic stability of ground ice on Mars suggest that it can exist very close to the surface at high latitudes, but can persist only at substantial depths near the equator. A variety of observed Martian landforms can be attributed to creep of the Martian regolith abetted by deformation of ground ice. Global mapping of creep features also supports the idea that ice is present in near-surface materials at latitudes higher than +/- 30 deg, and suggests that ice is largely absent from such materials at lower latitudes.

Individual Martian equatorial troughs are described, and their stratigraphy, geomorphology and structure are discussed. Possible origins and the overall sequence of events are addressed. Wall rock, interior layered deposits, irregular floor deposits, fractured floor material, and surficial deposits are examined. Chasma walls, wall stability, pits and pit chains, tributary canyons, and the transition from troughs to channels are also discussed.

The determination of the elemental composition of the surface of a planetary body can be achieved, in many cases, by remote-sensing gamma ray spectroscopy. A gamma ray spectrometer was carried on the Soviet spacecraft Phobos-2, and obtained data while in an elliptical orbit around Mars. Results of two independent approaches to data analysis, one by the Soviet group and one by an American group are reported. The results for five elements are given for two different orbits of Mars. Major geologic units that contribute to the signal for each orbit have been identified. The results from the two techniques are in general agreement and there appear to be no geologically significant differences between the results for each orbit.